Multiwavelength campaign on Mrk 509. VI. HST/COS observations of the far-ultraviolet spectrum

We present medium resolution (R~20,000) HST/COS ultraviolet spectra covering 1155-1760 A of the Seyfert 1 Mrk 509 obtained simultaneously with a Chandra/LETGS spectrum as part of a multiwavelength campaign in 2009 that included observations with XMM-Newton, SWIFT, and Integral. Our high S/N spectrum detects additional complexity in the absorption troughs from a variety of sources in Mrk 509, including the outflow from the active nucleus, the ISM and halo of the host galaxy, and infalling clouds or stripped gas from a merger that are illuminated by the AGN. Variability between the STIS and COS observation of the -400 km/s component allows us to set an upper limit on its distance of < 250 pc. Similarly, variability of a component at +150 km/s between two prior FUSE observations limits its distance to < 1.5 kpc. The UV absorption only partially covers the emission from the AGN nucleus. Covering fractions are lower than those previously seen with STIS, and are comparable to those seen with FUSE. Given the larger apertures of COS and FUSE compared to STIS, we favor scattered light from an extended region near the AGN as the explanation for the partial covering. As observed in prior X-ray and UV spectra, the UV absorption has velocities comparable to the X-ray absorption, but the bulk of the ultraviolet absorption is in a lower ionization state with lower total column density than the gas responsible for the X-ray absorption. We conclude that the outflow from the active nucleus is a multiphase wind.Comment: 21 pages, 9 figures. Accepted for publication in Astronomy & Astrophysics, 26 May 201

The Sloan Digital Sky Survey Reverberation Mapping Project: Rapid CIV Broad Absorption Line Variability

We report the discovery of rapid variations of a high-velocity CIV broad absorption line trough in the quasar SDSS J141007.74+541203.3. This object was intensively observed in 2014 as a part of the Sloan Digital Sky Survey Reverberation Mapping Project, during which 32 epochs of spectroscopy were obtained with the Baryon Oscillation Spectroscopic Survey spectrograph. We observe significant (>4sigma) variability in the equivalent width of the broad (~4000 km/s wide) CIV trough on rest-frame timescales as short as 1.20 days (~29 hours), the shortest broad absorption line variability timescale yet reported. The equivalent width varied by ~10% on these short timescales, and by about a factor of two over the duration of the campaign. We evaluate several potential causes of the variability, concluding that the most likely cause is a rapid response to changes in the incident ionizing continuum. If the outflow is at a radius where the recombination rate is higher than the ionization rate, the timescale of variability places a lower limit on the density of the absorbing gas of n_e > 3.9 x 10^5 cm^-3. The broad absorption line variability characteristics of this quasar are consistent with those observed in previous studies of quasars, indicating that such short-term variability may in fact be common and thus can be used to learn about outflow characteristics and contributions to quasar/host-galaxy feedback scenarios.Comment: 15 pages, 14 figures. Accepted for publication in the Astrophysical Journa

Gas reservoir of a hyper-luminous quasar at z= 2.6

Understanding the relationship between the formation and evolution of galaxies and their central super massive black holes (SMBH) is one of the main topics in extragalactic astrophysics. Links and feedback may reciprocally affect both black hole and galaxy growth. Observations of the CO line at redshifts of 2-4 are crucial to investigate the gas mass, star formation activity and accretion onto SMBHs, as well as the effect of AGN feedback. Potential correlations between AGN and host galaxy properties can be highlighted by observing extreme objects. Despite their luminosity, hyper-luminous QSOs at z=2-4 are still little studied at mm wavelengths. We targeted CO(3-2) in ULAS J1539+0557, an hyper-luminos QSO (Lbol> 10^48 erg/s) at z=2.658, selected through its unusual red colors in the UKIDSS Large Area Survey (ULAS). We find a molecular gas mass of 4.1+-0.8 10^10 Msun, and a gas fraction of 0.4-0.1, depending mostly on the assumed source inclination. We also find a robust lower limit to the star-formation rate (SFR=250-1600 Msun/yr) and star-formation efficiency (SFE=25-350 Lsun/(K km s-1 pc2) by comparing the observed optical-near-infrared spectral energy distribution with AGN and galaxy templates. The black hole gas consumption timescale, M(H_2)/dM(accretion)/dt, is ~160 Myr, similar or higher than the gas consumption timescale. The gas content and the star formation efficiency are similar to those of other high-luminosity, highly obscured QSOs, and at the lower end of the star-formation efficiency of unobscured QSOs, in line with predictions from AGN-galaxy co-evolutionary scenarios. Further measurements of the (sub)-mm continuum in this and similar sources are mandatory to obtain a robust observational picture of the AGN evolutionary sequence.32912

Discovery of an Ultraviolet Counterpart to an Ultra-Fast X-ray Outflow in the Quasar PG1211+143

This is an author-created, un-copyedited version of an article published in The Astrophysical Journal. The Version of Record is available online at https://doi.org/10.3847/1538-4357/aaa42bWe observed the quasar PG 1211+143 using the Cosmic Origins Spectrograph on the Hubble Space Telescope in 2015 April as part of a joint campaign with the Chandra X-ray Observatory and the Jansky Very Large Array. Our ultraviolet spectra cover the wavelength range 912-2100 Å. We find a broad absorption feature () at an observed wavelength of 1240 Å. Interpreting this as H i Lyα, in the rest frame of PG 1211+143 (z = 0.0809), this corresponds to an outflow velocity of -16,980 (outflow redshift ), matching the moderate ionization X-ray absorption system detected in our Chandra observation and reported previously by Pounds et al. With a minimum H i column density of , and no absorption in other UV resonance lines, this Lyα absorber is consistent with arising in the same ultrafast outflow as the X-ray absorbing gas. The Lyα feature is weak or absent in archival ultraviolet spectra of PG 1211+143, strongly suggesting that this absorption is transient, and intrinsic to PG 1211+143. Such a simultaneous detection in two independent wavebands for the first time gives strong confirmation of the reality of an ultrafast outflow in an active galactic nucleus.Peer reviewe

Catalytic Transformations of Alkynes via Ruthenium Vinylidene and Allenylidene Intermediates

NOTICE: This is the peer reviewed version of the following book chapter: Varela J. A., González-Rodríguez C., Saá C. (2014). Catalytic Transformations of Alkynes via Ruthenium Vinylidene and Allenylidene Intermediates. In: Dixneuf P., Bruneau C. (eds) Ruthenium in Catalysis. Topics in Organometallic Chemistry, vol 48, pp. 237-287. Springer, Cham. [doi: 10.1007/3418_2014_81]. This article may be used for non-commercial purposes in accordance with Springer Verlag Terms and Conditions for self-archiving.Vinylidenes are high-energy tautomers of terminal alkynes and they can be stabilized by coordination with transition metals. The resulting metal-vinylidene species have interesting chemical properties that make their reactivity different to that of the free and metal π-coordinated alkynes: the carbon α to the metal is electrophilic whereas the β carbon is nucleophilic. Ruthenium is one of the most commonly used transition metals to stabilize vinylidenes and the resulting species can undergo a range of useful transformations. The most remarkable transformations are the regioselective anti-Markovnikov addition of different nucleophiles to catalytic ruthenium vinylidenes and the participation of the π system of catalytic ruthenium vinylidenes in pericyclic reactions. Ruthenium vinylidenes have also been employed as precatalysts in ring closing metathesis (RCM) or ring opening metathesis polymerization (ROMP). Allenylidenes could be considered as divalent radicals derived from allenes. In a similar way to vinylidenes, allenylidenes can be stabilized by coordination with transition metals and again ruthenium is one of the most widely used metals. Metalallenylidene complexes can be easily obtained from terminal propargylic alcohols by dehydration of the initially formed metal-hydroxyvinylidenes, in which the reactivity of these metal complexes is based on the electrophilic nature of Cα and Cγ, while Cβ is nucleophilic. Catalytic processes based on nucleophilic additions and pericyclic reactions involving the π system of ruthenium allenylidenes afford interesting new structures with high selectivity and atom economy

Spectropolarimetry of high-redshift obscured and red quasars

Spectropolarimetry is a powerful technique that has provided critical support for the geometric unification model of local active galactic nuclei. In this paper, we present optical (rest-frame UV) Keck spectropolarimetry of five luminous obscured (Type 2) and extremely red quasars (ERQs) at z~2.5. Three objects reach polarization fractions of >10% in the continuum. We propose a model in which dust scattering is the dominant scattering and polarization mechanism in our targets, though electron scattering cannot be completely excluded. Emission lines are polarized at a lower level than is the continuum. This suggests that the emission-line region exists on similar spatial scales as the scattering region. In three objects we detect an intriguing 90 degree swing in the polarization position angle as a function of line-of-sight velocity in the emission lines of Ly-alpha, CIV and NV. We interpret this phenomenon in the framework of a geometric model with an equatorial dusty scattering region in which the material is outflowing at several thousand km/sec. Emission lines may also be scattered by dust or resonantly. This model explains several salient features of observations by scattering on scales of a few tens of pc. Our observations provide a tantalizing view of the inner region geometry and kinematics of high-redshift obscured and extremely red quasars. Our data and modeling lend strong support for toroidal obscuration and powerful outflows on the scales of the UV emission-line region, in addition to the larger scale outflows inferred previously from the optical emission-line kinematics.Comment: 26 pages, MNRAS, in pres

Infrared second harmonic generation spectroscopy of Ge(111) interfaces

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Infrared second harmonic generation spectroscopy of Ge(111) interfaces

no abstrac