Quantum fluctuations of D5dD_{5d} polarons on C60C_{60} molecules

The dynamic Jahn-Teller splitting of the six equivalent $D_{5d}$ polarons due to quantum fluctuations is studied in the framework of the Bogoliubov-de Gennes formalism. The tunneling induced level splittings are determined to be $^2 T_{1u} \bigoplus ^2 T_{2u}$ and $^1 A_g \bigoplus ^1 H_g$ for $C_{60}^{1-}$ and $C_{60}^{2-}$, respectively, which should give rise to observable effects in experiments.Comment: REVTEX 3.0, 13 pages, to be published in Phys. Rev.

Theory of Spontaneous Polarization of Endohedral Fullerenes

A pseudo-Jahn-Teller model describing central atom distortions is proposed for endohedral fullerenes of the form A@C$_{60}$ where A is either a rare gas or a metal atom. A critical (dimensionless) coupling $g_c$ is found, below which the symmetric configuration is stable and above which inversion symmetry is broken. Vibronic parameters are given for selected endohedral fullerenes.Comment: 4 pages, REVTEX, 1 Postscript figure. [Phys. Rev. Lett. (in press)

Needle age-related and seasonal photosynthetic capacity variation is negligible for modelling yearly gas exchange of a sparse temperate Scots pine forest

In this study, we quantified the predictive accuracy loss involved with omitting photosynthetic capacity variation for a Scots pine (<i>Pinus sylvestris</i> L.) stand in Flanders, Belgium. Over the course of one phenological year, we measured the maximum carboxylation capacity at 25 &deg;C (<i>V</i>_m25), the maximum electron transport capacity at 25 &deg;C (<i>J</i>_m25), and the leaf area index (LAI) of different-aged needle cohorts in the upper and lower canopy. We used these measurements as input for a process-based multi-layer canopy model with the objective to quantify the difference in yearly gross ecosystem productivity (GEP) and canopy transpiration (<i>E</i>_can) simulated under scenarios in which the observed needle age-related and/or seasonal variation of <i>V</i>_m25 and <i>J</i>_m25 was omitted. We compared simulated GEP with estimations obtained from eddy covariance measurements. Additionally, we measured summer needle N content to investigate the relationship between photosynthetic capacity parameters and needle N content along different needle ages. <br><br> Results show that <i>V</i>_m25 and <i>J</i>_m25 were, respectively, 27% and 13% higher in current-year than in one-year old needles. A significant seasonality effect was found on <i>V</i>_m25, but not on <i>J</i>_m25. Summer needle N content was considerably lower in current-year than in one-year-old needles. As a result, the correlations between <i>V</i>_m25 and needle N content and <i>J</i>_m25 and needle N content were negative and non-significant, respectively. Some explanations for these unexpected correlations were brought forward. Yearly GEP was overestimated by the canopy model by &plusmn;15% under all scenarios. The inclusion and omission of the observed needle age-related <i>V</i>_m25 and <i>J</i>_m25 variation in the model simulations led to statistically significant but ecologically irrelevant differences in simulated yearly GEP and <i>E</i>_can. Omitting seasonal variation did not yield significant simulation differences. Our results indicate that intensive photosynthetic capacity measurements over the full growing season and separate simulation of needle age classes were no prerequisites for accurate simulations of yearly canopy gas exchange. This is true, at least, for the studied stand, which has a very sparse canopy and is exposed to high N deposition and, hence, is not fully representative for temperate Scots pine stands. Nevertheless, we believe well-parameterized process-based canopy models – as applied in this study – are a useful tool to quantify losses of predictive accuracy involved with canopy simplification in modelling

Exact zero-point energy shift in the e⊗(n E)e\otimes (n~E), t⊗(n H)t\otimes (n~H) many modes dynamic Jahn-Teller systems at strong coupling

We find the exact semiclassical (strong coupling) zero-point energy shifts applicable to the $e\otimes (n E)$ and $t\otimes (n H)$ dynamic Jahn-Teller problems, for an arbitrary number $n$ of discrete vibrational modes simultaneously coupled to one single electronic level. We also obtain an analytical formula for the frequency of the resulting normal modes, which has an attractive and apparently general Slater-Koster form. The limits of validity of this approach are assessed by comparison with O'Brien's previous effective-mode approach, and with accurate numerical diagonalizations. Numerical values obtained for $t\otimes (n H)$ with $n =8$ and coupling constants appropriate to C$_{60}^-$ are used for this purpose, and are discussed in the context of fullerene.Comment: 20 pages, 4 ps figure

The carbon budget of terrestrial ecosystems at country-scale – a European case study

We summed estimates of the carbon balance of forests, grasslands, arable lands and peatlands to obtain country-specific estimates of the terrestrial carbon balance during the 1990s. Forests and grasslands were a net sink for carbon, whereas croplands were carbon sources in all European countries. Hence, countries dominated by arable lands tended to be losing carbon from their terrestrial ecosystems, whereas forest-dominated countries tended to be sequestering carbon. In some countries, draining and extraction of peatlands caused substantial reductions in the net carbon balance. Net terrestrial carbon balances were typically an order of magnitude smaller than the fossil fuel-related carbon emissions. Exceptions to this overall picture were countries where population density and industrialization are small. It is, however, of utmost importance to acknowledge that the typically small net carbon balance represents the small difference between two large but opposing fluxes: uptake by forests and grasslands and losses from arable lands and peatlands. This suggests that relatively small changes in either or both of these large component fluxes could induce large effects on the net total, indicating that mitigation schemes should not be discarded a priori. In the absence of carbon-oriented land management, the current net carbon uptake is bound to decline soon. Protecting it will require actions at three levels; a) maintaining the current sink activity of forests, b) altered agricultural management practices to reduce the emissions from arable soils or turn into carbon sinks and c) protecting current large reservoirs (wetlands and old forests), since carbon is lost more rapidly than sequestered

Thermal adaptation of net ecosystem exchange

Thermal adaptation of gross primary production and ecosystem respiration has been well documented over broad thermal gradients. However, no study has examined their interaction as a function of temperature, i.e. the thermal responses of net ecosystem exchange of carbon (NEE). In this study, we constructed temperature response curves of NEE against temperature using 380 site-years of eddy covariance data at 72 forest, grassland and shrubland ecosystems located at latitudes ranging from ~29° N to 64° N. The response curves were used to define two critical temperatures: transition temperature (&lt;i&gt;T&lt;/i&gt;&lt;sub&gt;b&lt;/sub&gt;) at which ecosystem transfer from carbon source to sink and optimal temperature (&lt;i&gt;T&lt;/i&gt;&lt;sub&gt;o&lt;/sub&gt;) at which carbon uptake is maximized. &lt;i&gt;T&lt;/i&gt;&lt;sub&gt;b&lt;/sub&gt; was strongly correlated with annual mean air temperature. &lt;i&gt;T&lt;/i&gt;&lt;sub&gt;o&lt;/sub&gt; was strongly correlated with mean temperature during the net carbon uptake period across the study ecosystems. Our results imply that the net ecosystem exchange of carbon adapts to the temperature across the geographical range due to intrinsic connections between vegetation primary production and ecosystem respiration

A pictorial visualization of normal mode vibrations of the fullerene C_60 molecule in terms of vibrations of a hollow sphere

Understanding the normal mode vibrations of a molecule is important in the analysis of vibrational spectra. However, the complicated 3D motion of large molecules can be difficult to interpret. We show how images of normal modes of the fullerene molecule C60 can be made easier to understand by superimposing them on images of the normal mode vibrations of a thin spherical shell. We describe an interactive demonstration that allows the normal mode to be viewed with or without the shell. The images of the normal modes can be reoriented, and animated to show the vibration. In addition, supporting information includes images of all 174 normal modes of C60 in a common orientation, each of which can be animated. The ideas could be applied to other molecules in which the atoms all lie close to the surface of a sphere

Experiences from the implementation of sustainable development in higher education institutions: environmental management for sustainable universities

During the last decades several international initiatives have emphasised that education is an imperative for societies to become more sustainable. This special volume stream is comprised of 33 papers that illustrate some of the efforts being taken by higher education institutions to contribute to sustainability. The majority of the papers were presented at the European Roundtable on Sustainable Consumption and Production e Environmental Management for Sustainable Universities conference in Istanbul, Turkey in 2013. The papers address topics such as implementation of sustainable development, stakeholder engagement and participation, campus operations, sustainability reporting and assessment, organisational change management, and curriculum development. the papers in this special volume stream provide significant steps for the higher education for sustainable development discipline by exploring new and rethink theories, approaches, concepts, methods, and frameworks, as well as providing case studies and guidelines for practitioners. As the collection of papers shows, there have been many efforts in the implementation of sustainable development in higher education institutions; however, there are still many challenges to integrate sustainable development into their systems, and many opportunities for research in the topic.info:eu-repo/semantics/publishedVersio

A comparison of different methods for assessing leaf area index in four canopy types

The agreement of Leaf Area Index (LAI) assessments from three indirect methods, i.e. the LAI–2200 Plant Canopy Analyzer, the SS1 SunScan Canopy Analysis System and Digital Hemispherical Photography (DHP) was evaluated for four canopy types, i.e. a short rotation coppice plantation (SRC) with poplar, a Scots pine stand, a Pedunculate oak stand and amaize field. In the SRC and in the maize field, the indirect measurements were compared with direct measurements (litter fall and harvesting). In the low LAI range (0 to 2) the discrepancies of the SS1 were partly explained by the inability to properly account for clumping and the uncertainty of the ellipsoidal leaf angle distribu tion parameter. The higher values for SS1 in the medium (2 to 6) to high (6 to 8) ranges might be explained by gap fraction saturation for LAI–2200 and DHP above certain values. Wood area index –understood as the woody light blocking elements from the canopy with respect to diameter growth– accounted for overestimation by all indirect methods when compared to direct methods in the SRC. The inter-comparison of the three indirect methods in the four canopy types showed a general agreement for all methods in the medium LAI range (2 to 6). LAI–2200 and DHP revealed the best agreement among the indirect methods along the entire range of LAI (0 to 8) in all canopy types. SS1 showed some discrepancies with the LAI–2200 and DHP at low (0 to 2) and high ranges of LAI (6 to 8