81 research outputs found
Synthesis and characterization of biodegradable lignin nanoparticles with tunable surface properties
Lignin nanoparticles can serve as biodegradable carriers of biocidal actives with minimal environmental footprint. Here we describe the colloidal synthesis and interfacial design of nanoparticles with tunable surface properties using two different lignin precursors, Kraft (Indulin AT) lignin and Organosolv (high-purity lignin). The green synthesis process is based on flash precipitation of dissolved lignin polymer, which enabled the formation of nanoparticles in the size range of 45–250 nm. The size evolution of the two types of lignin particles is fitted on the basis of modified diffusive growth kinetics and mass balance dependencies. The surface properties of the nanoparticles are fine-tuned by coating them with a cationic polyelectrolyte, poly(diallyldimethylammonium chloride). We analyze how the colloidal stability and dispersion properties of these two types of nanoparticles vary as a function of pH and salinities. The data show that the properties of the nanoparticles are governed by the type of lignin used and the presence of polyelectrolyte surface coating. The coating allows the control of the nanoparticles’ surface charge and the extension of their stability into strongly basic regimes, facilitating their potential application at extreme pH conditions
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A randomized trial of a lab-embedded discourse intervention to improve research ethics.
We report a randomized trial of a research ethics training intervention designed to enhance ethics communication in university science and engineering laboratories, focusing specifically on authorship and data management. The intervention is a project-based research ethics curriculum that was designed to enhance the ability of science and engineering research laboratory members to engage in reason giving and interpersonal communication necessary for ethical practice. The randomized trial was fielded in active faculty-led laboratories at two US research-intensive institutions. Here, we show that laboratory members perceived improvements in the quality of discourse on research ethics within their laboratories and enhanced awareness of the relevance and reasons for that discourse for their work as measured by a survey administered over 4 mo after the intervention. This training represents a paradigm shift compared with more typical module-based or classroom ethics instruction that is divorced from the everyday workflow and practices within laboratories and is designed to cultivate a campus culture of ethical science and engineering research in the very work settings where laboratory members interact
Effects of the Phoenix Lander descent thruster plume on the Martian surface
Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/94966/1/jgre2468.pd
Two Derivations of the Master Equation of Quantum Brownian Motion
Central to many discussion of decoherence is a master equation for the
reduced density matrix of a massive particle experiencing scattering from its
surrounding environment, such as that of Joos and Zeh. Such master equations
enjoy a close relationship with spontaneous localization models, like the GRW
model. This aim of this paper is to present two derivations of the master
equation. The first derivation is a pedagogical model designed to illustrate
the origins of the master equation as simply as possible, focusing on physical
principles and without the complications of S-matrix theory. This derivation
may serve as a useful tutorial example for students attempting to learn this
subject area. The second is the opposite: a very general derivation using
non-relativistic many body field theory. It reduces to the equation of the type
given by Joos and Zeh in the one-particle sector, but correcting certain
numerical factors which have recently become significant in connection with
experimental tests of decoherence. This master equation also emphasizes the
role of local number density as the ``preferred basis'' for decoherence in this
model.Comment: 19 pages, RevTe
Project #82: HFWH Vertical Treatment Zone
Problem Statement: Limited Emergency Department bed capacity and increased acuity resulted in increased left without completing service (LWCS) resulting in increased patient safety risk.
Goal: Design a new patient throughput workflow to provide safe, timely and quality patient-centered care resulting in decreased LWSC, decreased arrival to provider times, decreased LOS of the discharged patient, and increased patient satisfaction.https://scholarlycommons.henryford.com/qualityexpo2023/1007/thumbnail.jp
Introduction to special section on the Phoenix Mission: Landing Site Characterization Experiments, Mission Overviews, and Expected Science
Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/94752/1/jgre2486.pd
How Many Scientists Fabricate and Falsify Research? A Systematic Review and Meta-Analysis of Survey Data
The frequency with which scientists fabricate and falsify data, or commit other forms of scientific misconduct is a matter of controversy. Many surveys have asked scientists directly whether they have committed or know of a colleague who committed research misconduct, but their results appeared difficult to compare and synthesize. This is the first meta-analysis of these surveys
Chaos, decoherence and quantum cosmology
In this topical review we discuss the connections between chaos, decoherence
and quantum cosmology. We understand chaos as classical chaos in systems with a
finite number of degrees of freedom, decoherence as environment induced
decoherence and quantum cosmology as the theory of the Wheeler - DeWitt
equation or else the consistent history formulation thereof, first in mini
super spaces and later through its extension to midi super spaces. The overall
conclusion is that consideration of decoherence is necessary (and probably
sufficient) to sustain an interpretation of quantum cosmology based on the Wave
function of the Universe adopting a Wentzel - Kramers - Brillouin form for
large Universes, but a definitive account of the semiclassical transition in
classically chaotic cosmological models is not available in the literature yet.Comment: 40 page
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