The diversity of odonata and their endophytic ovipositions from the upper oligocene fossillagerstätte of rott (Rhineland, Germany)

A commented list of fossil Odonata from the Oligocene outcrop of Rott is given, together with descriptions of new traces of oviposition in plant tissues, very similar to ichnotaxa already known from the early Eocene Laguna del Hunco floras of Patagonia. The joint presences of odonatan larvae and traces of oviposition demonstrate the autochthony of these insects in the palaeolake of Rott, confirming the existence of a diverse and abundant aquatic entomofauna, a situation strikingly different to that in the contemporaneous Oligocene palaeolake of Céreste (France).Fil: Petrulevicius, Julian Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Naturales y Museo. División Paleozoología Invertebrados; ArgentinaFil: Wappler, Torsten. Universitat Bonn; AlemaniaFil: Nel, André. Muséum National d'Histoire Naturelle; FranciaFil: Rust, Jes. Universitat Bonn; Alemani

Relatório de estágio em farmácia comunitária

Relatório de estágio realizado no âmbito do Mestrado Integrado em Ciências Farmacêuticas, apresentado à Faculdade de Farmácia da Universidade de Coimbr

Synthèse et caractérisations structurales et magnétiques de quelques nouveaux oxydes mixtes des métaux de transition

No abstractPas de résum

True flies (Insecta: Diptera) from the late Eocene insect limestone (Bembridge Marls) of the Isle of Wight, England, UK

The Diptera fauna from the late Eocene of the Isle of Wight (Bembridge Marls) is studied including redescriptions of formerly described material. The fauna includes the following taxa: Anisopodidae – one species; Bibionidae – 11 species; Ceratopogonidae – one described and two unidentified species; Chironomidae – undetermined species of three subfamilies; Culicidae – four species; Cylindrotomidae – one species; Dixidae – one species; Keroplatidae – one described and four unidentified species; Limoniidae – 31 species; Mycetophilidae – 14 species; Psychodidae – two species; Scatopsidae – two species; Sciaridae – three species; Simuliidae – an unnamed species; Tipulidae – nine species. Diptera Brachycera: Agromyzidae – unidentified species; Anthomyzidae – two species; Asilidae – two species; Bombyliidae – one species; Chloropidae – one species; Dolichopodidae – unidentified species; Empididae – unidentified species; Ephydridae – two species; Heleomyzidae – unidentified species; Lauxaniidae – unidentified species; Otitidae – one species; Phoridae – unidentified species; Rhagionidae – two species; Stratiomyidae – two species; Syrphidae – unidentified species; Tabanidae – one species. Following new taxa are described: Leptotarsus (Longurio) fragmentatus Krzemiński, n. sp., Leptotarsus (Longurio) wegiereki Krzemiński, n. sp., Tipula (s. lato) anglicana Krzemiński, n. sp. (Tipulidae); Cyttaromyia rossi Krzemiński, n. sp. (Cylindrotomidae); Gurnardia corami Krzemiński, n. gen, n. sp., Pilaria hooleyi Krzemiński, n. sp., Pilaria volodii Krzemiński, n. sp., Cheilotrichia (Cheilotrichia) duplicata Krzemiński, n. sp., Cheilotrichia (Empeda) szwedoi Krzemiński, n. sp., Symplecta (Psiloconopa) gurnetensis Krzemiński, n. sp., Orimarga (Orimarga) lenae Krzemiński, n. sp., Dicranomyia (Dicranomyia) azari Krzemiński, n. sp., Dicranomyia (Dicranomyia) fasciata Krzemiński, n. sp., Helius (Helius) edmundi Krzemiński, n. sp., Helius (Helius) popovi Krzemiński, n. sp., Dicranoptycha staryi Krzemiński, n. sp. (Limoniidae); Wightipsychoda Azar, n. gen. (Psychodidae); Dilophus andrewrossi Nel, Colomb & Waller, n. sp., Bibiodes massiliensis Nel, Colomb & Waller, n. sp. (Bibionidae); Azana cockerelli Blagoderov, n. sp., Aglaomyia vectis Blagoderov, n. sp., Dziedzickia oligocenica Blagoderov, n. sp., Palaeoempalia saxea Blagoderov, n. sp., Mycomya hoolei Blagoderov, n. sp., Leia gurnardensis Blagoderov, n. sp. (Mycetophilidae); Regmoclemina haennii Krzemiński, n. sp. (Scatopsidae); Sylvicola problematica Krzemiński, n. sp. (Anisopodidae); Palaeoberidops barkeri Nicholson, n. gen., n. sp. (Stratiomyidae). The Diptera fauna and palaeohabitat of the Insect Bed is discussed

True flies (Insecta: Diptera) from the late Eocene insect limestone (Bembridge Marls) of the Isle of Wight, England, UK

The Diptera fauna from the late Eocene of the Isle of Wight (Bembridge Marls) is studied including redescriptions of formerly described material. The fauna includes the following taxa: Anisopodidae – one species; Bibionidae – 11 species; Ceratopogonidae – one described and two unidentified species; Chironomidae – undetermined species of three subfamilies; Culicidae – four species; Cylindrotomidae – one species; Dixidae – one species; Keroplatidae – one described and four unidentified species; Limoniidae – 31 species; Mycetophilidae – 14 species; Psychodidae – two species; Scatopsidae – two species; Sciaridae – three species; Simuliidae – an unnamed species; Tipulidae – nine species. Diptera Brachycera: Agromyzidae – unidentified species; Anthomyzidae – two species; Asilidae – two species; Bombyliidae – one species; Chloropidae – one species; Dolichopodidae – unidentified species; Empididae – unidentified species; Ephydridae – two species; Heleomyzidae – unidentified species; Lauxaniidae – unidentified species; Otitidae – one species; Phoridae – unidentified species; Rhagionidae – two species; Stratiomyidae – two species; Syrphidae – unidentified species; Tabanidae – one species. Following new taxa are described: Leptotarsus (Longurio) fragmentatus Krzemiński, n. sp., Leptotarsus (Longurio) wegiereki Krzemiński, n. sp., Tipula (s. lato) anglicana Krzemiński, n. sp. (Tipulidae); Cyttaromyia rossi Krzemiński, n. sp. (Cylindrotomidae); Gurnardia corami Krzemiński, n. gen, n. sp., Pilaria hooleyi Krzemiński, n. sp., Pilaria volodii Krzemiński, n. sp., Cheilotrichia (Cheilotrichia) duplicata Krzemiński, n. sp., Cheilotrichia (Empeda) szwedoi Krzemiński, n. sp., Symplecta (Psiloconopa) gurnetensis Krzemiński, n. sp., Orimarga (Orimarga) lenae Krzemiński, n. sp., Dicranomyia (Dicranomyia) azari Krzemiński, n. sp., Dicranomyia (Dicranomyia) fasciata Krzemiński, n. sp., Helius (Helius) edmundi Krzemiński, n. sp., Helius (Helius) popovi Krzemiński, n. sp., Dicranoptycha staryi Krzemiński, n. sp. (Limoniidae); Wightipsychoda Azar, n. gen. (Psychodidae); Dilophus andrewrossi Nel, Colomb & Waller, n. sp., Bibiodes massiliensis Nel, Colomb & Waller, n. sp. (Bibionidae); Azana cockerelli Blagoderov, n. sp., Aglaomyia vectis Blagoderov, n. sp., Dziedzickia oligocenica Blagoderov, n. sp., Palaeoempalia saxea Blagoderov, n. sp., Mycomya hoolei Blagoderov, n. sp., Leia gurnardensis Blagoderov, n. sp. (Mycetophilidae); Regmoclemina haennii Krzemiński, n. sp. (Scatopsidae); Sylvicola problematica Krzemiński, n. sp. (Anisopodidae); Palaeoberidops barkeri Nicholson, n. gen., n. sp. (Stratiomyidae). The Diptera fauna and palaeohabitat of the Insect Bed is discussed

A cobalt oxide–polypyrrole nanocomposite as an efficient and stable electrode material for electrocatalytic water oxidation

International audienceDeveloping electrolyzers operating under neutral or near-neutral conditions with catalysts based only on earth-abundant metals is highly desirable with a view to reduce the cost of hydrogen production from water splitting reaction and avoid the environmental issues related to corrosion usually encountered with alkaline electrolyzers. Herein, we report a highly active and stable anode material for oxygen evolving reaction (OER) in mild-pH conditions based on cobalt oxide-nanoparticles embedded into a poly(pyrrole-alkylammonium) matrix (denoted PPN+-CoOx). Examples of hybrid materials combining metal oxide nanoparticles as OER catalysts within a polymer film are still rare. However, they are very promising to control the formation and the size of metal particles in view to enhance the electrochemically active surface area and thus the electrocatalytic performances. Our strategy consists in electroprecipitating Co0 nanoparticles by reduction of an anionic cobalt oxalate complex into the cationic PPN+ film, the latter being previously deposited onto an electrode surface by electropolymerization. The Co0 nanoparticles within the composite are then partially in-situ oxidized under air exposure into CoO, and then finally fully oxidized into CoOx by successive scans between 0 and 1.2 V vs Ag/AgCl in a borate buffer at pH 9.2. This nanocomposite material is highly structured with around 30 nm-large CoOx nanoparticles well dispersed into the polypyrrole film conferring a high OER electrocatalytic activity at near neutral pH of 9.2 with exceptional values of mass activity and turnover frequency of 3.01 A mg-1 and 0.46 s-1 respectively, at an overpotential of 0.61 V and with a cobalt loading of 1.34 µg cm-2. These performances place the PPN+-CoOx electrode among the most active anodes described in the literature employing cobalt oxide under mild pH conditions. In addition, when the PPN+-CoOx material is electrodeposited on carbon paper with a higher roughness than a simple carbon electrode, the physisorption of the film on the electrode is considerably enhanced resulting in a stable catalytic current over more than 43 h. Post electrolysis characterizations by SEM and EDX confirm the integrity of the PPN+-CoOx material after long hours of electrocatalysis. This demonstrates the beneficial role of the polypyrrole matrix in the achievement of very stable and highly active anodes for water oxidation