18 research outputs found
<span style="font-size:13.0pt;mso-bidi-font-weight:bold">Ru catalyzed formylation of diethylamine with CO<sub>2</sub> and H<sub>2</sub> under moderate pressure condition </span>
752-756Ru catalyzed formylation of diethylamine (bulky
secondary amine) with CO2 and H2 has been investigated using
a series of phosphine ligands. Significant influence on the catalyst activity
and selectivity is observed with bidentate phosphine ligands. The Ru catalyst with
the ligand, 1,2-bis(diphenylphosphino)benzene exhibits the highest catalyst
performance (TON up to 2475). The high conversion (99%) and high selectivity to
the corresponding formamide (up to 90-98%) is achieved at 150 °C and moderate
pressure conditions. The effects of temperature, concentration of diethylamine and partial pressure of CO2
and H2 on the formylation of diethyl amine catalyzed have been
examined in order to improve the catalytic activity and selectivity.</span
Monodentate bulky trinaphthylphosphine as ligand in Rh, Co and Ru catalyzed hydroformylation of 1-hexene
27-32Rhodium,
cobalt, and ruthenium complexes of monodentate bulky trinaphthylphosphine
ligand, PNp3, have been synthesized and used as catalysts for the
hydroformylation of 1-hexene. The catalyst, RhCl(PNp3)3
shows excellent hydroformylation activity as compared to the Co/PNp3
and Ru/PNp3 system. The high conversion (99 %) with high selectivity
to aldehydes (97 %) is achieved by RhCl(PNp3)3 catalyst
whereas RuCl2(PNp3)3 is more active toward
hydrogenation rather than hydroformylation
Mid-temperature CO2 Adsorption over Different Alkaline Sorbents Dispersed over Mesoporous Al2O3
Mid-temperature CO<sub>2</sub> Adsorption over Different Alkaline Sorbents Dispersed over Mesoporous Al<sub>2</sub>O<sub>3</sub>
CO2 adsorbents
comprising various alkaline sorption
active phases supported on mesoporous Al2O3 were
prepared. The materials were tested regarding their CO2 adsorption behavior in the mid-temperature range, i.e., around 300
°C, as well as characterized via XRD, N2 physisorption,
CO2-TPD and TEM. It was found that the Na2O
sorption active phase supported on Al2O3 (originated
following NaNO3 impregnation) led to the highest CO2 adsorption capacity due to the presence of CO2-philic interfacial Al–O––Na+ sites, and the optimum active phase load was shown to be
12 wt % (0.22 Na/Al molar ratio). Additional adsorbents were prepared
by dispersing Na2O over different metal oxide supports
(ZrO2, TiO2, CeO2 and SiO2), showing an inferior performance than that of Na2O/Al2O3. The kinetics and thermodynamics of CO2 adsorption were also investigated at various temperatures, showing
that CO2 adsorption over the best-performing Na2O/Al2O3 material is exothermic and follows
the Avrami model, while tests under varying CO2 partial
pressures revealed that the Langmuir isotherm best fits the adsorption
data. Lastly, Na2O/Al2O3 was tested
under multiple CO2 adsorption–desorption cycles
at 300 and 500 °C, respectively. The material was found to maintain
its CO2 adsorption capacity with no detrimental effects
on its nanostructure, porosity and surface basic sites, thereby rendering
it suitable as a reversible CO2 chemisorbent or as a support
for the preparation of dual-function materials
Enhancing CO2 methanation over Ni catalysts supported on sol-gel derived Pr2O3-CeO2: An experimental and theoretical investigation
Ni-based catalysts supported on sol-gel prepared Pr-doped CeO2 with varied porosity and nanostructure were tested for the CO2 methanation reaction. It was found that the use of ethylene glycol in the absence of H2O during a modified Pechini synthesis led to a metal oxide support with larger pore size and volume, which was conducive toward the deposition of medium-sized Ni nanoparticles confined into the nanoporous structure. The high Ni dispersion and availability of surface defects and basic sites acted to greatly improve the catalyst's activity. CFD simulations were used to theoretically predict the catalytic performance given the reactor geometry, whereas COMSOL and ASPEN software were employed to design the models. Both modelling approaches (CFD and process simulation) showed a good validation with the experimental results and therefore confirm their ability for applications related to the prediction of the CO2 methanation behaviour
Enhancing CO2 methanation over Ni catalysts supported on sol-gel derived Pr2O3-CeO2: An experimental and theoretical investigation
Ni-based catalysts supported on sol-gel prepared Pr-doped CeO2 with varied porosity and nanostructure were tested for the CO2 methanation reaction. It was found that the use of ethylene glycol in the absence of H2O during a modified Pechini synthesis led to a metal oxide support with larger pore size and volume, which was conducive toward the deposition of medium-sized Ni nanoparticles confined into the nanoporous structure. The high Ni dispersion and availability of surface defects and basic sites acted to greatly improve the catalyst's activity. CFD simulations were used to theoretically predict the catalytic performance given the reactor geometry, whereas COMSOL and ASPEN software were employed to design the models. Both modelling approaches (CFD and process simulation) showed a good validation with the experimental results and therefore confirm their ability for applications related to the prediction of the CO2 methanation behaviour