The Thermal Evolution of Ices in the Environments of Newly Formed Stars: The CO_2 Diagnostic

Archival data from the Infrared Spectrometer of the Spitzer Space Telescope are used to study the 15 μm absorption feature of solid CO_2 toward 28 young stellar objects (YSOs) of approximately solar mass. Fits to the absorption profile using laboratory spectra enable categorization according to the degree of thermal processing of the ice matrix that contains the CO_2. The majority of YSOs in our sample (20 out of 28) are found to be consistent with a combination of polar (H_2O-rich) and nonpolar (CO-rich) ices at low temperature; the remainder exhibit profile structure consistent with partial crystallization as the result of significant heating. Ice-phase column densities of CO_2 are determined and compared with those of other species. Lines of sight with crystallization signatures in their spectra are found to be systematically deficient in solid-phase CO, as expected if CO is being sublimated in regions where the ices are heated to crystallization temperatures. Significant variation is found in the CO2 abundance with respect to both H_2O (the dominant ice constituent) and total dust column (quantified by the extinction, AV ). YSOs in our sample display typically higher CO_2 concentrations (independent of evidence for thermal processing) in comparison to quiescent regions of the prototypical cold molecular cloud. This suggests that enhanced CO_2 production is driven by photochemical reactions in proximity to some YSOs, and that photoprocessing and thermal processing may occur independently

Ice and Dust in the Quiescent Medium of Isolated Dense Cores

The relation between ices in the envelopes and disks surrounding YSOs and those in the quiescent interstellar medium is investigated. For a sample of 31 stars behind isolated dense cores, ground-based and Spitzer spectra and photometry in the 1-25 um wavelength range are combined. The baseline for the broad and overlapping ice features is modeled, using calculated spectra of giants, H2O ice and silicates. The adopted extinction curve is derived empirically. Its high resolution allows for the separation of continuum and feature extinction. The extinction between 13-25 um is ~50% relative to that at 2.2 um. The strengths of the 6.0 and 6.85 um absorption bands are in line with those of YSOs. Thus, their carriers, which, besides H2O and CH3OH, may include NH4+, HCOOH, H2CO and NH3, are readily formed in the dense core phase, before stars form. The 3.53 um C-H stretching mode of solid CH3OH was discovered. The CH3OH/H2O abundance ratios of 5-12% are larger than upper limits in the Taurus molecular cloud. The initial ice composition, before star formation occurs, therefore depends on the environment. Signs of thermal and energetic processing that were found toward some YSOs are absent in the ices toward background stars. Finally, the peak optical depth of the 9.7 um band of silicates relative to the continuum extinction at 2.2 um is significantly shallower than in the diffuse interstellar medium. This extends the results of Chiar et al. (2007) to a larger sample and higher extinctions.Comment: Accepted for publication in The Astrophysical Journa

Ices in the Quiescent IC 5146 Dense Cloud

This paper presents spectra in the 2 to 20 micron range of quiescent cloud material located in the IC 5146 cloud complex. The spectra were obtained with NASA's Infrared Telescope Facility (IRTF) SpeX instrument and the Spitzer Space Telescope's Infrared Spectrometer. We use these spectra to investigate dust and ice absorption features in pristine regions of the cloud that are unaltered by embedded stars. We find that the H2O-ice threshold extinction is 4.03+/-0.05 mag. Once foreground extinction is taken into account, however, the threshold drops to 3.2 mag, equivalent to that found for the Taurus dark cloud, generally assumed to be the touchstone quiescent cloud against which all other dense cloud and embedded young stellar object observations are compared. Substructure in the trough of the silicate band for two sources is attributed to CH3OH and NH3 in the ices, present at the ~2% and ~5% levels, respectively, relative to H2O-ice. The correlation of the silicate feature with the E(J-K) color excess is found to follow a much shallower slope relative to lines of sight that probe diffuse clouds, supporting the previous results by Chiar et al. (2007).Comment: 13 pages, 13 figures with multiple parts, accepted for publication in Astrophysical Journal, Feb. 201

Desorption of CO and O2 interstellar ice analogs

Solid O2 has been proposed as a possible reservoir for oxygen in dense clouds through freeze-out processes. The aim of this work is to characterize quantitatively the physical processes that are involved in the desorption kinetics of CO-O2 ices by interpreting laboratory temperature programmed desorption (TPD) data. This information is used to simulate the behavior of CO-O2 ices under astrophysical conditions. The TPD spectra have been recorded under ultra high vacuum conditions for pure, layered and mixed morphologies for different thicknesses, temperatures and mixing ratios. An empirical kinetic model is used to interpret the results and to provide input parameters for astrophysical models. Binding energies are determined for different ice morphologies. Independent of the ice morphology, the desorption of O2 is found to follow 0th-order kinetics. Binding energies and temperature-dependent sticking probabilities for CO-CO, O2-O2 and CO-O2 are determined. O2 is slightly less volatile than CO, with binding energies of 912+-15 versus 858+-15 K for pure ices. In mixed and layered ices, CO does not co-desorb with O2 but its binding energies are slightly increased compared with pure ice whereas those for O2 are slightly decreased. Lower limits to the sticking probabilities of CO and O2 are 0.9 and 0.85, respectively, at temperatures below 20K. The balance between accretion and desorption is studied for O2 and CO in astrophysically relevant scenarios. Only minor differences are found between the two species, i.e., both desorb between 16 and 18K in typical environments around young stars. Thus, clouds with significant abundances of gaseous CO are unlikely to have large amounts of solid O2.Comment: 8 pages + 2 pages online material, 8 figures (1 online), accepted by A&

The Relationship between the Optical Depth of the 9.7 micron Silicate Absorption Feature and Infrared Differential Extinction in Dense Clouds

We have examined the relationship between the optical depth of the 9.7 micron silicate absorption feature (tau_9.7) and the near-infrared color excess, E(J-Ks) in the Serpens, Taurus, IC 5146, Chameleon I, Barnard 59, and Barnard 68 dense clouds/cores. Our data set, based largely on Spitzer IRS spectra, spans E(J-Ks)=0.3 to 10 mag (corresponding to visual extinction between about 2 and 60 mag.). All lines of sight show the 9.7 micron silicate feature. Unlike in the diffuse ISM where a tight linear correlation between the 9.7 micron silicate feature optical depth and the extinction (Av) is observed, we find that the silicate feature in dense clouds does not show a monotonic increase with extinction. Thus, in dense clouds, tau_9.7 is not a good measure of total dust column density. With few exceptions, the measured tau_9.7 values fall well below the diffuse ISM correlation line for E(J-Ks) > 2 mag (Av >12 mag). Grain growth via coagulation is a likely cause of this effect.Comment: 11 pages including 2 figures, 1 table. Accepted for publication in ApJ Letters, 23 July 200

The 9.7 and 18 um silicate absorption profiles towards diffuse and molecular cloud lines-of-sight

Studying the composition of dust in the interstellar medium (ISM) is crucial in understanding the cycle of dust in our galaxy. The mid-infrared spectral signature of amorphous silicates, the most abundant dust species in the ISM, is studied in different lines-of-sight through the Galactic plane, thus probing different conditions in the ISM. We have analysed 10 spectra from the Spitzer archive, of which 6 lines-of-sight probe diffuse interstellar medium material and 4 probe molecular cloud material. The 9.7 um silicate absorption features in 7 of these spectra were studied in terms of their shape and strength. In addition, the shape of the 18 um silicate absorption features in 4 of the diffuse sightline spectra were analysed. The 9.7 um silicate absorption bands in the diffuse sightlines show a strikingly similar band shape. This is also the case for all but one of the 18 um silicate absorption bands observed in diffuse lines-of-sight. The 9.7 um bands in the 4 molecular sightlines show small variations in shape. These modest variations in the band shape are inconsistent with the interpretation of the large variations in {\tau}_9.7/E(J-K) between diffuse and molecular sightlines in terms of silicate grain growth. Instead, we suggest that the large changes in {\tau}_9.7 / E(J-K) must be due to changes in E(J-K).Comment: 14 pages, 19 figures, accepted for publication in A&

High-resolution SOFIA/EXES Spectroscopy of Water Absorption Lines in the Massive Young Binary W3 IRS 5

We present in this paper mid-infrared (5-8~$\mu$m) spectroscopy toward the massive young binary W3~IRS~5, using the EXES spectrometer in high-resolution mode ($R\sim$50,000) from the NASA Stratospheric Observatory for Infrared Astronomy (SOFIA). Many ($\sim$180) $\nu_2$=1--0 and ($\sim$90) $\nu_2$=2-1 absorption rovibrational transitions are identified. Two hot components over 500 K and one warm component of 190 K are identified through Gaussian fittings and rotation diagram analysis. Each component is linked to a CO component identified in the IRTF/iSHELL observations ($R$=88,100) through their kinematic and temperature characteristics. Revealed by the large scatter in the rotation diagram, opacity effects are important, and we adopt two curve-of-growth analyses, resulting in column densities of $\sim10^{19}$ cm$^{-2}$. In one analysis, the model assumes a foreground slab. The other assumes a circumstellar disk with an outward-decreasing temperature in the vertical direction. The disk model is favored because fewer geometry constraints are needed, although this model faces challenges as the internal heating source is unknown. We discuss the chemical abundances along the line of sight based on the CO-to-H$_2$O connection. In the hot gas, all oxygen not locked in CO resides in water. In the cold gas, we observe a substantial shortfall of oxygen and suggest that the potential carrier could be organics in solid ice.Comment: Accepted for publication in ApJ. 34 pages, 13 figures, and 14 tables. Comments are more than welcome

The Nature of Carbon Dioxide Bearing Ices in Quiescent Molecular Clouds

The properties of the ices that form in dense molecular clouds represent an important set of initial conditions in the evolution of interstellar and preplanetary matter in regions of active star formation. Of the various spectral features available for study, the bending mode of solid CO2 near 15 microns has proven to be a particularly sensitive probe of physical conditions, especially temperature. We present new observations of this absorption feature in the spectrum of Q21-1, a background field star located behind a dark filament in the Cocoon Nebula (IC5146). We show the profile of the feature be consistent with a two-component (polar + nonpolar) model for the ices, based on spectra of laboratory analogs with temperatures in the range 10-20K. The polar component accounts for 85% of the CO2 in the line of sight. We compare for the first time 15 micron profiles in three widely separated dark clouds (Taurus, Serpens and IC5146), and show that they are indistinguishable to within observational scatter. Systematic differences in the observed CO2/H2O ratio in the three clouds have little or no effect on the 15 micron profile. The abundance of elemental oxygen in the ices appears to be a unifying factor, displaying consistent behavior in the three clouds. We conclude that the ice formation process is robust and uniformly efficient, notwithstanding compositional variations arising from differences in how the O is distributed between the primary species (H2O, CO2 and CO) in the ices

Infrared H2O absorption in massive protostars at high spectral resolution: full spectral survey results of AFGL 2591 and AFGL 2136

Interstellar matter and star formatio