Organic Solar Cells: Problems and Perspectives

For photovoltaic cells to convert solar into electric energy is probably the most interesting research challenge nowadays. A good efficiency of these devices has been obtained by using inorganic semiconductor materials. On the other hand, manufacture processes are very expensive in terms of both materials and techniques. For this reason organic-based photovoltaic (OPV) cells are attracting the general attention because of the possible realization of more economical devices. Organic materials are abundant and easily handling. Unfortunately OPV cells efficiency is significantly lower than that of inorganic-based devices, representing a big point of weakness at the present. This is mainly due to the fact that organic semiconductors have a much higher band gap with respect to inorganic semiconductors. In addition, OPV cells are very susceptible to oxygen and water. In this paper we will describe some of the different approaches to the understanding and improving of organic photovoltaic devices

Mean Antarctic Circumpolar Current Transport Measured in Drake Passage

The Antarctic Circumpolar Current is an important component of the global climate system connecting the major ocean basins as it flows eastward around Antarctica, yet due to the paucity of data it remains unclear how much water is transported by the current. Between 2007 and 2011 flow through Drake Passage was continuously monitored with a line of moored instrumentation with unprecedented horizontal and temporal resolution. Annual mean near-bottom currents are remarkably stable from year to year. The mean depth-independent, or barotropic transport, determined from the near-bottom current meter records was 45.6 Sv with an uncertainty of 8.9 Sv. Summing the mean barotropic transport with the mean baroclinic transport relative to zero at the seafloor of 127.7 Sv gives a total transport through Drake Passage of 173.3 Sv. This new measurement is 30% larger than the canonical value often used as the benchmark for global circulation and climate models.Fil: Donohue, K. A.. University Of Rhode Island; Estados UnidosFil: Tracey, K. L.. University Of Rhode Island; Estados UnidosFil: Watts, D. R.. University Of Rhode Island; Estados UnidosFil: Chidichimo, María Paz. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Ministerio de Defensa. Armada Argentina. Servicio de Hidrografía Naval; Argentina. Universidad de Buenos Aires; ArgentinaFil: Chereskin, T. K.. University of California at San Diego. Scripps Institution of Oceanography; Estados Unido

Comunidades fúngicas asociadas a la descomposición del rastrojo en monocultivo y distintos sistemas de labranza

Los microorganismos del suelo son fundamentales en la degradación enzimática de restos vegetales y su reciclado desde la fracción mineral del suelo. Su actividad depende del desarrollo del cultivo, el tipo y manejo del suelo y el macro y microclima del lugar .Los hongos celulolíticos son uno de los principales grupos involucrados en la degradación del rastrojo. El conocimiento de la tasa de descomposición de los residuos es fundamental para planificar su adecuado uso. El objetivo del presente trabajo fue cuantificar e identificar la población fúngica asociada a la degradación del rastrojo de trigo, bajo monocultivo, dos sistemas de labranza y dos dosis de fertilizante

Brazil Current volume transport variability during 2009-2015 from a longterm moored array at 34.5°S

The Brazil Current, the western limb of the subtropical gyre of the South Atlantic Ocean, is one of the major Western Boundary Currents of the global ocean. Here, we present the first multiyear continuous daily time series of Brazil Current absolute volume transport obtained using 6+ years of observations from a line of four pressure-recording inverted echo sounders (PIES) deployed at 34.5°S. The array was augmented in December 2012 with two current meter-equipped PIES and in December 2013 with a moored Acoustic Doppler Current Profiler on the upper continental slope. The Brazil Current is bounded by the sea surface and the neutral density interface separating South Atlantic Central Water and Antarctic Intermediate Water, which is on average at a reference pressure of 628 ± 46 dbar, and it is confined west of 49.5°W. The Brazil Current has a mean strength of −14.0 ± 2.8 Sv (1 Sv ≡ 106 m3 s−1; negative indicates southward flow) with a temporal standard deviation of 8.8 Sv and peak-to-peak range from −41.7 to +20 Sv. About 80% of the absolute transport variance is concentrated at periods shorter than 150 days with a prominent peak at 100 days. The baroclinic component accounts for 85% of the absolute transport variance, but the barotropic variance is not negligible. The baroclinic and barotropic transports are uncorrelated, demonstrating the need to measure both transport components independently. Given the energetic high frequency transport variations, statistically significant seasonal to interannual variability and trends have yet to be detected.Fil: Chidichimo, María Paz. Ministerio de Defensa. Armada Argentina. Servicio de Hidrografía Naval. Departamento Oceanografía; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Instituto Franco-Argentino sobre Estudios del Clima y sus Impactos; Argentina. Centre National de la Recherche Scientifique. Institut de Recherche pour le Developpement. Département Ecologie, Biodiversité et Fonctionnement des Ecosystèmes Continentaux; FranciaFil: Piola, Alberto Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Ministerio de Defensa. Armada Argentina. Servicio de Hidrografía Naval; Argentina. Instituto Franco-Argentino sobre Estudios del Clima y sus Impactos; Argentina. Centre National de la Recherche Scientifique. Institut de Recherche pour le Developpement. Département Ecologie, Biodiversité et Fonctionnement des Ecosystèmes Continentaux; FranciaFil: Meinen, Christopher S.. Ministerio de Defensa. Armada Argentina. Servicio de Hidrografía Naval. Departamento Oceanografía; Argentina. National Ocean And Atmospheric Administration; Estados UnidosFil: Perez, Renellys. National Ocean And Atmospheric Administration; Estados UnidosFil: Campos, Edmo. Universidade de Sao Paulo; Brasil. American University Of Sharjah.; Emiratos Árabes UnidosFil: Dong, Shenfu. National Ocean And Atmospheric Administration; Estados UnidosFil: Lumpkin, Rick. National Ocean And Atmospheric Administration; Estados UnidosFil: Garzoli, S. L.. National Ocean And Atmospheric Administration; Estados Unido

Mineralización de los residuos de trigo provenientes de distintos sistemas de labranza: efecto sobre la pérdida de peso y dinámica del nitrógeno

En siembra directa y monocultivo los patógenos necrótrofos son más severos, porque aumentan el período de supervivencia sobre los rastrojos retenidos en el suelo. La descomposición de los residuos de cosecha depende de factores edáficos (temperatura, humedad y disponibilidad de nutrientes), químicos del rastrojo (concentración de N o la relación C/N, contenidos de lignina y carbohidratos solubles) y factores de manejo, (cantidad de rastrojo, tamaño de sus partículas (descomposición dentro o sobre el suelo) El objetivo fue investigar la pérdida de peso del rastrojo según los contenidos iniciales de nitrógeno en el suelo, trazando su dinámica

A combined optical/infrared spectral diagnostic analysis of the HH1 jet

Complete flux-calibrated spectra covering the spectral range from 6000 A to 2.5 um have been obtained along the HH1 jet and analysed in order to explore the potential of a combined optical/near-IR diagnostic applied to jets from young stellar objects. Important physical parameters have been derived along the jet using various diagnostic line ratios. This multi-line analysis shows, in each spatially unresolved knot, the presence of zones at different excitation conditions, as expected from the cooling layers behind a shock front. In particular, a density stratification in the jet is evident from ratios of various lines of different critical density. In particular, [FeII] lines originate in a cooling layer located at larger distances from the shock front than that generating the optical lines, where the compression is higher and the temperature is declining. The derived parameters were used to measure the mass flux along the jet, adopting different procedures, the advantages and limitations of which are discussed. dM/dt is high in the initial part of the flow but decreases by about an order of magnitude further out. Conversely, the mass flux associated with the warm molecular material is low and does not show appreciable variations along the jet. We suggest that part of the mass flux in the external regions is not revealed in optical and IR lines because it is associated with a colder atomic component, which may be traced by the far-IR [O I]63 um line. Finally, we find that the gas-phase abundance of refractory species is lower than the solar value suggesting that a significant fraction of dust grains may still be present in the jet beam.Comment: Accepted on Astronomy & Astrophysic

Recipes for stellar jets: results of combined optical/infrared diagnostics

We examine the conditions of the plasma along a sample of 'classical' Herbig-Haro jets located in the Orion and Vela star forming regions, through combined optical-infrared spectral diagnostics. Our sample includes HH 111, HH 34, HH 83, HH 73, HH 24 C/E, HH 24 J, observed at moderate spatial/spectral resolution. The obtained spectra cover a wide wavelength range from 0.6-2.5 um, including many transitions from regions of different excitation conditions. This allows us to probe the density and temperature stratification which characterises the cooling zones behind the shock fronts along the jet. The derived physical parameters (such as the extinction, the electron density and temperature, the ionisation fraction, and the total density) are used to estimate the depletion onto dust grains of Calcium and Iron with respect to solar abundances. This turns out to be between 70% and 0% for Ca and ~90% for Fe, suggesting that the weak shocks present in the beams are not capable of completely destroying the dust grains. We then derive the mass flux rates (Mdot_jet is on average 5 10^-8 M_solar yr^-1) and the associated linear momentum fluxes. The latter are higher than, or of the same order as, those measured in the coaxial molecular flows, suggesting that the flows are jet driven. Finally, we discuss differences between jets in our sample.Comment: 19 pages, 15 figures, accepted by A&

Highly variable upper and abyssal overturning cells in the South Atlantic

The Meridional Overturning Circulation (MOC) is a primary mechanism driving oceanic heat redistribution on Earth, thereby affecting Earth’s climate and weather. However, the full-depth structure and variability of the MOC are still poorly understood, particularly in the South Atlantic. This study presents unique multiyear records of the oceanic volume transport of both the upper (~3100 meters) overturning cells based on daily moored measurements in the South Atlantic at 34.5°S. The vertical structure of the time-mean flows is consistent with the limited historical observations. Both the upper and abyssal cells exhibit a high degree of variability relative to the temporal means at time scales, ranging from a few days to a few weeks. Observed variations in the abyssal flow appear to be largely independent of the flow in the overlying upper cell. No meaningful trends are detected in either cell.Fil: Kersalé, Marion. National Ocean And Atmospheric Administration; Estados Unidos. University of Miami; Estados UnidosFil: Meinen, Christopher S.. National Ocean And Atmospheric Administration; Estados UnidosFil: Perez, Renellys C.. National Ocean And Atmospheric Administration; Estados UnidosFil: Le Hénaff, Matthieu. National Ocean And Atmospheric Administration; Estados Unidos. University of Miami; Estados UnidosFil: Valla, Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Ministerio de Defensa. Armada Argentina. Servicio de Hidrografía Naval. Departamento Oceanografía; ArgentinaFil: Lamont, Tarron. University of Cape Town; SudáfricaFil: Sato, Olga T.. Universidade de Sao Paulo; BrasilFil: Dong, Shenfu. National Ocean And Atmospheric Administration; Estados UnidosFil: Terre, T.. University of Brest; Francia. Centre National de la Recherche Scientifique; FranciaFil: van Caspel, M.. Universidade de Sao Paulo; BrasilFil: Chidichimo, María Paz. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Ministerio de Defensa. Armada Argentina. Servicio de Hidrografía Naval. Departamento Oceanografía; ArgentinaFil: van den Berg, Marcel Alexander. Department of Environmental Affairs; SudáfricaFil: Speich, Sabrina. University Of Cape Town; SudáfricaFil: Piola, Alberto Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Ecole Normale Superieure. Laboratoire de Meteorologie Dynamique; Francia. Ministerio de Defensa. Armada Argentina. Servicio de Hidrografía Naval. Departamento Oceanografía; Argentina. Instituto Franco-Argentino sobre Estudios del Clima y sus Impactos; Argentina. Universidad de Buenos Aires; ArgentinaFil: Campos, Edmo. Universidade de Sao Paulo; Brasil. American University Of Sharjah.; Emiratos Árabes UnidosFil: Ansorge, Isabelle. University of Cape Town; SudáfricaFil: Volkov, Denis L.. University of Miami; Estados Unidos. National Ocean And Atmospheric Administration; Estados UnidosFil: Lumpkin, Rick. National Ocean And Atmospheric Administration; Estados UnidosFil: Garzoli, S. L.. University of Miami; Estados Unidos. National Ocean And Atmospheric Administration; Estados Unido

CHIANTI - an Atomic Database for Emission Lines. Paper VI: Proton Rates and Other Improvements

The CHIANTI atomic database contains atomic energy levels, wavelengths, radiative transition probabilities and electron excitation data for a large number of ions of astrophysical interest. Version 4 has been released, and proton excitation data is now included, principally for ground configuration levels that are close in energy. The fitting procedure for excitation data, both electrons and protons, has been extended to allow 9 point spline fits in addition to the previous 5 point spline fits. This allows higher quality fits to data from close-coupling calculations where resonances can lead to significant structure in the Maxwellian-averaged collision strengths. The effects of photoexcitation and stimulated emission by a blackbody radiation field in a spherical geometry on the level balance equations of the CHIANTI ions can now be studied following modifications to the CHIANTI software. With the addition of H I, He I and N I, the first neutral species have been added to CHIANTI. Many updates to existing ion data-sets are described, while several new ions have been added to the database, including Ar IV, Fe VI and Ni XXI. The two-photon continuum is now included in the spectral synthesis routines, and a new code for calculating the relativistic free-free continuum has been added. The treatment of the free-bound continuum has also been updated.Comment: CHIANTI is available at http://wwwsolar.nrl.navy.mil/chianti.htm

Baroclinic Transport Time Series of the Antarctic Circumpolar Current Measured in Drake Passage

The first multiyear continuous time series of Antarctic Circumpolar Current (ACC) baroclinic transport through Drake Passage measured by moored observations is presented. From 2007 to 2011, 19 current- and pressure-recording inverted echo sounders and 3 current-meter moorings were deployed in Drake Passage to monitor the transport during the cDrake experiment. Full-depth ACC baroclinic transport relative to the bottom has a mean strength of 127.7 ± 1.0 Sverdrups (Sv; 1 Sv ≡ 106 m3 s−1) with a standard deviation of 8.1 Sv. Mean annual baroclinic transport is remarkably steady. About 65% of the baroclinic transport variance is associated with time periods shorter than 60 days with peaks at 20 and 55 days. Nearly 28% of apparent energy in the spectrum computed from transport subsampled at the 10-day repeat cycle of the Jason altimeter results from aliasing of high-frequency signals. Approximately 80% of the total baroclinic transport is carried by the Subantarctic Front and the Polar Front. Partitioning the baroclinic transport among neutral density γn layers gives 39.2 Sv for Subantarctic Surface Water and Antarctic Intermediate Water (γn \u3c 27.5 kg m−3), 57.5 Sv for Upper Circumpolar Deep Water (27.5 \u3c γn \u3c 28.0 kg m−3), 27.7 Sv for Lower Circumpolar Deep Water (28.0 \u3c γn \u3c 28.2 kg m−3), and 3.3 Sv for Antarctic Bottom Water (γn \u3e 28.2 kg m−3). The transport standard deviation in these layers decreases with depth (4.0, 3.1, 2.1, and 1.1 Sv, respectively). The transport associated with each of these water masses is statistically steady. The ACC baroclinic transport exhibits considerable variability and is a major contributor to total ACC transport variability