Photoelectric emission from the alkali metal doped vacuum-ice interface

The photoelectron photoemission spectra and thresholds for low coverages of Li and K adsorbed on water-ice have been measured, compared with photoionization spectra of the gas-phase atoms, and modeled by quantum chemical calculations. For both alkali metals the threshold for photoemission is dramatically decreased and the cross section increased on adsorption to the water-ice surface. Quantum chemical calculations suggest that the initial state is formed by the metal atoms adsorbed into the water-ice surface, forming a state with a delocalized electron distribution. This state is metastable and decays on the hundreds of seconds time scale at 92 K. The decay is markedly faster for Li than for K, probably due to diffusion into the ice film

Diurnal variation of the potassium layer in the upper atmosphere

Measurements of the diurnal cycle of potassium (K) atoms between 80 and 110km have been made during October (for the years 2004–2011) using a Doppler lidar at Kühlungsborn, Germany (54.1°N,11.7°E). A pronounced diurnal variation is observed in the K number density, which is explored by using a detailed description of the neutral and ionized chemistry of K in a three-dimensional chemistry climate model. The model captures both the amplitude and phase of the diurnal and semidiurnal variability of the layer, although the peak diurnal amplitude around 90 kmis overestimated. Themodel shows that the total potassium density (≈K+K++KHCO3) exhibits little diurnal variation at each altitude, and the diurnal variations are largely driven by photochemical conversion between these reservoir species. In contrast, tidally driven vertical transport has a small effect at this midlatitude location, and diurnal fluctuations in temperature are of little significance because they are small and the chemistry of K is relatively temperature independent

On the size and velocity distribution of cosmic dust particles entering the atmosphere

The size and velocity distribution of cosmic dust particles entering the Earth's atmosphere is uncertain. Here we show that the relative concentrations of metal atoms in the upper mesosphere, and the surface accretion rate of cosmic spherules, provide sensitive probes of this distribution. Three cosmic dust models are selected as case studies: two are astronomical models, the first constrained by infrared observations of the Zodiacal Dust Cloud and the second by radar observations of meteor head echoes; the third model is based on measurements made with a spaceborne dust detector. For each model, a Monte Carlo sampling method combined with a chemical ablation model is used to predict the ablation rates of Na, K, Fe, Mg, and Ca above 60 km and cosmic spherule production rate. It appears that a significant fraction of the cosmic dust consists of small (<5 µg) and slow (<15 km s−1) particles

Measurements of the vertical fluxes of atomic Fe and Na at the mesopause: implications for the velocity of cosmic dust entering the atmosphere

The downward fluxes of Fe and Na, measured near the mesopause with the University of Colorado lidars near Boulder, and a chemical ablation model developed at the University of Leeds, are used to constrain the velocity/mass distribution of the meteoroids entering the atmosphere and to derive an improved estimate for the global influx of cosmic dust. We find that the particles responsible for injecting a large fraction of the ablated material into the Earth's upper atmosphere enter at relatively slow speeds and originate primarily from the Jupiter Family of Comets. The global mean Na influx is 17,200 ± 2800 atoms/cm2/s, which equals 298 ± 47 kg/d for the global input of Na vapor and 150 ± 38 t/d for the global influx of cosmic dust. The global mean Fe influx is 102,000 ± 18,000 atoms/cm2/s, which equals 4.29 ± 0.75 t/d for the global input of Fe vapor

Radar detectability studies of slow and small zodiacal dust cloud particles. I. The case of Arecibo 430 MHz meteor head echo observations

Recent model development of the Zodiacal Dust Cloud (ZDC) argues that the incoming flux of meteoric material into the Earth's upper atmosphere is mostly undetected by radars because they cannot detect small extraterrestrial particles entering the atmosphere at low velocities due to the relatively small production of electrons. In this paper, we present a new methodology utilizing meteor head echo radar observations that aims to constrain the ZDC physical model by ground-based measurements. In particular, for this work, we focus on Arecibo 430 MHz observations since this is the most sensitive radar utilized for this type of observations to date. For this, we integrate and employ existing comprehensive models of meteoroid ablation, ionization, and radar detection to enable accurate interpretation of radar observations and show that reasonable agreement in the hourly rates is found between model predictions and Arecibo observations when (1) we invoke the lower limit of the model predicted flux (∼16 t d-1) and (2) we estimate the ionization probability of ablating metal atoms using laboratory measurements of the ionization cross sections of high-speed metal atom beams, resulting in values up to two orders of magnitude lower than the extensively utilized figure reported by Jones for low-speed meteors. However, even at this lower limit, the model overpredicts the slow portion of the Arecibo radial velocity distributions by a factor of three, suggesting that the model requires some revision

Solar cycle response and long-term trends in the mesospheric metal layers

The meteoric metal layers (Na, Fe, and K)—which form as a result of the ablation of incoming meteors—act as unique tracers for chemical and dynamical processes that occur within the upper mesosphere/lower thermosphere region. In this work, we examine whether these metal layers are sensitive indicators of decadal long-term changes within the upper atmosphere. Output from a whole-atmosphere climate model is used to assess the response of the Na, K, and Fe layers across a 50 year period (1955–2005). At short timescales, the K layer has previously been shown to exhibit a very different seasonal behavior compared to the other metals. Here we show that this unusual behavior is also exhibited at longer timescales (both the ~11 year solar cycle and 50 year periods), where K displays a much more pronounced response to atmospheric temperature changes than either Na or Fe. The contrasting solar cycle behavior of the K and Na layers predicted by the model is confirmed using satellite and lidar observations for the period 2004–2013

Measurements of the vertical fluxes of atomic Fe and Na at the mesopause: implications for the velocity of cosmic dust entering the atmosphere

The downward fluxes of Fe and Na, measured near the mesopause with the University of Colorado lidars near Boulder, and a chemical ablation model developed at the University of Leeds, are used to constrain the velocity/mass distribution of the meteoroids entering the atmosphere and to derive an improved estimate for the global influx of cosmic dust. We find that the particles responsible for injecting a large fraction of the ablated material into the Earth's upper atmosphere enter at relatively slow speeds and originate primarily from the Jupiter Family of Comets. The global mean Na influx is 17,200 ± 2800 atoms/cm2/s, which equals 298 ± 47 kg/d for the global input of Na vapor and 150 ± 38 t/d for the global influx of cosmic dust. The global mean Fe influx is 102,000 ± 18,000 atoms/cm2/s, which equals 4.29 ± 0.75 t/d for the global input of Fe vapor

Global investigation of the Mg atom and ion layers using SCIAMACHY/Envisat observations between 70 and 150 km altitude and WACCM-Mg model results

Mg and Mg+ concentration fields in the upper mesosphere/lower thermosphere (UMLT) region are retrieved from SCIAMACHY/Envisat limb measurements of Mg and Mg+ dayglow emissions using a 2-D tomographic retrieval approach. The time series of monthly mean Mg and Mg+ number density and vertical column density in different latitudinal regions are presented. Data from the limb mesosphere–thermosphere mode of SCIAMACHY/Envisat are used, which cover the 50 to 150 km altitude region with a vertical sampling of ≈3.3 km and latitudes up to 82°. The high latitudes are not observed in the winter months, because there is no dayglow emission during polar night. The measurements were performed every 14 days from mid-2008 until April 2012. Mg profiles show a peak at around 90 km altitude with a density between 750 cm−3 and 1500 cm−3. Mg does not show strong seasonal variation at latitudes below 40°. For higher latitudes the density is lower and only in the Northern Hemisphere a seasonal cycle with a summer minimum is observed. The Mg+ peak occurs 5–15 km above the neutral Mg peak altitude. These ions have a significant seasonal cycle with a summer maximum in both hemispheres at mid and high latitudes. The strongest seasonal variations of Mg+ are observed at latitudes between 20 and 40° and the density at the peak altitude ranges from 500 cm−3 to 4000 cm−3. The peak altitude of the ions shows a latitudinal dependence with a maximum at mid latitudes that is up to 10 km higher than the peak altitude at the equator. The SCIAMACHY measurements are compared to other measurements and WACCM model results. The WACCM results show a significant seasonal variability for Mg with a summer minimum, which is more clearly pronounced than for SCIAMACHY, and globally a higher peak density than the SCIAMACHY results. Although the peak density of both is not in agreement, the vertical column density agrees well, because SCIAMACHY and WACCM profiles have different widths. The agreement between SCIAMACHY and WACCM results is much better for Mg+ with both showing the same seasonality and similar peak density. However, there are also minor differences, e.g. WACCM showing a nearly constant altitude of the Mg+ layer's peak density for all latitudes and seasons

Relict of Olivines in Micrometeorites: Precursors and interactions in the Earth's atmosphere

Antarctica micrometeorites (~1200) and cosmic spherules (~5000) from deep sea sediments are studied using electron microscopy to identify Mg-rich olivine grains in order to determine the nature of the particle precursors. Mg-rich olivine (FeO < 5wt%) in micrometeorites suffers insignificant chemical modification during its history and is a well-preserved phase. 420 forsterite grains enclosed in 162 micrometeorites of different types - unmelted, scoriaceous and porphyritic - are examined in this study. Forsterites in micrometeorites of different types are crystallized during their formation in solar nebula; their closest analogues are chondrule components of CV-type chondrites or volatile rich CM chondrites. The forsteritic olivines are suggested to have originated from a cluster of closely related carbonaceous asteroids that have Mg-rich olivines in the narrow range of CaO (0.1−0.3 wt%), Al2O3 (0.0−0.3wt%), MnO (0.0−0.3wt%) and Cr2O3 (0.1−0.7wt%). Numerical simulations carried out with the Chemical Ablation Model (CABMOD) enable us to define the physical conditions of atmospheric entry that preserve the original compositions of the Mg-rich olivines in these particles. The chemical compositions of relict olivines affirm the role of heating at peak temperatures and the cooling rates of the micrometeorites. This modelling approach provides a foundation for understanding the ablation of the particles and the circumstances in which the relict grains tend to survive

Crushing singularities in spacetimes with spherical, plane and hyperbolic symmetry

It is shown that the initial singularities in spatially compact spacetimes with spherical, plane or hyperbolic symmetry admitting a compact constant mean curvature hypersurface are crushing singularities when the matter content of spacetime is described by the Vlasov equation (collisionless matter) or the wave equation (massless scalar field). In the spherically symmetric case it is further shown that if the spacetime admits a maximal slice then there are crushing singularities both in the past and in the future. The essential properties of the matter models chosen are that their energy-momentum tensors satisfy certain inequalities and that they do not develop singularities in a given regular background spacetime.Comment: 19 page