2,569 research outputs found
Silicon microcantilever sensors to detect the reversible conformational change of a molecular switch, Spiropyan
The high sensitivity of silicon microcantilever sensors has expanded their use in areas ranging from gas sensing to bio-medical applications. Photochromic molecules also represent promising candidates for a large variety of sensing applications. In this work, the operating principles of these two sensing methods are combined in order to detect the reversible conformational change of a molecular switch, spiropyran. Thus, arrays of silicon microcantilever sensors were functionalized with spiropyran on the gold covered side and used as test microcantilevers. The microcantilever deflection response was observed, in five sequential cycles, as the transition from the spiropyran (SP) (CLOSED) to the merocyanine (MC) (OPEN) state and vice-versa when induced by UV and white light LED sources, respectively, proving the reversibility capabilities of this type of sensor. The microcantilever deflection direction was observed to be in one direction when changing to the MC state and in the opposite direction when changing back to the SP state. A tensile stress was induced in the microcantilever when the SP to MC transition took place, while a compressive stress was observed for the reverse transition. These different type of stresses are believed to be related to the spatial conformational changes induced in the photochromic molecule upon photo-isomerisation
Resolving galaxies in time and space: II: Uncertainties in the spectral synthesis of datacubes
In a companion paper we have presented many products derived from the
application of the spectral synthesis code STARLIGHT to datacubes from the
CALIFA survey, including 2D maps of stellar population properties and 1D
averages in the temporal and spatial dimensions. Here we evaluate the
uncertainties in these products. Uncertainties due to noise and spectral shape
calibration errors and to the synthesis method are investigated by means of a
suite of simulations based on 1638 CALIFA spectra for NGC 2916, with
perturbations amplitudes gauged in terms of the expected errors. A separate
study was conducted to assess uncertainties related to the choice of
evolutionary synthesis models. We compare results obtained with the Bruzual &
Charlot models, a preliminary update of them, and a combination of spectra
derived from the Granada and MILES models. About 100k CALIFA spectra are used
in this comparison.
Noise and shape-related errors at the level expected for CALIFA propagate to
0.10-0.15 dex uncertainties in stellar masses, mean ages and metallicities.
Uncertainties in A_V increase from 0.06 mag in the case of random noise to 0.16
mag for shape errors. Higher order products such as SFHs are more uncertain,
but still relatively stable. Due to the large number statistics of datacubes,
spatial averaging reduces uncertainties while preserving information on the
history and structure of stellar populations. Radial profiles of global
properties, as well as SFHs averaged over different regions are much more
stable than for individual spaxels. Uncertainties related to the choice of base
models are larger than those associated with data and method. Differences in
mean age, mass and metallicity are ~ 0.15 to 0.25 dex, and 0.1 mag in A_V.
Spectral residuals are ~ 1% on average, but with systematic features of up to
4%. The origin of these features is discussed. (Abridged)Comment: A&A, accepte
Star formation histories in mergers: the spatially resolved properties of the early-stage merger luminous infrared galaxies IC 1623 and NGC 6090
The role of major mergers in galaxy evolution is investigated through a detailed characterization of the stellar populations, ionized gas properties and star formation rates (SFR) in the early-stage merger luminous infrared galaxies (LIRGs) IC 1623 W and NGC 6090, by analysing optical integral field spectroscopy and high-resolution Hubble Space Telescope imaging. The spectra were processed with the starlight full spectral fitting code, and the emission lines measured in the residual spectra. The results are compared with non-interacting control spiral galaxies from the Calar Alto Legacy Integral Field Area survey. Merger-induced star formation is extended and recent, as revealed by the young ages (50–80 Myr) and high contributions to light of young stellar populations (50–90 per cent), in agreement with merger simulations in the literature. These early-stage mergers have positive central gradients of the stellar metallicity, with an average ∼0.6 Z⊙. Compared to non-interacting spirals, they have lower central nebular metallicity, and flatter profiles, in agreement with the gas inflow scenario. We find that they are dominated by star formation, although shock excitation cannot be discarded in some regions, where high velocity dispersion is found (170–200 km s−1). The average SFR in these early-stage mergers (∼23–32 M⊙ yr−1) is enhanced with respect to main-sequence Sbc galaxies by factors of 6–9, slightly above the predictions from classical merger simulations, but still possible in about 15 per cent of major galaxy mergers, where U/LIRGs belong
Wearable Electrochemical Sensors for Monitoring Performance Athletes
Nowadays, wearable sensors such as heart rate monitors and pedometers are in common use. The use of wearable systems such as these for personalized exercise regimes for health and rehabilitation is particularly interesting. In particular, the true potential of wearable chemical sensors, which for the real-time ambulatory monitoring of bodily fluids such as tears, sweat, urine and blood has not been realized. Here we present a brief introduction into the fields of ionogels and organic electrochemical transistors, and in particular, the concept of an OECT transistor incorporated into a sticking-plaster, along with a printable “ionogel” to provide a wearable biosensor platform
Imprints of galaxy evolution on H ii regions Memory of the past uncovered by the CALIFA survey
H ii regions in galaxies are the sites of star formation and thus particular
places to understand the build-up of stellar mass in the universe. The line
ratios of this ionized gas are frequently used to characterize the ionization
conditions. We use the Hii regions catalogue from the CALIFA survey (~5000 H ii
regions), to explore their distribution across the classical [OIII]/Hbeta vs.
[NII]/Halpha diagnostic diagram, and how it depends on the oxygen abundance,
ionization parameter, electron density, and dust attenuation. We compared the
line ratios with predictions from photoionization models. Finally, we explore
the dependences on the properties of the host galaxies, the location within
those galaxies and the properties of the underlying stellar population. We
found that the location within the BPT diagrams is not totally predicted by
photoionization models. Indeed, it depends on the properties of the host
galaxies, their galactocentric distances and the properties of the underlying
stellar population. These results indicate that although H ii regions are short
lived events, they are affected by the total underlying stellar population. One
may say that H ii regions keep a memory of the stellar evolution and chemical
enrichment that have left an imprint on the both the ionizing stellar
population and the ionized gasComment: 18 pages, 8 figures, accepted for publishing in A&
Integral field spectroscopy of nitrogen overabundant blue compact dwarf galaxies
We study the spatial distribution of the physical properties and of oxygen
and nitrogen abundances in three Blue Compact Dwarf Galaxiess (HS 0128+2832, HS
0837+4717 and Mrk 930) with a reported excess of N/O in order to investigate
the nature of this excess and, particularly, if it is associated with
Wolf-Rayet (WR) stars We have observed these BCDs by using PMAS integral field
spectroscopy in the optical spectral range (3700 - 6900 {\AA}), mapping their
physical-chemical properties, using both the direct method and appropriate
strong-line methods. We make a statistical analysis of the resulting
distributions and we compare them with the integrated properties of the
galaxies. Our results indicate that outer parts of the three galaxies are
placed on the "AGN-zone" of the [NII]/H{\alpha} vs. [OIII]/H{\beta} diagnostic
diagram most likely due to a high N/O combined with the excitation structure in
these regions. From the statistical analysis, it is assumed that a certain
property can be considered as spatially homogeneous (or uniform) if a normal
gaussian function fits its distribution in several regions of the galaxy.
Moreover, a disagreement between the integrated properties and the mean values
of the distribution usually appears when a gaussian does not fit the
corresponding distribution. We find that for Mrk 930, the uniformity is found
for all parameters, except for electron density and reddening. The rotation
curve together with the H{\alpha} map and UV images, reveal a perturbed
morphology and possible interacting processes. The N/O is found to be constant
in the three studied objects at spatial scales of the order of several kpc so
we conclude that the number of WR stars estimated from spectroscopy is not
sufficient to pollute the ISM and to produce the observed N/O excess in these
objectsComment: 17 pages, 14 figures, accepted for publication in Astronomy &
Astrophysic
Eyespot resistance gene Pch-1 in H-93 wheat lines. Evidence of linkage to markers of chromosome group 7 and resolution from the endopeptídase locus Ep-Dlb
Gene Pch1, which confers resistance to eyespot disease (Pseudocercosporella herpotrichoides Fron), has been located on chromosome 7D in the H-93 wheat-Aegilops ventricosa transfer lines using isozyme markers and DNA probes corresponding to group 7 chromosomes. Previous experiments had failed to ascertain this location. The lack of segregation of the resistance trait in progeny from reciprocal crosses between lines H-93-70 and VPM1 indicates that their respective resistance factors are allelic. Line H-93-51 carries the endopeptidase allele Ep-D1b but is susceptible to eyespot, which indicates that resistance to eyespot is not a product of the Ep-D locus, as had been proposed in a previous hypohesi
CRB2 completes a fully expressed Crumbs complex in the Retinal Pigment Epithelium
The CRB proteins CRB1, CRB2 and CRB3 are members of the cell polarity complex Crumbs in mammals that together with Scribble and Par complexes stablish the polarity of a variety of cell types. Although many members of the Crumbs complex proteins are expressed in the retinal pigment epithelium (RPE), and even though the mRNA of CRB2 has been detected in ARPE-19 cells and in the RPE/Choroid, to date no CRB protein has yet been found in this tissue. To investigate this possibility, we generated an antibody that specifically recognize the mouse CRB2 protein, and we demonstrate the expression of CRB2 in mouse RPE. Confocal analysis shows that CRB2 is restricted to the apicolateral membrane of RPE cells, and more precisely, in the tight junctions. Our study identified CRB2 as the member of the CRB protein family that is present together with the rest of the components of the Crumbs complex in the RPE apico-lateral cell membrane. Considering that the functions of CRB proteins are decisive in the establishment and maintenance of cell-cell junctions in several epithelial-derived cell types, we believe that these findings are a relevant starting point for unraveling the functions that CRB2 might perform in the RPE
Ionized gas kinematics of galaxies in the CALIFA survey I: Velocity fields, kinematic parameters of the dominant component, and presence of kinematically distinct gaseous systems
This work provides an overall characterization of the kinematic behavior of
the ionized gas of the galaxies included in the Calar Alto Legacy Integral
field Area (CALIFA), offering kinematic clues to potential users of this survey
for including kinematical criteria for specific studies. From the first 200
galaxies observed by CALIFA, we present the 2D kinematic view of the 177
galaxies satisfying a gas detection threshold. After removing the stellar
contribution, we used the cross-correlation technique to obtain the radial
velocity of the dominant gaseous component. The main kinematic parameters were
directly derived from the radial velocities with no assumptions on the internal
motions. Evidence of the presence of several gaseous components with different
kinematics were detected by using [OIII] profiles. Most objects in the sample
show regular velocity fields, although the ionized-gas kinematics are rarely
consistent with simple coplanar circular motions. 35% of the objects present
evidence of a displacement between the photometric and kinematic centers larger
than the original spaxel radii. Only 17% of the objects in the sample exhibit
kinematic lopsidedness when comparing receding and approaching sides of the
velocity fields, but most of them are interacting galaxies exhibiting nuclear
activity. Early-type galaxies in the sample present clear photometric-kinematic
misaligments. There is evidence of asymmetries in the emission line profiles
suggesting the presence of kinematically distinct gaseous components at
different distances from the nucleus. This work constitutes the first
determination of the ionized gas kinematics of the galaxies observed in the
CALIFA survey. The derived velocity fields, the reported kinematic
peculiarities and the identification of the presence of several gaseous
components might be used as additional criteria for selecting galaxies for
specific studies.Comment: 38 pages, 16 figures, 4 tables. Paper accepted for publication in A&
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