826 research outputs found
A simple ansatz for the study of velocity autocorrelation functions in fluids at different timescales
A simple ansatz for the study of velocity autocorrelation functions in fluids
at different timescales is proposed. The ansatz is based on an effective
summation of the infinite continued fraction at a reasonable assumption about
convergence of relaxation times of the higher order memory functions, which
have a purely kinetic origin. The VAFs obtained within our approach are
compared with the results of the Markovian approximation for memory kernels. It
is shown that although in the "overdamped" regime both approaches agree to a
large extent at the initial and intermediate times of the system evolution, our
formalism yields power law relaxation of the VAFs which is not observed at the
description with a finite number of the collective modes. Explicit expressions
for the transition times from kinetic to hydrodynamic regimes are obtained from
the analysis of the singularities of spectral functions in the complex
frequency plane.Comment: 14 pages, 2 figure
Magnetism of small V clusters embedded in a Cu fcc matrix: an ab initio study
We present extensive first principles density functional theory (DFT)
calculations dedicated to analyze the magnetic and electronic properties of
small V clusters (n=1,2,3,4,5,6) embedded in a Cu fcc matrix. We consider
different cluster structures such as: i) a single V impurity, ii) several
V dimers having different interatomic distance and varying local atomic
environment, iii) V and iv) V clusters for which we assume compact
as well as 2- and 1-dimensional atomic configurations and finally, in the case
of the v) V and vi) V structures we consider a square pyramid and a
square bipyramid together with linear arrays, respectively. In all cases, the V
atoms are embedded as substitutional impurities in the Cu network. In general,
and as in the free standing case, we have found that the V clusters tend to
form compact atomic arrays within the cooper matrix. Our calculated non
spin-polarized density of states at the V sites shows a complex peaked
structure around the Fermi level that strongly changes as a function of both
the interatomic distance and local atomic environment, a result that
anticipates a non trivial magnetic behavior. In fact, our DFT calculations
reveal, in each one of our clusters systems, the existence of different
magnetic solutions (ferromagnetic, ferrimagnetic, and antiferromagnetic) with
very small energy differences among them, a result that could lead to the
existence of complex finite-temperature magnetic properties. Finally, we
compare our results with recent experimental measurements.Comment: 7 pages and 4 figure
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First Steps towards Underdominant Genetic Transformation of Insect Populations
The idea of introducing genetic modifications into wild populations of insects to stop them from spreading diseases is more than 40 years old. Synthetic disease refractory genes have been successfully generated for mosquito vectors of dengue fever and human malaria. Equally important is the development of population transformation systems to drive and maintain disease refractory genes at high frequency in populations. We demonstrate an underdominant population transformation system in Drosophila melanogaster that has the property of being both spatially self-limiting and reversible to the original genetic state. Both population transformation and its reversal can be largely achieved within as few as 5 generations. The described genetic construct {Ud} is composed of two genes; (1) a UAS-RpL14.dsRNA targeting RNAi to a haploinsufficient gene RpL14 and (2) an RNAi insensitive RpL14 rescue. In this proof-of-principle system the UAS-RpL14.dsRNA knock-down gene is placed under the control of an Actin5c-GAL4 driver located on a different chromosome to the {Ud} insert. This configuration would not be effective in wild populations without incorporating the Actin5c-GAL4 driver as part of the {Ud} construct (or replacing the UAS promoter with an appropriate direct promoter). It is however anticipated that the approach that underlies this underdominant system could potentially be applied to a number of species.
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Microscopic dynamics in liquid metals: the experimental point of view
The experimental results relevant for the understanding of the microscopic
dynamics in liquid metals are reviewed, with special regards to the ones
achieved in the last two decades. Inelastic Neutron Scattering played a major
role since the development of neutron facilities in the sixties. The last ten
years, however, saw the development of third generation radiation sources,
which opened the possibility of performing Inelastic Scattering with X rays,
thus disclosing previously unaccessible energy-momentum regions. The purely
coherent response of X rays, moreover, combined with the mixed
coherent/incoherent response typical of neutron scattering, provides enormous
potentialities to disentangle aspects related to the collectivity of motion
from the single particle dynamics.
If the last twenty years saw major experimental developments, on the
theoretical side fresh ideas came up to the side of the most traditional and
established theories. Beside the raw experimental results, therefore, we review
models and theoretical approaches for the description of microscopic dynamics
over different length-scales, from the hydrodynamic region down to the single
particle regime, walking the perilous and sometimes uncharted path of the
generalized hydrodynamics extension. Approaches peculiar of conductive systems,
based on the ionic plasma theory, are also considered, as well as kinetic and
mode coupling theory applied to hard sphere systems, which turn out to mimic
with remarkable detail the atomic dynamics of liquid metals. Finally, cutting
edges issues and open problems, such as the ultimate origin of the anomalous
acoustic dispersion or the relevance of transport properties of a conductive
systems in ruling the ionic dynamic structure factor are discussed.Comment: 53 pages, 41 figures, to appear in "The Review of Modern Physics".
Tentatively scheduled for July issu
Crossing borders: new teachers co-constructing professional identity in performative times
This paper draws on a range of theoretical perspectives on the construction of new teachersā professional identity. It focuses particularly on the impact of the development in many national education systems of a performative culture of the management and regulation of teachersā work. Whilst the role of interactions with professional colleagues and school managers in the performative school has been extensively researched, less attention has been paid to new teachersā interactions with students. This paper highlights the need for further research focusing on the process of identity co-construction with students. A key theoretical concept employed is that of liminality, the space within which identities are in transition as teachers adjust to the culture of a new professional workplace, and the nature of the engagement of new teachers, or teachers who change schools, with students. The authors argue that an investigation into the processes of this co-construction of identity offers scope for new insights into the extent to which teachers might construct either a teacher identity at odds with their personal and professional values, or a more āauthenticā identity that counters performative discourses. These insights will in turn add to our understanding of the complex range of factors impacting on teacher resilience and motivation
The Stratigraphy of Central and Western Butte and the Greenheugh Pediment Contact
The Greenheugh pediment at the base of Aeolis Mons (Mt. Sharp), which may truncate units in the Murray formation and is capped by a thin sandstone unit, appears to represent a major shift in climate history within Gale crater. The pediment appears to be an erosional remnant of potentially a much more extensive feature. Curiositys traverse through the southern extent of Glen Torridon (south of Vera Rubin ridge) has brought the rover in contact with several new stratigraphic units that lie beneath the pediment. These strata were visited at two outcrop-forming buttes (Central and Western butte- both remnants of the retreating pediment) south of an orbitally defined boundary marking the transition from the Fractured Clay-bearing Unit (fCU) and the fractured Intermediate Unit (fIU). Here we present preliminary interpretations of the stratigraphy within Central and Western buttes and propose the Western butte cap rocks do not match the pediment capping unit
All electron and pseudopotential study of the spin polarization of the V (001) surface: LDA versus GGA
The spin-polarization at the V(001) surface has been studied by using
different local (LSDA) and semilocal (GGA) approximations to the
exchange-correlation potential of DFT within two ab initio methods: the
all-electron TB-LMTO-ASA and the pseudopotential LCAO code SIESTA (Spanish
Initiative for Electronic Simulations with Thousands of Atoms). A comparative
analysis is performed first for the bulk and then for a N-layer V(001) film (7
< N < 15). The LSDA approximation leads to a non magnetic V(001) surface with
both theoretical models in agreement (disagreement) with magneto-optical Kerr
(electron-capture spectroscopy) experiments. The GGA within the pseudopotential
method needs thicker slabs than the LSDA to yield zero moment at the central
layer, giving a high surface magnetization (1.70 Bohr magnetons), in contrast
with the non magnetic solution obtained by means of the all-electron code.Comment: 12 pages, 1 figure. Latex gzipped tar fil
Phage T4 SegB protein is a homing endonuclease required for the preferred inheritance of T4 tRNA gene region occurring in co-infection with a related phage
Homing endonucleases initiate nonreciprocal transfer of DNA segments containing their own genes and the flanking sequences by cleaving the recipient DNA. Bacteriophage T4 segB gene, which is located in a cluster of tRNA genes, encodes a protein of unknown function, homologous to homing endonucleases of the GIY-YIG family. We demonstrate that SegB protein is a site-specific endonuclease, which produces mostly 3ā² 2-nt protruding ends at its DNA cleavage site. Analysis of SegB cleavage sites suggests that SegB recognizes a 27-bp sequence. It contains 11-bp conserved sequence, which corresponds to a conserved motif of tRNA TĻC stem-loop, whereas the remainder of the recognition site is rather degenerate. T4-related phages T2L, RB1 and RB3 contain tRNA gene regions that are homologous to that of phage T4 but lack segB gene and several tRNA genes. In co-infections of phages T4 and T2L, segB gene is inherited with nearly 100% of efficiency. The preferred inheritance depends absolutely on the segB gene integrity and is accompanied by the loss of the T2L tRNA gene region markers. We suggest that SegB is a homing endonuclease that functions to ensure spreading of its own gene and the surrounding tRNA genes among T4-related phages
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