On stoichiometry and intermixing at the spinel/perovskite interface in CoFe2O4/BaTiO3 thin films

The performance of complex oxide heterostructures depends primarily on the interfacial coupling of the two component structures. This interface character inherently varies with the synthesis method and conditions used since even small composition variations can alter the electronic, ferroelectric, or magnetic functional properties of the system. The focus of this article is placed on the interface character of a pulsed laser deposited CoFe2O4/BaTiO3 thin film. Using a range of state-of-the-art transmission electron microscopy methodologies, the roles of substrate morphology, interface stoichiometry, and cation intermixing are determined on the atomic level. The results reveal a surprisingly uneven BaTiO3 substrate surface formed after the film deposition and Fe atom incorporation in the top few monolayers inside the unit cell of the BaTiO3 crystal. Towards the CoFe2O4 side, a disordered region extending several nanometers from the interface was revealed and both Ba and Ti from the substrate were found to diffuse into the spinel layer. The analysis also shows that within this somehow incompatible composite interface, a different phase is formed corresponding to the compound Ba2Fe3Ti5O15, which belongs to the ilmenite crystal structure of FeTiO3 type. The results suggest a chemical activity between these two oxides, which could lead to the synthesis of complex engineered interfaces

Directional Dependence of ΛCDM Cosmological Parameters

We study hemispherical power asymmetry in the Wilkinson Microwave Anisotropy Probe 9 yr data. We analyze the combined V- and W-band sky maps, after application of the KQ85 mask, and find that the asymmetry is statistically significant at the 3.4σ confidence level for ℓ = 2-600, where the data are signal-dominated, with a preferred asymmetry direction (l, b) = (227, –27). Individual asymmetry axes estimated from six independent multipole ranges are all consistent with this direction. Subsequently, we estimate cosmological parameters on different parts of the sky and show that the parameters A_s, n_s , and Ω_b are the most sensitive to this power asymmetry. In particular, for the two opposite hemispheres aligned with the preferred asymmetry axis, we find n_s = 0.959 ± 0.022 and n_s = 0.989 ± 0.024, respectively

Learning what to remember: vocabulary knowledge and children’s memory for object names and features

Although young children can map a novel name to a novel object, it remains unclear what they actually remember about objects when they initially make such a name-object association. In the current study we investigated 1) what children remembered after they were initially introduced to name-object associations and 2) how their vocabulary size and vocabulary structure influenced what they remembered. As a group, children had difficulty remembering each of the features of the original novel objects. Further analyses revealed that differences in vocabulary structure predicted children’s ability to remember object features. Specifically, children who produced many names for categories organized by similarity in shape (e.g., ball, cup) had the best memory for newly-learned objects’ features—especially their shapes. In addition, the more features children remembered, the more likely they were to retain the newly-learned name-object associations. Vocabulary size, however, was not predictive of children’s feature memory or retention. Taken together, these findings demonstrate that children’s existing vocabulary structure, rather than simply vocabulary size, influences what they attend to when encountering a new object and subsequently their ability to remember new name-object associations

Spectral Properties of Acoustic Gravity Wave Turbulence

The nonlinear turbulent interactions between acoustic gravity waves are investigated using two dimensional nonlinear fluid simulations. The acoustic gravity waves consist of velocity and density perturbations and propagate across the density gradients in the vertical direction in the Earth's atmosphere. We find that the coupled two component model exhibits generation of large scale velocity potential flows along the vertical direction, while the density perturbations relax towards an isotropic random distribution. The characteristic turbulent spectrum associated with the system has a Kolmogorov-like feature and tends to relax towards a $k^{-5/3}$ spectrum, where $k$ is a typical wavenumber. The cross field diffusion associated with the velocity potential grows linearly and saturates in the nonlinear phase

Dielectric properties characterization of La- and Dy-doped BiFeO3 thin films

The dielectric response of La- and Dy- doped BiFeO3 thin films at microwave frequencies (up to 12 GHz) has been monitored as a function of frequency, direct current (dc) electric field, and magnetic field in a temperature range from 25 to 300 °C. Both the real and imaginary parts of the response have been found to be non-monotonic (oscillating) functions of measuring frequency. These oscillations are not particularly sensitive to a dc electric field; however, they are substantially dampened by a magnetic field. The same effect has been observed when the volume of the characterized sample is increased. This phenomenon is attributed to the presence of a limited number of structural features with a resonance type response. The exact origin of these features is unknown at present. Leakage current investigations were performed on the whole set of films. The films were highly resistive with low leakage current, thereby giving us confidence in the microwave measurements. These typically revealed ‘N'-type I-V characteristic

Searching for hidden mirror symmetries in CMB fluctuations from WMAP 7 year maps

We search for hidden mirror symmetries at large angular scales in the WMAP 7 year Internal Linear Combination map of CMB temperature anisotropies using global pixel based estimators introduced for this aim. Two different axes are found for which the CMB intensity pattern is anomalously symmetric (or anti-symmetric) under reflection with respect to orthogonal planes at the 99.84(99.96)% CL (confidence level), if compared to a result for an arbitrary axis in simulations without the symmetry. We have verified that our results are robust to the introduction of the galactic mask. The direction of such axes is close to the CMB kinematic dipole and nearly orthogonal to the ecliptic plane, respectively. If instead the real data are compared to those in simulations taken with respect to planes for which the maximal mirror symmetry is generated by chance, the confidence level decreases to 92.39 (76.65)%. But when the effect in question translates into the anomalous alignment between normals to planes of maximal mirror (anti)-symmetry and these natural axes mentioned. We also introduce the representation of the above estimators in the harmonic domain, confirming the results obtained in the pixel one. The symmetry anomaly is shown to be almost entirely due to low multipoles, so it may have a cosmological and even primordial origin. Contrary, the anti-symmetry one is mainly due to intermediate multipoles that probably suggests its non-fundamental nature. We have demonstrated that these anomalies are not connected to the known issue of the low variance in WMAP observations and we have checked that axially symmetric parts of these anomalies are small, so that the axes are not the symmetry ones.Comment: 18 pages, 10 figures, 2 tables. Consideration and discussion expanded, 5 figures and 1 table added, main conclusions unchange

Crossing the Dripline to 11N Using Elastic Resonance Scattering

The level structure of the unbound nucleus 11N has been studied by 10C+p elastic resonance scattering in inverse geometry with the LISE3 spectrometer at GANIL, using a 10C beam with an energy of 9.0 MeV/u. An additional measurement was done at the A1200 spectrometer at MSU. The excitation function above the 10C+p threshold has been determined up to 5 MeV. A potential-model analysis revealed three resonance states at energies 1.27 (+0.18-0.05) MeV (Gamma=1.44 +-0.2 MeV), 2.01(+0.15-0.05) MeV, (Gamma=0.84 +-$0.2 MeV) and 3.75(+-0.05) MeV, (Gamma=0.60 +-0.05 MeV) with the spin-parity assignments I(pi) =1/2+, 1/2- and 5/2+, respectively. Hence, 11N is shown to have a ground state parity inversion completely analogous to its mirror partner, 11Be. A narrow resonance in the excitation function at 4.33 (+-0.05) MeV was also observed and assigned spin-parity 3/2-.Comment: 14 pages, 9 figures, twocolumn Accepted for publication in PR

Barrier penetration and rotational damping of thermally excited superdeformed nuclei

We construct a microscopic model of thermally excited superdeformed states that describes both the barrier penetration mechanism, leading to the decay-out transitions to normal deformed states, and the rotational damping causing fragmentation of rotational E2 transitions. We describe the barrier penetration by means of a tunneling path in the two-dimensional deformation energy surface, which is calculated with the cranked Nilsson-Strutinsky model. The individual excited superdeformed states and associated E2 transition strengths are calculated by the shell model diagonalization of the many-particle many-hole excitations interacting with the delta-type residual two-body force. The effect of the decay-out on the excited superdeformed states are discussed in detail for $^{152}$Dy, $^{143}$Eu and $^{192}$Hg.Comment: 33pages, 32 figures, submitted to Nucl.Phys.

The molybdenum isotopic composition of the modern ocean

Natural variations in the isotopic composition of molybdenum (Mo) are showing increasing potential as a tool in geochemistry. Although the ocean is an important reservoir of Mo, data on the isotopic composition of Mo in seawater are scarce. We have recently developed a new method for the precise determination of Mo isotope ratios on the basis of preconcentration using a chelating resin and measurement by multiple-collector inductively coupled plasma mass spectrometry (MC-ICP-MS), which allows us to measure every stable Mo isotope. In this study, 172 seawater samples obtained from 9 stations in the Pacific, Atlantic, and Southern Oceans were analyzed, giving global coverage and the first full depth-profiles. The average isotope composition in δA/95Mo (relative to a Johnson Matthey Mo standard solution) was as follows: δ92/95Mo = –2.54 ± 0.16‰ (2SD), δ94/95Mo = –0.73 ± 0.19‰, δ96/95Mo = 0.85 ± 0.07‰, δ97/95Mo = 1.68 ± 0.08‰, δ98/95Mo = 2.48 ± 0.10‰, and δ100/95Mo = 4.07 ± 0.18‰. The δ values showed an excellent linear correlation with atomic mass of AMo (R2 = 0.999). Three-isotope plots for the Mo isotopes were fitted with straight lines whose slopes agreed with theoretical values for mass-dependent isotope fractionation. These results demonstrate that Mo isotopes are both uniformly distributed and follow a mass-dependent fractionation law in the modern oxic ocean. A common Mo standard is urgently required for the precise comparison of Mo isotopic compositions measured in different laboratories. On the other hand, our results strongly support the possibility of seawater as an international reference material for Mo isotopic composition