Evidence for suppressed mid-Holocene northeastern Australian monsoon variability from coral luminescence

Summer monsoon rainfall in northeastern (NE) Australia exhibits substantial interannual variability resulting in highly variable river flows. The occurrence and magnitude of these seasonal river flows are reliably recorded in modern inshore corals as luminescent lines. Here we present reconstructed annual river flows for two ~120 year mid-Holocene windows based on luminescence measurements from five cores obtained from three separate coral colonies. We were able to cross-date the luminescence signatures in four cores from two of the colonies, providing confidence in the derived reconstruction. Present-day NE Australian rainfall and river flow are sensitive to El Niño–Southern Oscillation (ENSO) variability, with La Niña (El Niño) events typically associated with wetter (drier) monsoon seasons. Thus, our replicated and annually resolved coral records provide valuable insights into the northern Australian summer monsoon and ENSO variability at a key period (6 ka) when greenhouse gas levels and ice sheet cover were comparable to the preindustrial period but orbital forcing was different. Average modern and mid-Holocene growth characteristics were very similar, suggesting that sea surface temperatures off NE Australia at 6 kyr were also close to present values. The reconstructed river flow record suggests, however, that the mid-Holocene Australian summer monsoon was weaker, less variable from year to year (possibly indicative of reduced ENSO variability), and characterized by more within-season flood pulses than present. In contrast to today, the delivery of moisture appears to have been dominated by eastward propagating convective coupled waves associated with the Madden-Julian Oscillation

Solar decathlon : Show-Me solar team

Project Leaders: Barbara Buffaloe, Katie-Grantham-Lough, Michael Goldschmidt, Robert Stone, Luke Sudkamp, Paul Bilger, Anna Fleischer, Chris Krueger, Heather Benson, Anne Felts, Adam Smith, Renee Henry, Ben Brannon, Ruth Brent Tofle, Jo Britt-Rankin, Marjorie Sable"University of Missouri--Columbia (MU) and the Missouri University of Science & Technology (S&T) have composed the "Show-Me Solar Team." This team is composed of undergraduate and graduate students with a goal to design and build the most attractive, effective, and energy-efficient solar-powered house for the 2009 Solar Decathlon. The Solar Decathlon, an international design competition, exists to educate the public on solar energy, energy efficiency, and the best in home design. While this effort is well over the budget available for the current funding opportunity, we have selected certain components for submission in this application. Specifically, this effort includes architecture, interior design, architectural engineering, electrical engineering, civil engineering, history, and business disciplines across two campuses in a unique experience for all involved and utilizes technology and IT communications to make it happen. Most of the components of the project are done through computer and the virtual world. The students must rely on the ability to communicate via the internet for most decisions because only occasional face-to-face meetings take place. In addition, students on both campuses utilize computer programs related to their discipline and learn programs associated with other disciplines due to the multidisciplinary efforts required. For example, MU students often use Google Sketch?up to convey the architectural elements of the home. S&T students, new to Google Sketch-up, have found that with a tutorial by MU that they can better understand the dialogue going on between the teams on the design. We believe that the Show-Me Solar team�s proposal for the Interdisciplinary Innovation Fund meets the requirements from the MU Information Technology Committee. The student-led team is working hard to make the University of Missouri system a leader in the next wave of home design through the use of innovative technology and strong relationships between disciplines. We look forward to working with the MUITC and hope that our combined effort will continue to foster interdisciplinary projects throughout the UM system. Please let us know if any further clarification is needed." --DescriptionMU Interdisciplinary Innovations Fun

Enantioselective Hydrogenation of Activated Aryl Imines Catalyzed by an Iron(II) P-NH-P′ Complex

International audienceChiral amines are key building blocks in synthetic chemistry with numerous applications in the agricultural and pharmaceutical industries. Asymmetric imine hydrogenation, particularly with iridium catalysts, is well developed. However, imine reduction still remains challenging in the context of replacing such a precious metal with a cheap, nontoxic, and environmentally friendly substitute such as iron. Here, we report that an unsymmetrical iron P-NH-P′ catalyst that was previously shown to be effective for the asymmetric hydrogenation of aryl ketones is also a very effective catalyst for the asymmetric hydrogenation of prochiral aryl imines activated with N-diphenylphosphinoyl or N-tosyl groups. The P-NH-P′ abbreviation stands for (S,S)-PPh2CHPhCHPhNHCH2CH2PiPr2. Density functional theory results suggest that, surprisingly, the NH group on the catalyst activates and orients the imine to hydride attack by hydrogen bonding to the PO or SO group on the imine nitrogen, as opposed to the imine nitrogen itself. This may explain why N-Ph and N-Bu imines are not hydrogenated

Drought Variability in the Eastern Australia and New Zealand Summer Drought Atlas (ANZDA, CE 1500-2012) Modulated by the Interdecadal Pacific Oscillation

Agricultural production across eastern Australia and New Zealand is highly vulnerable to drought, but there is a dearth of observational drought information prior to CE (Christian Era) 1850. Using a comprehensive network of 176 drought-sensitive tree-ring chronologies and one coral series, we report the first Southern Hemisphere gridded drought atlas extending back to CE 1500. The austral summer (December-February) Palmer drought sensitivity index reconstruction accurately reproduces historically documented drought events associated with the first European settlement of Australia in CE 1788, and the leading principal component explains over 50 percent of the underlying variance. This leading mode of variability is strongly related to the Interdecadal Pacific Oscillation tripole index (IPO), with a strong and robust antiphase correlation between (1) eastern Australia and the New Zealand North Island and (2) the South Island. Reported positive, negative, and neutral phases of the IPO are consistently reconstructed by the drought atlas although the relationship since CE 1976 appears to have weakened

Reply to Comment on 'Drought Variability in the Eastern Australia and New Zealand Summer Drought Atlas (ANZDA, CE 1500-2012) Modulated by the Interdecadal Pacific Oscillation'

This reply is in response to Vance et al (2017), who expressed concern that their Law Dome summer sea salt record (LDsss; Vance et al 2013) and two Interdecadal Pacific Oscillation (IPO) reconstructions (PLF and DT-median; Vance et al 2015) were not compared properly in our recent study (Palmer et al 2015) describing the eastern Australian and New Zealand summer Drought Atlas (ANZDA) and that this omission mischaracterizes their records

Effects of climate change on oceanic fisheries in the tropical Pacific: implications for economic development and food security

The four species of tuna that underpin oceanic fisheries in the tropical Pacific (skipjack, yellowfin, bigeye and albacore tuna) deliver great economic and social benefits to Pacific Island countries and territories (PICTs). Domestic tuna fleets and local fish processing operations contribute 3–20 % to gross domestic product in four PICTs and licence fees from foreign fleets provide an average of 3–40 % of government revenue for seven PICTs. More than 12,000 people are employed in tuna processing facilities and on tuna fishing vessels. Fish is a cornerstone of food security for many PICTs and provides 50–90 % of dietary animal protein in rural areas. Several PICTs have plans to (1) increase the benefits they receive from oceanic fisheries by increasing the amount of tuna processed locally, and (2) allocate more tuna for the food security of their rapidly growing populations. The projected effects of climate change on the distribution of tuna in the tropical Pacific Ocean, due to increases in sea surface temperature, changes in velocity of major currents and decreases in nutrient supply to the photic zone from greater stratification, are likely to affect these plans. PICTs in the east of the region with a high dependence on licence fees for government revenue are expected to receive more revenue as tuna catches increase in their exclusive economic zones. On the other hand, countries in the west may encounter problems securing enough fish for their canneries as tuna are redistributed progressively to the east. Changes in the distribution of tuna will also affect the proportions of national tuna catches required for food security. We present priority adaptations to reduce the threats to oceanic fisheries posed by climate change and to capitalise on opportunities

The Kuleshov Effect: the influence of contextual framing on emotional attributions

Filmmakers have long recognized the importance of editing techniques to guide the audiences' perceptions and enhance the impact of a scene. We demonstrate behaviorally that pairing identical faces with either neutral or emotionally salient contextual movies, an editing technique referred to as the ‘Kuleshov Effect’, results in both altered attributions of facial expression and mental-state. Using functional neuroimaging (fMRI), we show that faces paired with emotional movies enhance BOLD responses in the bilateral temporal pole, anterior cingulate cortices, amygdala and bilateral superior temporal sulcus relative to identical faces juxtaposed with neutral movies. An interaction was observed in the right amygdala when subtle happy and fear faces were juxtaposed with positive and negative movies, respectively. An interaction between happy faces and negative context was also observed in bilateral amygdala suggesting that the amygdala may act to prime or tag affective value to faces. A parametric modulation of BOLD signal by attribution ratings indicated a dissociation between ventrolateral and the ventromedial prefrontal cortex for negative and positive contextually evoked attributions, respectively. These prefrontal regions may act to guide appropriate choices across altering contexts. Together, these findings offer a neurobiological basis for contextual framing effects on social attributions