Design, characterisation and properties of Mo-Ti-Fe alloys reinforced by ordered intermetallic precipitates

Reinforcement of solid solution matrices with ordered intermetallic precipitates is known to be an effective strategy for obtaining high strength, damage tolerant alloys and has been central to the success of nickel based superalloys. This strategy has also been exploited in a number of bcc-based systems, for example in maraging steels where ferrite is strengthened by L21 (Heusler) and/or B2 structured intermetallic precipitates. However, only limited studies have explored the possibility of extending this approach to bcc alloys based on refractory metals and titanium. Recent research has shown that titanium-iron alloys comprising eutectic A2 Ti and B2 TiFe phases may be produced with strengths of over 2.5 GPa, alongside elongations to failures of ~15%. These impressive properties are thought to be a result of a fine microstructural length scale and a high lattice misfit between the phases. Here, we report on the phase equilibria in the Mo-Ti-Fe ternary system. In this system, an extensive two-phase field was identified between B2 TiFe intermetallic phase and the A2 (Ti, Mo) solid solution, that extended to Mo rich compositions. Knowledge of how this phase equilibrium varies with temperature enabled the design of alloys that could be homogenised in the single-phase solid solution and subsequently reinforced by solid state precipitates following a lower temperature heat treatment. The microstructure obtained was finer than has been produced through an invariant reaction and an initial assessment of their mechanical properties revealed substantial strength. The prospects for modifying these alloys to enable their use at higher temperatures will be discussed. This work was supported through the Rolls-Royce/EPSRC Strategic Partnership under EP/H022309/1 and EP/H500375/1, as well as the DARE project under EP/L025213/1

Atomic detail visualization of photosynthetic membranes with GPU-accelerated ray tracing

The cellular process responsible for providing energy for most life on Earth, namely, photosynthetic light-harvesting, requires the cooperation of hundreds of proteins across an organelle, involving length and time scales spanning several orders of magnitude over quantum and classical regimes. Simulation and visualization of this fundamental energy conversion process pose many unique methodological and computational challenges. We present, in two accompanying movies, light-harvesting in the photosynthetic apparatus found in purple bacteria, the so-called chromatophore. The movies are the culmination of three decades of modeling efforts, featuring the collaboration of theoretical, experimental, and computational scientists. We describe the techniques that were used to build, simulate, analyze, and visualize the structures shown in the movies, and we highlight cases where scientific needs spurred the development of new parallel algorithms that efficiently harness GPU accelerators and petascale computers

New approaches in W-gravities

We have devoted an effort to study some nonlinear actions, characteristics of the ${\cal W}$-theories, in the framework of the soldering formalism. We have disclosed interesting new results concerning the embedding of the original chiral ${\cal W}$-particles in different metrical spaces in the final soldered action, i.e., the metric gets modified by the soldering interference process. The results are presented in a weak field approximation for the ${\cal W}_N$ case when N is greater than 3 and also in an exact way for ${\cal W}_2$. We have promoted a generalization of the interference phenomena to ${\cal W}_N$-theories of different chiralities and shown that the geometrical features introduced can yield a new understanding about the interference formalism in quantum field theories.Comment: 28 pages, Late

The microstructural evolution of CM247LC manufactured through laser powder bed fusion

Numerous challenges persist with the additive manufacturing of high γ′ containing Ni-based superalloys such as CM247LC. Currently, significant cracking occurs during deposition of CM247LC components using laser powder bed fusion and during post-processing. Whilst post-deposition procedures seek to eliminate or minimise cracks, current procedures do not produce a microstructure suitable for service. This study systematically investigates the microstructural evolution of CM247LC manufactured using laser powder bed fusion following multiple post processing treatments. Phase and textural changes after each processing step were consistent with previous studies, although an additional Hf-rich and Cr-depleted segregation zone was identified along intercellular boundaries in the as-deposited condition, believed to be associated with the cracking propensity. Compositional modification of CM247LC including removal of Hf, reduction of C and addition of Nb eliminated the segregation zone but these changes were associated with an increased susceptibility to solidification and liquation cracking

Assessing institutional relations in development partnerships: the Land Development Corporation and the Hong Kong Government prior to 1997

This paper interprets and develops contemporary notions of partnership in relation to Hong Kong's Land Development Corporation. It demonstrates how such agencies are likely to become overdependent on their private-sector partners or ineffective in policy delivery, unless endowed with adequate powers and resources. In this context, it suggests that the LDC's capacity to promote urban renewal was undermined particularly by the institutional requirement to assemble redevelopment sites in multiple ownership principally through negotiation. While seeking to explain this weakness in relation to the socio-cultural context of Hong Kong, it warns that, in applying the Western experience of partnership elsewhere, full account must be taken of local circumstances and constraints

Atoms to phenotypes: Molecular design principles of cellular energy metabolism

We report a 100-million atom-scale model of an entire cell organelle, a photosynthetic chromatophore vesicle from a purple bacterium, that reveals the cascade of energy conversion steps culminating in the generation of ATP from sunlight. Molecular dynamics simulations of this vesicle elucidate how the integral membrane complexes influence local curvature to tune photoexcitation of pigments. Brownian dynamics of small molecules within the chromatophore probe the mechanisms of directional charge transport under various pH and salinity conditions. Reproducing phenotypic properties from atomistic details, a kinetic model evinces that low-light adaptations of the bacterium emerge as a spontaneous outcome of optimizing the balance between the chromatophore’s structural integrity and robust energy conversion. Parallels are drawn with the more universal mitochondrial bioenergetic machinery, from whence molecular-scale insights into the mechanism of cellular aging are inferred. Together, our integrative method and spectroscopic experiments pave the way to first-principles modeling of whole living cells

Two Types of Planning in Neighborhoods

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/68338/2/10.1177_0739456X8400300209.pd

Measurement of the charge ratio of atmospheric muons with the CMS detector

This is the pre-print version of this Article. The official published version can be accessed from the link below - Copyright @ 2010 ElsevierWe present a measurement of the ratio of positive to negative muon fluxes from cosmic ray interactions in the atmosphere, using data collected by the CMS detector both at ground level and in the underground experimental cavern at the CERN LHC. Muons were detected in the momentum range from 5 GeV/c to 1 TeV/c. The surface flux ratio is measured to be 1.2766 \pm 0.0032(stat.) \pm 0.0032 (syst.), independent of the muon momentum, below 100 GeV/c. This is the most precise measurement to date. At higher momenta the data are consistent with an increase of the charge ratio, in agreement with cosmic ray shower models and compatible with previous measurements by deep-underground experiments

Measurements of inclusive W and Z cross sections in pp collisions at root s=7 TeV

This is the pre-print version of the Published Article, which can be accessed from the link below - Copyright @ 2011 Springer VerlagMeasurements of inclusive W and Z boson production cross sections in pp collisions at sqrt(s)=7 TeV are presented, based on 2.9 inverse picobarns of data recorded by the CMS detector at the LHC. The measurements, performed in the electron and muon decay channels, are combined to give sigma(pp to WX) times B(W to muon or electron + neutrino) = 9.95 \pm 0.07(stat.) \pm 0.28(syst.) \pm 1.09(lumi.) nb and sigma(pp to ZX) times B(Z to oppositely charged muon or electron pairs) = 0.931 \pm 0.026(stat.) \pm 0.023(syst.) \pm 0.102(lumi.) nb. Theoretical predictions, calculated at the next-to-next-to-leading order in QCD using recent parton distribution functions, are in agreement with the measured cross sections. Ratios of cross sections, which incur an experimental systematic uncertainty of less than 4%, are also reported