Cross-domain consequences of workplace bullying: A multi-source daily diary study

In this multi-source daily diary study we examine the effect of exposure to workplace bullying behaviors on family domain outcomes (conflicts at home, relationship satisfaction), and the mediating role that psychological detachment and affective distress play in this relationship. A sample of 68 employees and their spouses filled in a quantitative diary for 5 consecutive working days twice a day (N occasions = 680). Multilevel analyses showed that daily workplace bullying positively predicted both self-report and spouse-report conflicts at home, and daily psychological detachment mediated this relationship. In addition, daily affective distress was the mediator only for self-report conflicts at home. Further, it was found an indirect effect of both affective distress and detachment on the relationship between bullying and self-reported relationship satisfaction. Detachment also showed an indirect role in the association between bullying and spouse-reported relationship satisfaction. To our knowledge, this is one of the first studies in showing that negative effects of workplace bullying go beyond the work setting and beyond the employee. Moreover, this study adds to an emerging line of research exploring how daily negative work experiences are transferred to and interferes with the non-work domain. The theoretical and practical implications of these findings are discussed

La europeización de Grecia y los antecedentes de su temprano acceso a la Europa comunitaria

Resumen: La historia contemporánea de Grecia permite distinguir entre una vinculación temprana del país al proceso de integración de Europa, al inicio de la segunda posguerra mundial, y una europeización más tardía, a partir de 1975, cuando comienza a tramitarse su adhesión a las Comunidades Europeas. El artículo aborda estas dos cuestiones desde una perspectiva histórica, así como el impacto del proceso de europeización sobre las estructuras y la dinámica del sistema político griego. La pertenencia a la UE ha significado para Grecia un verdadero apoyo para la democratización y modernización del país. Aquí, la europeización propiamente dicha, aunque pretendida, ha sido más tardía de lo que cabía esperar, y ha suscitado en un principio resistencias. Sin embargo, conforme avanzaban los años noventa, ha habido verdaderamente cambios significativos al respecto. Palabras clave: Grecia, integración europea, europeización, Unión Europea, política exterior. Abstract: Greece’s recent political history makes it possible to distinguish between the country’s engagement with the European integration process, soon after the Second World War, and its Europeanization itself, since 1975, when Greece applied to join the European Community. This article addresses both issues from a historical perspective. It also evaluates the impact of Europeanization in the structure and procedures of the Greek political system. For Greece, EU membership has been seen, from the beginning, as a means of encouraging democratization in the country, as well as an external stimulus for advancing modernization. Here Europeanization refers precisely to an intended yet belated process. However, despite initial resistance, EU-influenced domestic changes have become increasingly significant since the mid-1990s. Keywords: Greece, European integration, Europeanization, European Union, foreign polic

Estudio comparativo del fraccionamiento de los carbohidratos de la miel mediante tratamiento con carbón activo y levaduras para la detección de adulteraciones

Recientemente se ha descrito la utilidad de los anhídridos de difructosa (DFAs) como buenos marcadores para la detección de adulteraciones de miel con jarabes de alto contenido en fructosa (HFCS) y de azúcar invertido (IS). Sin embargo, para la detección de estos compuestos es necesario realizar un fraccionamiento previo de los carbohidratos de estas muestras, dado que la alta concentración de monosacáridos (glucosa y fructosa) presentes en la miel dificulta el análisis de los compuestos minoritarios. Por tanto, el objetivo de este trabajo se basó en la comparación de un tratamiento con levaduras propuesto con anterioridad y un fraccionamiento con carbónactivo para eliminar la fracción de monosacáridos,concentrando así los compuestos minoritarios de la miely en concreto los DFAs presentes en muestras adulteradas.Se llevó a cabo la optimización de dichos métodos para conseguir el mayor enriquecimiento en DFAs comprobándose que ambos son útiles para la detección de adulteraciones de miel de hasta un 5% de HFCS e IS

Prácticas y teorías de descubrir paisajes: Viajeras y cultivadoras del estudio de la geografía en España, desde fi nales del siglo XIX hasta el primer tercio del XX

The purpose of this article is to present on one hand, how travelling from one country to another helped women travellers break free from the feminine stereotype of their time; and on the other hand, their experiences travelling became an inspiration for other women to teach geography. The travels of these women and the method of teaching geography that they inspired are connected the joy of travelling and the pleasure of learning about the environment.El propósito de este artículo es presentar; por un lado, cómo el cambiar de país ayudó a las viajeras para rasgar sutilmente con el canon estereotipado de mujer, fijado por el discurso oficial burgués del momento y por otro, cómo la difusión social, tanto de las experiencias por diferentes lugares del mundo como el avance de la Geografía, pasó de la mano de mujeres, especialistas en las ciencias sociales y naturales, a los ámbitos educativos, para fomentar una enseñanza del entorno respetuosa con mujeres y hombres. Los viajes y el método de enseñar Geografía quedan enlazados por la forma en que se conectaron el placer de viajar y el gozo de aprender, acerca del medio circundante

Positive Experiences at Work and Daily Recovery: Effects on Couple’s Well-Being

The present diary study investigates, at the within-person level, how job satisfaction mediates the relationship between self-rated job performance and recovery experiences (i.e., psychological detachment from work and relaxation) during off-job time. Furthermore, we explore the effects of these two recovery experiences on couple´s well-being. Data were collected from 145 dual-earner couples (N = 290 participants; N = 1450 occasions) with a daily diary design (five consecutive working days). Multilevel analyses showed that daily job performance positively predicted psychological detachment and relaxation, and that daily job satisfaction partially mediated this relationship. In addition, we found that psychological detachment and relaxation have positive effects on own and partner´s indicators of well-being (i.e., relationship satisfaction and positive emotions). The benefits of recovery go beyond the individual and affect their partner´s level of well-being

Chemical modification of titanium precursor to obtain stable silica-titania sol: acetylacetone

[ES] La técnica Sol-Gel se ha utilizado para sintetizar una serie de sistemas multicomponentes, entre ellos SiO2 – TiO2. El mayor problema en la obtención de geles multicomponentes estables es la desigual velocidad de hidrólisis y condensación que presentan los alcóxidos precursores de los cationes de interés. En este trabajo se muestra cómo adicionando acetilacetona, acacH, al sistema TEOS – Ti(OBu)4 – H2O se puede obtener un sol estable. Se tomaron diferentes concentraciones de los precursores de silicio y titanio y una sola concentración de acacH. Se utilizó espectroscopia infrarroja, FTIR, para identificar los grupos funcionales presentes en el sistema y además se midió regularmente la viscosidad para determinar cualitativamente el avance de la policondensación del sistema.[EN] Sol-gel processing has become a well established technique for producing ceramic powders or glasses. This processing has been utilized to synthesize several interesting systems, e.g. the SiO2 – TiO2 system. A major concern in the stable multicomponent geles is that the hydrolysis and condensation velocities are diferent for each precursor, TEOS and Ti(OBu)4 in this work. The chemical control of these reactions is currently performed by adding complexing reagents that react with metal alkoxides at a molecular level, giving rise to new molecular precursors of different structure, reactivity and functionanality. This paper shows that stable TEOS – Ti(OBu)4 – H2O sol can be reproducibly prepared in the presence of acetylacetone. We shall then show that the acac behaves as a ligand, directly bonded to the titanium ion. Thus the formation of precipitate is avoided. Infra-red spectroscopy (FTIR) and viscosity measures were used to demostrated this behaviour of the system.Este trabajo fue financiado a través de los proyectos COLCIENCIAS N° 1103-05-605-93 y VRI-Universidad del Cauca N° 752. Agradecemos a Ecopetrol-ICP la colaboración prestada con los estudios de espectroscopia infrarroja y a la red CyTED VIII.E la ayuda económica y técnica gracias a la cual A. Mafla pudo realizar su pasantía en el ICVCSIC de Madrid-España.Peer reviewe

Structural changes in biscuits made with cellulose emulsions as fat replacers

[EN] Biscuits are a popular baked cereal food much appreciated by consumers. In the last few years, cellulose derivatives have been successfully used as fat replacers in biscuits. In this way, not only is the total amount of fat reduced but also the saturated fatty acids and the trans fatty acids are eliminated. The aim of this study is to increase understanding of the functionality of different cellulose ether emulsions used as fat replacers in biscuits. For this purpose, three emulsions with different cellulose ethers were designed: hydroxypropyl methylcellulose, methylcellulose and methylcellulose with greater methoxyl substitution (MCH). The microstructure and textural properties of the doughs and biscuits prepared with these emulsions were studied and the effects of cellulose types and glycerol as textural improver were also analysed. The results showed that the incorporation of glycerol in the doughs made with methylcellulose and hydroxypropyl methylcellulose cellulose emulsions seems to make the dough softer, bringing the values closer to those of the control dough; however, this effect disappears once the dough is baked. The presence of glycerol does not seem to have an effect on the hardness of the doughs and biscuits made using the methylcellulose with greater methoxyl substitution (MCH) emulsion.The author(s) disclosed receipt of the following financial support for the research, authorship, and/or publication of this article: The authors are grateful to the Spanish Ministry of Economy and Competitiveness for financial support (AGL2015-68923-C2) and gratefully acknowledge the financial support of EU FEDER funds.Teresa Sanz; Quiles Chuliá, MD.; Salvador Alcaraz, A.; Hernando Hernando, MI. (2017). Structural changes in biscuits made with cellulose emulsions as fat replacers. Food Science and Technology International. 23(6):480-489. https://doi.org/10.1177/1082013217703273S48048923

Characterization of goat colostrum oligosaccharides by nano-liquid chromatography on chip quadrupole time-of-flight mass spectrometry and hydrophilic interaction liquid chromatography-quadrupole mass spectrometry

A detailed qualitative and quantitative characterization of goat colostrum oligosaccharides (GCO) has been carried out for the first time. Defatted and deproteinized colostrum samples, previously treated by size exclusion chromatography (SEC) to remove lactose, were analyzed by nanoflow liquid chromatography–quadrupole-time of flight mass spectrometry (Nano-LC-Chip–Q-TOF MS). Up to 78 oligosaccharides containing hexose, hexosamine, fucose, N-acetylneuraminic acid or Nglycolylneuraminic acid monomeric units were identified in the samples, some of them detected for the first time in goat colostra. As a second step, a hydrophilic interaction liquid chromatography coupled to mass spectrometry (HILIC-MS) methodology was developed for the separation and quantitation of the main GCO, both acidic and neutral carbohydrates. Among other experimental chromatographic conditions, mobile phase additives and column temperature were evaluated in terms of retention time, resolution, peak width and symmetry of target carbohydrates. Narrow peaks (wh: 0.2–0.6 min) and good symmetry (As: 0.8–1.4) were obtained for GCO using an acetonitrile:water gradient with 0.1% ammonium hydroxide at 40 ◦C. These conditions were selected to quantify the main oligosaccharides in goat colostrum samples. Values ranging from 140 to 315 mg L−1 for neutral oligosaccharides and from 83 to 251 mg L−1 for acidic oligosaccharides were found. The combination of both techniques resulted to be useful to achieve a comprehensive characterization of GCO.This work has been funded by Junta de Andalucía (project AGR2011-7626), CSIC (project i-link0827), Comunidad Autónoma de Madrid (Spain) and European funding from FEDER program (AVANSECAL-CM S2013/ABI-3028) and Fundación Ramón Areces. This work was also supported by the UC Davis RISE program and the National Institutes of Health awards R21AT006180, R01AT007079, R01AT008759-02.Peer reviewe

Interpreting ELISA analyses from wild animal samples: some recurrent issues and solutions

Many studies in disease and ecological immunology rely on the use of assays that quantify the amount of specific antibodies (immunoglobulin) in samples. Enzyme‐linked immunosorbent assays (ELISAs) are increasingly used in ecology due to their availability for a broad array of antigens and the limited amount of sampling material they require. Two recurrent methodological issues are nevertheless faced by researchers: (1) the limited availability of immunological assays and reagents developed for non‐model species, and (2) the statistical determination of the cut‐off threshold used to distinguish individual samples that are likely to have or not to have antibodies against a specific antigen. Here, we outline two solutions to deal with these issues. First, we show that implementing two assays with differing detection methods can help validate the use of reagents, such as antibodies, in species different from their intended target. We illustrate this by comparing the quantification of specific vaccinal antibodies against Newcastle disease virus (NDV) using two ELISA approaches in four seabird species (Cory's shearwater, European shag, European storm petrel and Southern rockhopper penguin). Second, we provide a simple way to determine from the distribution of ELISA values whether the assayed samples are likely to be made of a single group of individuals (likely negative) or of two groups of individuals (negative and positive). We illustrate the use of this approach with two independent datasets: NDV antibody levels following vaccination and anti‐Borrelia antibody levels following natural exposure. The practical implementation of these methodological approaches could provide a way to efficiently apply ELISAs and other immune‐based assays to address questions in the growing fields of ecological immunology and disease ecology