3D Modelling for the Dispersion of Sediments Dredged in the Port of La Rochelle with Open TELEMAC-MASCARET

Hydrodynamic

Electrochemical methods for speciation of trace elements in marine waters. Dynamic aspects

The contribution of electrochemical methods to the knowledge of dynamic speciation of toxic trace elements in marine waters is critically reviewed. Due to the importance of dynamic considerations in the interpretation of the electrochemical signal, the principles and recent developments of kinetic features in the interconversion of metal complex species will be presented. As dynamic electrochemical methods, only stripping techniques (anodic stripping voltammetry and stripping chronopotentiometry) will be used because they are the most important for the determination of trace elements. Competitive ligand ex- change-adsorptive cathodic stripping voltammetry, which should be considered an equilibrium technique rather than a dynamic method, will be also discussed because the complexing parameters may be affected by some kinetic limitations if equilibrium before analysis is not attained and/or the flux of the adsorbed complex is in fluenced by the lability of the natural complexes in the water sample. For a correct data interpretation and system characterization the comparison of results obtained from different techniques seems essential in the articulation of a serious discussion of their meaning

Metals impact into the Paranaguá Estuarine Complex (Brazil) during the exceptional flood of 2011

Abstract Particulate and dissolved metal concentrations were determined after the largest flood in the last 30 years on the east-west axis of the Paranaguá Estuarine Complex (PEC) and compared to the those of the dry period at two stations. Results confirmed that the flood greatly affected riverine outflows and the behavior of metals in the PEC. In particular, a sharp decrease in salinity was followed by extremely high SPM concentrations leading to a decrease in DO concentrations at both stations. For the dissolved phase, ANOSIM analysis showed a significant dissimilarity at each station between the sampled periods, whereas for the particulate phase this dissimilarity was found only for the samplings taken at the Antonina Station. KD values suggested dissolved Cu behavior was related to the presence of organic complexes and dissolved Mn had sediment resuspension of redox sediments and or/pore water injection as sources. Metal concentrations were lower than in polluted estuaries, though high enrichment factors found after the flood pointed to the influence of anthropogenic sources. In conclusion, the flood's influence was more evident at the Antonina Station, due to its location in the upper estuary, whereas in Paranaguá a high SPM content with low metal concentration was found, following the common pattern generally found in other marine systems subject to heavy rainfall events

Modeling sand/mud transport and morphodynamics inthe Seine river mouth (France) : an attempt using a process-based approach.

The mouth of the Seine River estuary (France) has undergone marked morphological evolution over several decades mainly due to engineering works aimed at improving access to Rouen and Le Havre harbours. The intertidal areas are decreasing in size and the lower estuary is accumulating sediment and prograding. In order to understand and better describe the major morphological behaviours of the estuary, a morphodynamic numerical model was developed within the Seine-Aval program. At the end of the 1st part of the research program, a validated fine sediment transport model (3D) was available (Le Hir et al., 2001b). As the present morphological study addresses medium-term issues (a few decades), and because of the need to investigate impacts of local structures or events, we chose to use the so-called "process-based approach" starting from the existing model. First, the existing model was upgraded to account for (suspended) sand transport, and to achieve coupling between morphological changes and sediment transport. Erodability of the sediment accounts for the respective proportions of mud and sand. Simulations starting from an arbitrary surficial sediment cover show that the model is able to reproduce realistic sediment patterns. For example, it is able to change the sediment nature on the intertidal flat near Le Havre from sand to mud. Observed structures of suspended sediment are also reproduced: fine particles mainly follow the turbidity maximum whereas significant concentrations of sand grains in suspension are found where the hydrodynamic stresses are intense. Concerning morphodynamics, simulations with real forcing over one year are discussed. The effect of waves on the bathymetric evolution of the mouth is shown and the sensitivity of morphodynamics to the coupling procedure is tested

Storm-induced marine flooding: Lessons from a multidisciplinary approach

International audienceThere is a growing interest for marine flooding related to recent catastrophic events and their unintended consequences in terms of casualties and damages, and to the increasing population and issues along the coasts in a context of changing climate. Consequently, the knowledge on marine flooding has progressed significantly for the last years and this review, focused on storm-induced marine submersions, responds to the need for a synthesis. Three main components are presented in the review: (1) a state-of-the-art on marine submersions from the viewpoint of several scientific disciplines; (2) a selection of examples demonstrating the added value of interdisciplinary approaches to improve our knowledge of marine submersions; (3) a selection of examples showing how the management of future crises or the planning efforts to adapt to marine submersions can be supported by new results or techniques from the research community.From a disciplinary perspective, recent progress was achieved with respect to physical processes, numerical modeling, the knowledge of past marine floods and vulnerability assessment. At a global scale, the most vulnerable coastal areas to marine flooding with high population density are deltas and estuaries. Recent and well-documented floods allow analyzing the vulnerability parameters of different coastal zones. While storm surges can nowadays be reproduced accurately, the modeling of coastal flooding is more challenging, particularly when barrier breaches and wave overtopping have to be accounted for. The chronology of past marine floods can be reconstructed combining historical archives and sediment records. Sediment records of past marine floods localized in back barrier depressions are more adequate to reconstruct past flooding chronology. For the two last centuries, quantitative and descriptive historical data can be used to characterize past marine floods. Beyond providing a chronology of events, sediment records combined with geochronology, statistical analysis and climatology, can be used to reconstruct millennial-scale climate variability and enable a better understanding of the possible regional and local long-term trends in storm activity. Sediment records can also reveal forgotten flooding of exceptional intensity, much more intense than those of the last few decades. Sedimentological and historical archives, combined with high-resolution topographic data or numerical hindcast of storms can provide quantitative information and explanations for marine flooding processes. From these approaches, extreme past sea levels height can be determined and are very useful to complete time series provided by the instrumental measurements on shorter time scales. In particular, historical data can improve the determination of the return periods associated with extreme water levels, which are often inaccurate when computed based on instrumental data, due to the presence of gaps and too short time-series. Long-term numerical hindcast of tides and surges can also be used to provide the required time series for statistical analysis. Worst-case scenarios, used to define coastal management plans and strategies, can be obtained from realistic atmospheric settings with different tidal ranges and by shifting the trajectory of storms.Management of future crises and planning efforts to adapt to marine submersions are optimized by predictions of water levels from hydrodynamic models. Such predictions combined with in situ measurements and analysis of human stakes can be used to define a vulnerability index. Then, the efficiency of adaptation measures can be evaluated with respect to the number of lives that could be potentially saved. Numerical experiments also showed that the realignment of coastal defenses could result in water level reduction up to 1 m in the case where large marshes are flooded. Such managed realignment of coastal defenses may constitute a promising adaptation to storm-induced flooding and future sea level rise. From a legal perspective, only a few texts pay specific attention to the risk of marine flooding whether nationally or globally. Recent catastrophic events and their unintended consequences in terms of death and damages have triggered political decisions, like in USA after hurricane Katrina, and in France after catastrophic floods that occurred in 2010

Storm-induced marine flooding: Lessons from a multidisciplinary approach

International audienceThere is a growing interest for marine flooding related to recent catastrophic events and their unintended consequences in terms of casualties and damages, and to the increasing population and issues along the coasts in a context of changing climate. Consequently, the knowledge on marine flooding has progressed significantly for the last years and this review, focused on storm-induced marine submersions, responds to the need for a synthesis. Three main components are presented in the review: (1) a state-of-the-art on marine submersions from the viewpoint of several scientific disciplines; (2) a selection of examples demonstrating the added value of interdisciplinary approaches to improve our knowledge of marine submersions; (3) a selection of examples showing how the management of future crises or the planning efforts to adapt to marine submersions can be supported by new results or techniques from the research community.From a disciplinary perspective, recent progress was achieved with respect to physical processes, numerical modeling, the knowledge of past marine floods and vulnerability assessment. At a global scale, the most vulnerable coastal areas to marine flooding with high population density are deltas and estuaries. Recent and well-documented floods allow analyzing the vulnerability parameters of different coastal zones. While storm surges can nowadays be reproduced accurately, the modeling of coastal flooding is more challenging, particularly when barrier breaches and wave overtopping have to be accounted for. The chronology of past marine floods can be reconstructed combining historical archives and sediment records. Sediment records of past marine floods localized in back barrier depressions are more adequate to reconstruct past flooding chronology. For the two last centuries, quantitative and descriptive historical data can be used to characterize past marine floods. Beyond providing a chronology of events, sediment records combined with geochronology, statistical analysis and climatology, can be used to reconstruct millennial-scale climate variability and enable a better understanding of the possible regional and local long-term trends in storm activity. Sediment records can also reveal forgotten flooding of exceptional intensity, much more intense than those of the last few decades. Sedimentological and historical archives, combined with high-resolution topographic data or numerical hindcast of storms can provide quantitative information and explanations for marine flooding processes. From these approaches, extreme past sea levels height can be determined and are very useful to complete time series provided by the instrumental measurements on shorter time scales. In particular, historical data can improve the determination of the return periods associated with extreme water levels, which are often inaccurate when computed based on instrumental data, due to the presence of gaps and too short time-series. Long-term numerical hindcast of tides and surges can also be used to provide the required time series for statistical analysis. Worst-case scenarios, used to define coastal management plans and strategies, can be obtained from realistic atmospheric settings with different tidal ranges and by shifting the trajectory of storms.Management of future crises and planning efforts to adapt to marine submersions are optimized by predictions of water levels from hydrodynamic models. Such predictions combined with in situ measurements and analysis of human stakes can be used to define a vulnerability index. Then, the efficiency of adaptation measures can be evaluated with respect to the number of lives that could be potentially saved. Numerical experiments also showed that the realignment of coastal defenses could result in water level reduction up to 1 m in the case where large marshes are flooded. Such managed realignment of coastal defenses may constitute a promising adaptation to storm-induced flooding and future sea level rise. From a legal perspective, only a few texts pay specific attention to the risk of marine flooding whether nationally or globally. Recent catastrophic events and their unintended consequences in terms of death and damages have triggered political decisions, like in USA after hurricane Katrina, and in France after catastrophic floods that occurred in 2010

On the early fate of hydrothermal iron at deep-sea vents: A reassessment after in situ filtration

Deep-sea hydrothermal venting is now recognized as a major source of iron (Fe), an essential trace element that controls marine productivity. However, the reactions occurring during dispersal from buoyant plumes to neutrally buoyant hydrothermal plumes are still poorly constrained. Here we report for the first time on the dissolved-particulate partition of Fe after in situ filtration at the early stage of mixing at different hydrothermal discharges, i.e., Lucky Strike (37 degrees N), TAG (26 degrees N), and Snakepit (23 degrees N) on the Mid-Atlantic Ridge. We found that hydrothermal iron is almost completely preserved (>90%) in the dissolved fraction, arguing for low iron-bearing sulfide precipitation of iron in basalt-hosted systems with low Fe:H2S ratios. This result can only be explained by a kinetically limited formation of pyrite. The small part of Fe being precipitated as sulfides in the mixing gradient (<10%) is restricted to the inclusion of Fe in minerals of high Cu and Zn content. We also show that secondary venting is a source of Fe-depleted hydrothermal solutions. These results provide new constrains on Fe fluxes from hydrothermal venting