The intermediate pyrolysis and catalytic steam reforming of brewers spent grain

Brewers spent grain (BSG) is a widely available feedstock representing approximately 85% of the total by-products generated in the brewing industry. This is currently either disposed of to landfill or used as cattle feed due to its high protein content. BSG has received little or no attention as a potential energy resource, but increasing disposal costs and environmental constraints are now prompting the consideration of this. One possibility for the utilisation of BSG for energy is via intermediate pyrolysis to produce gases, vapours and chars. Intermediate pyrolysis is characterised by indirect heating in the absence of oxygen for short solids residence times of a few minutes, at temperatures of 350-450 °C. In the present work BSG has been characterised by chemical, proximate, ultimate and thermo-gravimetric analysis. Intermediate pyrolysis of BSG at 450 °C was carried out using a twin coaxial screw reactor known as Pyroformer to give yields of char 29%, 51% of bio-oil and 19% of permanent gases. The bio-oil liquid was found to separate in to an aqueous phase and organic phase. The organic phase contained viscous compounds that could age over time leading to solid tars that can present problems in CHP application. The quality of the pyrolysis vapour products before quenching can be upgraded to achieve much improved suitability as a fuel by downstream catalytic reforming. A Bench Scale batch pyrolysis reactor has then been used to pyrolyse small samples of BSG under a range of conditions of heating rate and temperature simulating the Pyroformer. A small catalytic reformer has been added downstream of the reactor in which the pyrolysis vapours can be further cracked and reformed. A commercial reforming nickel catalyst was used at 500, 750 and 850 °C at a space velocity about 10,000 L/h with and without the addition of steam. Results are presented for the properties of BSG, and the products of the pyrolysis process both with and without catalytic post-processing. Results indicate that catalytic reforming produced a significant increase in permanent gases mainly (H2 and CO) with H2 content exceeding 50 vol% at higher reforming temperatures. Bio-oil yield decreased significantly as reforming temperature increased with char remaining the same as pyrolysis condition remained unchanged. The process shows an increase in heating value for the product gas ranging between 10.8-25.2 MJ/m as reforming temperature increased

Combined heat and power from the intermediate pyrolysis of biomass materials: performance, economics and environmental impact

Combined heat and power from the intermediate pyrolysis of biomass materials offers flexible, on demand renewable energy with some significant advantages over other renewable routes. To maximize the deployment of this technology an understanding of the dynamics and sensitivities of such a system is required. In the present work the system performance, economics and life-cycle environmental impact is analysed with the aid of the process simulation software Aspen Plus. Under the base conditions for the UK, such schemes are not currently economically competitive with energy and char products produced from conventional means. However, under certain scenarios as modelled using a sensitivity analysis this technology can compete and can therefore potentially contribute to the energy and resource sustainability of the economy, particularly in on-site applications with low-value waste feedstocks. The major areas for potential performance improvement are in reactor cost reductions, the reliable use of waste feedstocks and a high value end use for the char by-product from pyrolysis

The Geometry of Cold, Metal-Enriched Gas Around Galaxies at z∼1.2z\sim1.2

We present the first results from a Hubble Space Telescope WFC3/IR program, which obtained direct imaging and grism observations of galaxies near quasar sightlines with a high frequency of uncorrelated foreground Mg II absorption. These highly efficient observations targeted 54 Mg II absorbers along the line of sight to nine quasars at $z_{qso}\sim2$. We find that 89% of the absorbers in the range $0.64< z < 1.6$ can be spectroscopically matched to at least one galaxy with an impact parameter less than 200 kpc and $|\Delta z|/(1+z)<0.006$. We have estimated the star formation rates and measured structural parameters for all detected galaxies with impact parameters in the range 7-200 kpc and star formation rates greater than 1.3 M$_{\odot}$ yr$^{-1}$. We find that galaxies associated with Mg II absorption have significantly higher mean star formation rates and marginally higher mean star formation rate surface densities compared to galaxies with no detected Mg II. Nearly half of the Mg II absorbers match to more than one galaxy, and the mean equivalent width of the Mg II absorption is found to be greater for groups, compared to isolated galaxies. Additionally, we observe a significant redshift evolution in the physical extent of Mg II-absorbing gas around galaxies and evidence of an enhancement of Mg II within 50 degrees of the minor axis, characteristic of outflows, which persists to 80 kpc around the galaxies, in agreement with recent predictions from simulations.Comment: 21 pages, 20 figures, Submitted to Ap

Supramolecular assemblies involving metal organic ring interactions: Heterometallic Cu(II)-Ln(III) two dimensional coordination polymers

Three isostructural two-dimensional coordination polymers of the general formula [Ln2(CuL)3(H2O)9]$5.5H2O, where Ln is La (1), Nd (2), and Gd (3), have been synthesized and isolated from aqueous solutions and their single-crystal structures determined by X-ray diffraction. The supramolecular interaction between the non-aromatic metallorings plays an important role in stabilizing the structure of these compounds. The thermal stability, reversible solvent uptake, electronic properties and magnetic studies of these compounds are also reported

A fuzzy levelised energy cost method for renewable energy technology assessment

Renewable energy project development is highly complex and success is by no means guaranteed. Decisions are often made with approximate or uncertain information yet the current methods employed by decision-makers do not necessarily accommodate this. Levelised energy costs (LEC) are one such commonly applied measure utilised within the energy industry to assess the viability of potential projects and inform policy. The research proposes a method for achieving this by enhancing the traditional discounting LEC measure with fuzzy set theory. Furthermore, the research develops the fuzzy LEC (F-LEC) methodology to incorporate the cost of financing a project from debt and equity sources. Applied to an example bioenergy project, the research demonstrates the benefit of incorporating fuzziness for project viability, optimal capital structure and key variable sensitivity analysis decision-making. The proposed method contributes by incorporating uncertain and approximate information to the widely utilised LEC measure and by being applicable to a wide range of energy project viability decisions

A barrier and techno-economic analysis of small-scale bCHP (biomass combined heat and power) schemes in the UK

bCHP (Biomass combined heat and power) systems are highly efficient at smaller-scales when a significant proportion of the heat produced can be effectively utilised for hot water, space heating or industrial heating purposes. However, there are many barriers to project development and this has greatly inhibited deployment in the UK. Project viability is highly subjective to changes in policy, regulation, the finance market and the low cost fossil fuel incumbent. The paper reviews the barriers to small-scale bCHP project development in the UK along with a case study of a failed 1.5MWel bCHP scheme. The paper offers possible explanations for the project's failure and suggests adaptations to improve the project resilience. Analysis of the project's: capital structuring contract length and bankability; feedstock type and price uncertainty, and plant oversizing highlight the negative impact of the existing project barriers on project development. The research paper concludes with a discussion on the effects of these barriers on the case study project and this industry more generally. A greater understanding of the techno-economic effects of some barriers for small-scale bCHP schemes is demonstrated within this paper, along with some methods for improving the attractiveness and resilience of projects of this kind

Prosociality in business: a human empowerment framework

This study introduces a human empowerment framework to better understand why some businesses are more socially oriented than others in their policies and activities. Building on Welzel’s theory of emancipation, we argue that human empowerment—comprised of four components: action resources, emancipative values, social movement activity, and civic entitlements—enables, motivates, and entitles individuals to pursue social goals for their businesses. Using a sample of over 15,000 entrepreneurs from 43 countries, we report strong empirical evidence for two ecological effects of the framework components on prosociality. We find that human empowerment (1) lifts entrepreneurs’ willingness to choose a social orientation for their business, and (2) reinforces the gender effect on prosociality in business activity. We discuss the human empowerment framework’s added value in understanding how modernization processes fully leverage the potential of social business activities for societies

Determining the halo mass scale where galaxies lose their gas

A major question in galaxy formation is how the gas supply that fuels activity in galaxies is modulated by their environment. We use spectroscopy of a set of well characterized clusters and groups at $0.410.4$) of these old galaxies with weak [OII] emission. We use line ratios and compare to studies of local early type galaxies to conclude that this gas is likely excited by post-AGB stars and hence represents a diffuse gas component in the galaxies. For cluster and group galaxies the fraction with EW([OII])$>5$\AA\ is $f_{[OII]}=0.08^{+0.03}_{-0.02}$ and $f_{[OII]}=0.06^{+0.07}_{-0.04}$ respectively. For field galaxies we find $f_{[OII]}=0.27^{+0.07}_{-0.06}$, representing a 2.8$\sigma$ difference between the [OII] fractions for old galaxies between the different environments. We conclude that a population of old galaxies in all environments has ionized gas that likely stems from stellar mass loss. In the field galaxies also experience gas accretion from the cosmic web and in groups and clusters these galaxies have had their gas accretion shut off by their environment. Additionally, galaxies with emission preferentially avoid the virialized region of the cluster in position-velocity space. We discuss the implications of our results, among which is that gas accretion shutoff is likely effective at group halo masses (log~${\cal M}/$\msol$>12.8$) and that there are likely multiple gas removal processes happening in dense environments