Complementary use of TEM and APT for the investigation of steels nanostructured by severe plastic deformation

The properties of bulk nanostructured materials are often controlled by atomic scale features like segregation along defects or composition gradients. Here we discuss about the complimentary use of TEM and APT to obtain a full description of nanostructures. The advantages and limitations of both techniques are highlighted on the basis of experimental data collected in severely deformed steels with a special emphasis on carbon spatial distribution

Technological potential of logistics service providers and the relationship dynamics.

Notre papier porte sur plusieurs résultats d'une enquête effectuée auprès des prestataires logistiques français. L'idée défendue est que l'effort technologique des prestataires de services logistiques contribue à la performance de la relation et plus généralement de la chaîne logistique dans sa globalité. Etre innovant semble constituer un indicateur d'autonomie et de capacité à copiloter les flux. L'effort technologique apparaît ainsi comme une trajectoire stratégique de différenciation pertinente pour les prestataires logistiques.logistic, service providers

Nanostructure and properties of a Cu-Cr composite processed by severe plastic deformation

A Cu-Cr composite was processed by severe plastic deformation to investigate the role of interphase boundaries on the grain size reduction mechanisms. The as-deformed material exhibits a grain size of only 20nm. This gives rise to a dramatic increase of the hardness. Some deformation induced Cu super saturated solid solutions were clearly exhibited and it is shown that they decrease the hardness. The formation of such supersaturated solid solution and their influence on the mechanical properties are discussed

Mechanical alloying of Cu and Fe induced by severe plastic deformation of a Cu-Fe composite

A filamentary composite elaborated by cold drawing was processed by High Pressure Torsion (HPT). The nanostructure resulting from this severe plastic deformation (SPD) was investigated thanks to scanning electron microscopy, transmission electron microscopy, X-ray diffraction and 3D atom probe. Although the mutual solubility of Cu and Fe is extremely low at room temperature in equilibrium conditions, it is shown that nanoscaled Fe clusters dissolve in the Cu matrix. The non-equilibrium copper supersaturated solid solutions contain up to 20at.% Fe. The driving force of the dissolution is attributed to capillary pressures and mechanisms which could enhanced the atomic mobility during HPT are discussed. We conclude that the interdiffusion is the result of a dramatic increase of the vacancy concentration during SPD.Comment: 20 page

Chemical behavior of tungstate solutions. Part 1. A spectroscopic survey of the species involved

This study is focused on the composition and the evolution of tungstate ions solutions as a function of pH and increasing concentrations. The Raman analysis showed that, during the titration of the tungstate solutions, WO4 2−, HWO4 − ions and probably W2O7 2−, HW2O7 2− and H2W2O7 solvated species could exist in aqueous solutions. For diluted solutions, additions of a strong acid does not cause any precipitation, whereas the formation of the unstable solid tungstic acid (H2WO4 or WO3·H2O) could occur in concentrated solutions

Secure Silicon: Towards Virtual Prototyping

Evaluating security vulnerabilities of software implementations at design step is of primary importance for applications developers, while it has received litte attention from scientific communauty. In this paper, we describe virtual prototyping of an implementation of Elliptic curve cryptography (ECC), aiming to make it secure against first-order horizontal and vertical side-channel attacks (SCAs). Reproducing information leakage as close to reality as possible requires bit- and clock-cycle accuracy, we got with Mentor Graphics Modelsim tool, simulating the execution of the ECC software implementations on PULPino, an open-source 32-bit microcontroller based on the recently released RISC-V instruction set architecture. For each clock cycle, we compute the number of bit toggles into microcontroller's registers, an image of the power consumption, and watch the program counter to identify the assembly instruction executed, then the corresponding C function. We first start with a naive double-and-add implementation relying on cryptographic primitives of the mbed TLS library, formerly PolarSSL before acquisition by ARM. The virtual analysis pinpoints differences in the way the double function on one side and the add function on the other side manage variables and internal operations, which can be used for horizontal SCAs. We propose some modifications of the C code, hence independent of the considered microcontroller, with an overhead extremely small compared to that of the double-and-add-always countermeasure. Then, we reiterate analyses, still for the mbed TLS library, but using the regular Montgomery ladder version, most used in practice as more efficient

Decomposition process in a FeAuPd alloy nanostructured by severe plastic deformation

The decomposition process mechanisms have been investigated in a Fe50Au25Pd25 (at.%) alloy processed by severe plastic deformation. Phases were characterized by X-ray diffraction and microstructures were observed using transmission electron microscopy. In the coarse grain alloy homogenized and aged at $450 ^{circ}\mathrm{C}$, the bcc \alpha-Fe and fcc AuPd phases nucleate in the fcc supersaturated solid solution and grow by a discontinuous precipitation process resulting in a typical lamellar structure. The grain size of the homogenized FeAuPd alloy was reduced in a range of 50 to 100nm by high pressure torsion. Aging at $450 ^{circ}\mathrm{C}$ this nanostructure leads to the decomposition of the solid solution into an equi-axed microstructure. The grain growth is very limited during aging and the grain size remains under 100nm. The combination of two phases with different crystallographic structures (bcc \alpha-Fe and fcc AuPd) and of the nanoscaled grain size gives rise to a significant hardening of the allo

INAUT, a Controlled Language for the French Coast Pilot Books Instructions nautiques

We describe INAUT, a controlled natural language dedicated to collaborative update of a knowledge base on maritime navigation and to automatic generation of coast pilot books (Instructions nautiques) of the French National Hydrographic and Oceanographic Service SHOM. INAUT is based on French language and abundantly uses georeferenced entities. After describing the structure of the overall system, giving details on the language and on its generation, and discussing the three major applications of INAUT (document production, interaction with ENCs and collaborative updates of the knowledge base), we conclude with future extensions and open problems.Comment: 10 pages, 3 figures, accepted for publication at Fourth Workshop on Controlled Natural Language (CNL 2014), 20-22 August 2014, Galway, Irelan