Removal of Radium from Synthetic Shale Gas Brines by Ion Exchange Resin

Rapid development of hydraulic fracturing for natural gas production from shale reservoirs presents a significant challenge related to the management of the high-salinity wastewaters that return to the surface. In addition to high total dissolved solids (TDS), shale gas-produced brines typically contain elevated concentrations of radium (Ra), which must be treated properly to prevent contamination of surface waters and allow for safe disposal or reuse of produced water. Treatment strategies that isolate radium in the lowest volume waste streams would be desirable to reduce disposal cost and generate useful treatment by-products. The present study evaluates the potential of a commercial strong acid cation exchange resin for removing Ra2+ from high-TDS brines using fixed-bed column reactors. Column reactors were operated with varying brine chemistries and salinities in an effort to find optimal conditions for Ra2+ removal through ion exchange. To overcome competing divalent cations present in the brine for exchange sites, the chelating agent, EDTA, was used to form stable complexes predominantly with the higher concentration Ca2+, Mg2+, and Sr2+ divalent cations, while isolating the much lower concentration Ra2+ species. Results showed that Ra2+ removal by the resin strongly depended on the TDS concentration and could be improved with careful selection of EDTA concentration. This strategy of metal chelation coupled with ion exchange resins may be effective in enhancing Ra2+ removal and reducing the generation and disposal cost if volume reduction of low-level radioactive solid waste can be achieved.Peer Reviewedhttps://deepblue.lib.umich.edu/bitstream/2027.42/140367/1/ees.2016.0002.pd

Seesaw and Lepton Flavour Violation in SUSY SO(10)

That $\mu \to e, \gamma$ and $\tau \to \mu,\gamma$ are sensitive probes of SUSY models with a see-saw mechanism is a well accepted fact. Here we propose a `top-down' approach in a general SUSY SO(10) scheme. In this framework, we show that at least one of the neutrino Yukawa couplings is as large as the top Yukawa coupling. This leads to a strong enhancement of these leptonic flavour changing decay rates. We examine two `extreme' cases, where the lepton mixing angles in the neutrino Yukawa couplings are either small (CKM-like) or large (PMNS-like). In these two cases, we quantify the sensitivity of leptonic radiative decays to the SUSY mass spectrum. In the PMNS case, we find that the ongoing experiments at the B-factories can completely probe the spectrum up to gaugino masses of 500 GeV (any tan $\beta$). Even in the case of CKM-like mixings, large regions of the parameter space will be probed in the near future, making these two processes leading candidates for indirect SUSY searches.Comment: 22 pages with 2 figures. Figures for \tau -> \mu \gamma decay corrected after typo found in the program. Decay \mu -> e gamma completely unchanged and conclusions basicaly unchange

Lyα\alpha Leaks and Reionization

Ly$\alpha$ absorption spectra of QSOs at redshifts $z\simeq6$ show complete Gunn-Peterson absorption troughs (dark gaps) separated by tiny leaks. The dark gaps are from the intergalactic medium (IGM) where the density of neutral hydrogen are high enough to produce almost saturated absorptions, however, where the transmitted leaks come from is still unclear so far. We demonstrate that leaking can originate from the lowest density voids in the IGM as well as the ionized patches around ionizing sources using semi-analytical simulations. If leaks were produced in lowest density voids, the IGM might already be highly ionized, and the ionizing background should be almost uniform; in contrast, if leaks come from ionized patches, the neutral fraction of IGM would be still high, and the ionizing background is significantly inhomogeneous. Therefore, the origin of leaking is crucial to determining the epoch of inhomogeneous-to-uniform transition of the the ionizing photon background. We show that the origin could be studied with the statistical features of leaks. Actually, Ly$\alpha$ leaks can be well defined and described by the equivalent width $W$ and the full width of half area $W_{\rm H}$, both of which are less contaminated by instrumental resolution and noise. It is found that the distribution of $W$ and $W_{\rm H}$ of Ly$\alpha$ leaks are sensitive to the modeling of the ionizing background. We consider four representative reionization models. It is concluded that the leak statistics provides an effective tool to probe the evolutionary history of reionization at $z\simeq5-6.5$. Similar statistics would also be applicable to the reionization of He II at $z \simeq 3$(Abridged)Comment: 11 pages including 10 figures, accepted for publication in MNRA

Anomalous U(1) symmetry and lepton flavor violation

We show that in a large class of models based on anomalous U(1) symmetry which addresses the fermion mass hierarchy problem, leptonic flavor changing processes are induced that are in the experimentally interesting range. The flavor violation occurs through the renormalization group evolution of the soft SUSY breaking parameters between the string scale and the U(1)_A breaking scale. We derive general expressions for the evolution of these parameters in the presence of higher dimensional operators. Several sources for the flavor violation are identified: flavor-dependent contributions to the soft masses from the U(1)_A gaugino, scalar mass corrections proportional to the trace of U(1)_A charge, non-proportional A-terms from vertex corrections, and the U(1)_A D-term. Quantitative estimates for the decays \mu -> e \gamma and \tau -> \mu \gamma are presented in supergravity models which accommodate the relic abundance of neutralino dark matter.Comment: References added, typos corrected, 28 pages LaTeX, includes 14 eps figure

Background Dependent Lorentz Violation: Natural Solutions to the Theoretical Challenges of the OPERA Experiment

To explain both the OPERA experiment and all the known phenomenological constraints/observations on Lorentz violation, the Background Dependent Lorentz Violation (BDLV) has been proposed. We study the BDLV in a model independent way, and conjecture that there may exist a "Dream Special Relativity Theory", where all the Standard Model (SM) particles can be subluminal due to the background effects. Assuming that the Lorentz violation on the Earth is much larger than those on the interstellar scale, we automatically escape all the astrophysical constraints on Lorentz violation. For the BDLV from the effective field theory, we present a simple model and discuss the possible solutions to the theoretical challenges of the OPERA experiment such as the Bremsstrahlung effects for muon neutrinos and the pion decays. Also, we address the Lorentz violation constraints from the LEP and KamLAMD experiments. For the BDLV from the Type IIB string theory with D3-branes and D7-branes, we point out that the D3-branes are flavour blind, and all the SM particles are the conventional particles as in the traditional SM when they do not interact with the D3-branes. Thus, we not only can naturally avoid all the known phenomenological constraints on Lorentz violation, but also can naturally explain all the theoretical challenges. Interestingly, the energy dependent photon velocities may be tested at the experiments.Comment: RevTex4, 14 pages, minor corrections, references adde

Lepton Flavor Violation within a realistic SO(10)/G(224) Framework

Lepton flavor violation (LFV) is studied within a realistic unified framework, based on supersymmetric SO(10) or an effective G(224) = SU(2)_L\times SU(2)_R\times SU(4)^c symmetry, that successfully describes (i) fermion masses and mixings, (ii) neutrino oscillations, as well as (iii) CP violation. LFV emerges as an important prediction of this framework, bringing no new parameters, barring the few SUSY parameters, which are assumed to be flavor-universal at M^*>= M_{GUT}. We study LFV (i.e. \mu -> e\gamma, \tau -> \mu\gamma, \tau -> e\gamma and \mu N -> e N) within this framework by including contributions both from the presence of the right handed neutrinos as well as those arising from renormalization group running in the post-GUT regime (M^* to M_{GUT}). Typically the latter, though commonly omitted in the literature, is found to dominate. Our predicted rates for \mu -> e\gamma show that while some choices of (m_o, m_{1/2}) are clearly excluded by the current empirical limit, this decay should be seen with an improvement of the current sensitivity by a factor of 10--100, even if sleptons are moderately heavy (<= 800 GeV, say). For the same reason, \mu-e conversion (\mu N -> e N) should show in the planned MECO experiment. Implications of WMAP and (g-2)_{\mu}-measurements are noted, as also the significance of the measurement of parity-odd asymmetry in the decay of polarized \mu^+ into e^+ \gamma.Comment: 17 pages, 1 figur

Experimental Studies of Phase Change Materials in a Bubbling Fluidized Bed

Proceedings of: 14th International Conference on Fluidization: From Fundamentals to Products. Noordwijkerhout, Netherlands, 26-31 may 2013.The aim of this work is to experimentally study the behaviour of three microencapsulated PCM in a bubbling fluidized bed for thermal energy storage. Different experiments, heating and cooling the granular PCM with fluidizing air, are carried out with different superficial gas velocities. When achieving their phase change temperature two of the three materials present agglomeration. For this reason, the material flowability and wear resistance are studied by measuring the angle of repose and attrition, respectively. Nevertheless, the angle of repose does not seem to be influenced by the temperature of the material and the particle size distributions after the attrition tests indicate that the bed particles are just slightly smaller than the original ones.This work was partially founded by the Spanish Government (Project ENE2010-15403), the regional Government of Castilla-La Mancha (Project PPIC10-0055-4054) and Castilla-La Mancha University (Project GE20101662).Publicad

Lepton Flavor Violation and the Origin of the Seesaw Mechanism

The right--handed neutrino mass matrix that is central to the understanding of small neutrino masses via the seesaw mechanism can arise either (i) from renormalizable operators or (ii) from nonrenormalizable or super-renormalizable operators, depending on the symmetries and the Higgs content of the theory beyond the Standard Model. In this paper, we study lepton flavor violating (LFV) effects in the first class of seesaw models wherein the \nu_R Majorana masses arise from renormalizable Yukawa couplings involving a B-L = 2 Higgs field. We present detailed predictions for \tau -> \mu + \gamma and \mu -> e + \gamma branching ratios in these models taking the current neutrino oscillation data into account. Focusing on minimal supergravity models, we find that for a large range of MSSM parameters suggested by the relic abundance of neutralino dark matter and that is consistent with Higgs boson mass and other constraints, these radiative decays are in the range accessible to planned experiments. We compare these predictions with lepton flavor violation in the second class of models arising entirely from the Dirac Yukawa couplings. We study the dependence of the ratio r \equiv B(\mu -> e+\gamma)/B(\tau ->\mu +\gamma) on the MSSM parameters and show that measurement of r can provide crucial insight into the origin of the seesaw mechanism.Comment: 20 pages, Revtex, 7 figure

Geodesic motion in the Kundt spacetimes and the character of envelope singularity

We investigate geodesics in specific Kundt type N (or conformally flat) solutions to Einstein's equations. Components of the curvature tensor in parallelly transported tetrads are then explicitly evaluated and analyzed. This elucidates some interesting global properties of the spacetimes, such as an inherent rotation of the wave-propagation direction, or the character of singularities. In particular, we demonstrate that the characteristic envelope singularity of the rotated wave-fronts is a (non-scalar) curvature singularity, although all scalar invariants of the Riemann tensor vanish there.Comment: 21 pages, 3 figures. To appear in Class. Quantum Gra

Relic abundance of mass-varying cold dark matter particles

In models of coupled dark energy and dark matter the mass of the dark matter particle depends on the cosmological evolution of the dark energy field. In this note we exemplify in a simple model the effects of this mass variation on the relic abundance of cold dark matter.Comment: 5 pages, no figures. Version published in PL