Substrate Adhesion of a Nongrafted Flexible Polymer in a Cavity

In a contact density chain-growth study we investigate the solubility-temperature pseudo-phase diagram of a lattice polymer in a cavity with an attractive surface. In addition to the main phases of adsorbed and desorbed conformations we find numerous subphases of collapsed and expanded structures.Comment: 20 pages, 6 figure

Bankrupting terrorism: the role of US anti-terrorism litigation in the prevention of terrorism and other hybrid threats: a legal assessment and outlook

Global terrorist networks are dependent on receiving financial support from a variety of sources, including individuals, charities and corporations. Also known as terrorist financing, the potential of terrorism finance to resemble a global threat has been recognised and also its closeness to other international crimes such as money laundering and organized crime. As a result, possible responses have to constitute co-ordinated, multi-lateral and multi faceted actions under the umbrella of a wide range of international stakeholders such as the United Nations Security Council and the Financial Action Task Force. Combating terrorism requires a ‘holistic’ approach which allows for a mix of possible responses. Besides “kinetic” security operations (such as targeted killings) and the adoption of criminal prosecution measures another possible response could be the use of US styled transnational civil litigation by victims of terrorism against both, terrorist groups and their sponsors. Corporations, both profit and non profit, such as banks and other legal entities, as well as individuals, are often complicit in international terrorism in a role of aiders and abettors by providing financial assistance to the perpetrators (cf. UN Al-Qaida Sanctions List: The List established and maintained by the 1267 Committee with respect to individuals, groups, undertakings and other entities associated with Al-Qaida). Such collusion in acts of terrorism gains additional importance against the background of so called “Hybrid Threats”, NATO’s new concept of identifying and countering new threats arising from multi-level threat scenarios. This article discusses the potential impact of US terrorism lawsuits for the global fight against terrorism

Influence of weathering and pre-existing large scale fractures on gravitational slope failure: insights from 3-D physical modelling

Using a new 3-D physical modelling technique we investigated the initiation and evolution of large scale landslides in presence of pre-existing large scale fractures and taking into account the slope material weakening due to the alteration/weathering. The modelling technique is based on the specially developed properly scaled analogue materials, as well as on the original vertical accelerator device enabling increases in the 'gravity acceleration' up to a factor 50. The weathering primarily affects the uppermost layers through the water circulation. We simulated the effect of this process by making models of two parts. The shallower one represents the zone subject to homogeneous weathering and is made of low strength material of compressive strength &sigma;_l. The deeper (core) part of the model is stronger and simulates intact rocks. Deformation of such a model subjected to the gravity force occurred only in its upper (low strength) layer. In another set of experiments, low strength (<i>&sigma;_w</i>) narrow planar zones sub-parallel to the slope surface (<i>&sigma;_w<&sigma;_l</i>) were introduced into the model's superficial low strength layer to simulate localized highly weathered zones. In this configuration landslides were initiated much easier (at lower 'gravity force'), were shallower and had smaller horizontal size largely defined by the weak zone size. Pre-existing fractures were introduced into the model by cutting it along a given plan. They have proved to be of small influence on the slope stability, except when they were associated to highly weathered zones. In this latter case the fractures laterally limited the slides. Deep seated rockslides initiation is thus directly defined by the mechanical structure of the hillslope's uppermost levels and especially by the presence of the weak zones due to the weathering. The large scale fractures play a more passive role and can only influence the shape and the volume of the sliding units

Locally triggered seismicity in the central Swiss Alps following the large rainfall event of August 2005

In 2005 August, an unusual series of 47 earthquakes occurred over a 12-hr period in central Switzerland. The earthquakes occurred at the end of 3-d period of intensive rainfall, with over 300 mm of precipitation. The highest seismicity occurred as two distinct clusters in the region of Muotatal and Riemenstalden, Switzerland, a well-known Karst area that received a particularly large amount of rainfall. The large increase in seismicity, compared to the background, and the short time delay between the onset of the intense rainfall and the seismicity strongly suggest that earthquakes were triggered by rainfall. In our preferred model, an increase in fluid pressure at the surface due to a large amount of rain leads to a local increase in pore fluid pressure at depth. The increase in pore fluid pressure will reduce the shear strength of a porous medium by counteracting normal stress and, at the end, provoke failure. The series of triggered earthquakes in central Switzerland occurred in regions that have been seismically active in the past, showing similar hypocentre locations and magnitudes. This suggests that these earthquakes occurred on existing faults that were critically stressed. We modelled the intense rainfall as a step increase in fluid pressure at the surface that migrates to greater depths following the solution of the one-dimensional diffusion equation in a homogeneous half space. This allowed us to estimate the hydraulic diffusivity by plotting triggered seismicity in a time-depth plot. We found values of hydraulic diffusivity in the range from 0.01 to 0.5 m2 s−1 for our study area. These values are in good agreement with previous studies on earthquakes that were triggered by fluids, supporting the idea that the observed earthquake series was triggered by the large amount of rainfal

Just war and military morale: a brief reflection on the correlation between the legality of war and the moral repercussions for members of US and UK forces arising from the questionable legality of the campaign Iraqi Freedom of March 2003

Does it matter to a member of the military whether the military campaign in which he is taking part is lawful or not? Despite the observation that the crime of aggression (post Kampala 2010) constitutes a ‘leadership crime par excellence,’ which limits any (future) criminal responsibility accordingly, the legality or illegality of any military action under international law can create moral implications for the common foot soldier and mid-level officer and also have a tangible impact on the national legal frameworks under which these forces operate. This short article uses the example of Operation Iraqi Freedom (2003) to discuss the repercussions of a—most likely—illegal military campaign for individual members of democratic armed forces before the background of the present discussion of NATO led action in Libya

Conformational Mechanics of Polymer Adsorption Transitions at Attractive Substrates

Conformational phases of a semiflexible off-lattice homopolymer model near an attractive substrate are investigated by means of multicanonical computer simulations. In our polymer-substrate model, nonbonded pairs of monomers as well as monomers and the substrate interact via attractive van der Waals forces. To characterize conformational phases of this hybrid system, we analyze thermal fluctuations of energetic and structural quantities, as well as adequate docking parameters. Introducing a solvent parameter related to the strength of the surface attraction, we construct and discuss the solubility-temperature phase diagram. Apart from the main phases of adsorbed and desorbed conformations, we identify several other phase transitions such as the freezing transition between energy-dominated crystalline low-temperature structures and globular entropy-dominated conformations.Comment: 13 pages, 15 figure

NESTMOD: The NetMod-NEST Interface

NESTMOD is a combined analytical modeling and simulation tool, based on the existing tools NetMod and NEST. It provides both transient and steady-state response statistics from models of interconnected local area networks that can execute at any level of detail desired. This gives users the potential to model both networks of extremely large scope (hundreds of thousands of nodes), and to look at great detail for any combination of the ISO layers. This paper describes the interface implementation, and presents an example to illustrate the potential power of the tool.http://deepblue.lib.umich.edu/bitstream/2027.42/107970/1/citi-tr-91-7.pd

Economic inequalities in burden of illness, diagnosis and treatment of five long-term conditions in England: panel study

We compared the distribution by wealth of self-reported illness burden (estimated from validated scales, biomarker and reported symptoms) for angina, cataract, depression, diabetes and osteoarthritis, with the distribution of self-reported medical diagnosis and treatment. We aimed to determine if the greater illness burden borne by poorer participants was matched by appropriately higher levels of diagnosis and treatment

La santé en Suisse : le point sur les maladies chroniques : rapport national sur la santé 2015

Le vieillissement de la population va de pair avec une progression constante des maladies chroniques dans notre société. Les modes de vie modernes favorisent l'apparition de ces maladies, notamment par le tabagisme, par le manque d'activité physique et par une alimentation déséquilibrée. Les maladies chroniques somatiques sont aujourd'hui dans la ligne de mire des responsables de la politique de la santé. Elles constituent, avec les maladies chroniques psychiques, dont les conséquences sont multiples, un défi de taille pour notre système de santé et un problème majeur de santé publique. La prise en charge des maladies chroniques requiert une bonne coordination du système de santé. La Confédération et les cantons y travaillent activement en s'engageant par exemple dans le domaine du personnel de santé et de l'organisation des structures de soins. Confédération et cantons contribuent à faire en sorte que les maladies chroniques psychiques ou somatiques deviennent moins fréquentes ou soient traitées suffisamment tôt. Tels sont les objectifs des politiques de promotion de la santé et de prévention des maladies, dont l'importance ira croissant à l'avenir. Le présent rapport national sur la santé donne une vue d'ensemble de la santé dans la population suisse; il met en lumière certains aspects importants des maladies chroniques dans notre pays. Puisse-t-il donner des impulsions nouvelles et aider les acteurs du système suisse de santé à maîtriser ensemble les défis liés à ces maladies

Mid-infrared sub-wavelength grating mirror design: tolerance and influence of technological constraints

High polarization selective Si/SiO2 mid-infrared sub-wavelength grating mirrors with large bandwidth adapted to VCSEL integration are compared. These mirrors have been automatically designed for operation at \lambda = 2.3 $\mu$m by an optimization algorithm which maximizes a specially defined quality factor. Several technological constraints in relation with the grating manufacturing process have been imposed within the optimization algorithm and their impact on the optical properties of the mirror have been evaluated. Furthermore, through the tolerance computation of the different dimensions of the structure, the robustness with respect to fabrication errors has been tested. Finally, it appears that the increase of the optical performances of the mirror imposes a less tolerant design with severer technological constraints resulting in a more stringent control of the manufacturing process.Comment: The final publication is available at http://iopscience.iop.org/2040-8986/13/12/125502