721 research outputs found
Nonbipartite Dulmage-Mendelsohn Decomposition for Berge Duality
The Dulmage-Mendelsohn decomposition is a classical canonical decomposition
in matching theory applicable for bipartite graphs, and is famous not only for
its application in the field of matrix computation, but also for providing a
prototypal structure in matroidal optimization theory. The Dulmage-Mendelsohn
decomposition is stated and proved using the two color classes, and therefore
generalizing this decomposition for nonbipartite graphs has been a difficult
task. In this paper, we obtain a new canonical decomposition that is a
generalization of the Dulmage-Mendelsohn decomposition for arbitrary graphs,
using a recently introduced tool in matching theory, the basilica
decomposition. Our result enables us to understand all known canonical
decompositions in a unified way. Furthermore, we apply our result to derive a
new theorem regarding barriers. The duality theorem for the maximum matching
problem is the celebrated Berge formula, in which dual optimizers are known as
barriers. Several results regarding maximal barriers have been derived by known
canonical decompositions, however no characterization has been known for
general graphs. In this paper, we provide a characterization of the family of
maximal barriers in general graphs, in which the known results are developed
and unified
Two-Dimensional FTIR as a Tool to Study the Chemical Interactions within Cellulose-Ionic Liquid Solutions
In this study two-dimensional FTIR analysis was applied to understand the temperature effects on processing cellulose solutions in imidazolium-based ionic liquids. Analysis of the imidazolium ion ÎœC2âH peak revealed hydrogen bonding within cellulose solutions to be dynamic on heating and cooling. The extent of hydrogen bonding was stronger on heating, consistent with greater ion mobility at higher temperature when the ionic liquid network structure is broken. At ambient temperatures a blue shifted ÎœC2âH peak was indicative of greater cation-anion interactions, consistent with the ionic liquid network structure. Both cellulose and water further impact the extent of hydrogen bonding in these solutions. The FTIR spectral changes appeared gradual with temperature and contrast shear induced rheology changes which were observed on heating above 70°C and cooling below 40°C. The influence of cellulose on solution viscosity was not distinguished on initial heating as the ionic liquid network structure dominates rheology behaviour. On cooling, the quantity of cellulose has a greater influence on solution rheology. Outcomes suggest processing cellulose in ionic liquids above 40°C and to reduce the impacts of cation-anion effects and enhance solubilisation, processing should be done at 70°C
Single-particle states in spherical Si/SiO quantum dots
We calculate ground and excited electron and hole levels in spherical Si
quantum dots inside SiO in a multiband effective mass approximation.
Luttinger Hamiltonian is used for holes and the strong anisotropy of the
conduction electron effective mass in Si is taken into account. As boundary
conditions for electron and hole wave functions we use continuity of the wave
functions and the velocity density at the boundary of the quantum dots.Comment: 8 pages, 5 figure
Extended sudden approximation model for high-energy nucleon removal reactions
A model based on the sudden approximation has been developed to describe high
energy single nucleon removal reactions. Within this approach, which takes as
its starting point the formalism of Hansen \cite{Anne2}, the nucleon-removal
cross section and the full 3-dimensional momentum distributions of the core
fragments including absorption, diffraction, Coulomb and nuclear-Coulomb
interference amplitudes, have been calculated. The Coulomb breakup has been
treated to all orders for the dipole interaction. The model has been compared
to experimental data for a range of light, neutron-rich psd-shell nuclei. Good
agreement was found for both the inclusive cross sections and momentum
distributions. In the case of C, comparison is also made with the
results of calculations using the transfer-to-the-continuum model. The
calculated 3-dimensional momentum distributions exhibit longitudinal and
transverse momentum components that are strongly coupled by the reaction for
s-wave states, whilst no such effect is apparent for d-waves. Incomplete
detection of transverse momenta arising fromlimited experimental acceptances
thus leads to a narrowing of the longitudinal distributions for nuclei with
significant s-wave valence neutron configurations, as confirmed by the data.
Asymmetries in the longitudinal momentum distributions attributed to
diffractive dissociation are also explored.Comment: 16 figures, submitted to Phys. Rev.
Molecular Origin of Polyglutamine Aggregation in Neurodegenerative Diseases
Expansion of polyglutamine (polyQ) tracts in proteins results in protein aggregation and is associated with cell death in at least nine neurodegenerative diseases. Disease age of onset is correlated with the polyQ insert length above a critical value of 35â40 glutamines. The aggregation kinetics of isolated polyQ peptides in vitro also shows a similar critical-length dependence. While recent experimental work has provided considerable insights into polyQ aggregation, the molecular mechanism of aggregation is not well understood. Here, using computer simulations of isolated polyQ peptides, we show that a mechanism of aggregation is the conformational transition in a single polyQ peptide chain from random coil to a parallel ÎČ-helix. This transition occurs selectively in peptides longer than 37 glutamines. In the ÎČ-helices observed in simulations, all residues adopt ÎČ-strand backbone dihedral angles, and the polypeptide chain coils around a central helical axis with 18.5 ± 2 residues per turn. We also find that mutant polyQ peptides with proline-glycine inserts show formation of antiparallel ÎČ-hairpins in their ground state, in agreement with experiments. The lower stability of mutant ÎČ-helices explains their lower aggregation rates compared to wild type. Our results provide a molecular mechanism for polyQ-mediated aggregation
Hydrogen sulfide removal from biogas using a salak fruit seeds packed bed reactor with sulfur oxidizing bacteria as biofilm
A packed bed reactor was evaluated for hydrogen sulfide (H2S) removal by sulfur-oxidizing bacteria attached as a biofilm on salak fruit seeds (SFS). The bacteria were isolated from the sludge of the wastewater of a biogas plant. The promising isolate from the previous work was used in a biofilter, and its capacity to remove H2S was evaluated at effects of time of operation, effects of biogas flow rate, effects of axial distance, and packing material. Obtained results showed that isolate attached to SFS in an 80 cm height and 8 cm inside diameter biofilter column could decrease H2S in biogas from 142.48 ppm to 4.06 ppm (97.15% removal efficiency) for a biogas flow rate of 8550 g m3 h1 corresponding to a residence time of 4 h.
Simple kinetic models of sulfide removal and bacterial growth was proposed to describe the operation of the biofilter. The radial H2S concentration gradient in the flowing gas is to be neglected so is the H2S concentration in the biofilm at certain axial distance. Meanwhile, the rate of H2S degradation was approximated by Monod type equation.
The obtained simultaneous ordinary differential equations solved by Runge-Kutta method. Comparing the calculated results and the experimental data, it can be concluded that model proposed can sufficiently describe the performance of the H2S removal. The suitable values of the parameters are as follows: max = 0.0000007 (s1), KS = 0.0000039 (g cm3), kG = 0.0086 (cm s1), HS = 0.9 ((g cm3)/(g cm3)), and Yx/s = 10.Directorate General of Higher Educations of Indonesia - scholarship of doctorate program (BPPDN) at
Gadjah Mada University ; Hibah Bersaing 2015 and Sandwich-Like program 201
Principles to enable comprehensive national marine ecosystem status assessments from disparate data: The state of the marine environment in Kuwait
This paper presents an approach for preparing a comprehensive national marine ecosystem assessment and its application to the marine and coastal areas of the State of Kuwait. The approach is based on a set of principles to enable diverse data sources, of differing data quality and salience, to be combined into a single coordinated national assessment of marine ecosystem status to support the implementation of ecosystem-based management. The approach enables state assessments for multiple components of the marine ecosystem to be undertaken in a coordinated manner, using differing methods varying from quantitative to qualitative assessments depending on data and indicator availability. The marine ecosystem assessment is structured according to 6 major themes: i) Biodiversity, ii) Commercial Fisheries, iii) Food and Water Quality for Human Health, iv) Environmental Pollution, v) Eutrophication and Harmful Algal Blooms, and vi) Coastal Process and Oceanography. Comprehensive ecosystem assessments are an essential part of implementing the ecosystem approach, however detailed data directly related to clear, specified numerical management targets covering all aspects of a marine ecosystem are rarely available. The development of a State of the Marine Environment Report (SOMER) for Kuwait demonstrate that a coordinated comprehensive ecosystem assessment can be conducted using disparate data, and in relation to partially specified regulatory management objectives. The Kuwait SOMER highlighted the issues of coastal pollution, particularly sewage for human health and the environment. It shows that the rapid urbanization of Kuwait has led to significant changes in the ecology, with clear impacts on coral reef health, the availability of nesting locations for turtles and habitats for migratory birds. Long-term changes in nutrient input, via waste water and modified freshwater inputs is resulting in demonstrable impacts on a range of marine species and habitats within Kuwait marine waters. It also supports the move towards a regional approach required due to transboundary properties of many of the ecosystem components, drivers and pressures
Kuwait's marine biodiversity: Qualitative assessment of indicator habitats and species
The tropical waters of the Northern Arabian Gulf have a long history of maritime resource richness. High levels of biodiversity result from the complex matrix of coastal habitats, coral reefs and sea grass beds that characterise the region. Insight into the ongoing health of such habitats and the broader Kuwait maritime environment can be gauged by the status of indicator species found within these habitats. Here we review information on the occurrence, distribution and threats to key marine habitats and associated indicator species to provide an updated assessment of the state of the Kuwait's marine biodiversity. Critical evaluation of historic data highlights knowledge gaps needed inform the focus of future monitoring and conservation efforts. This assessment is designed to evaluate performance against environmental policy commitments, while providing a solid foundation for the design of comprehensive marine ecosystem management strategies
Growing Pollen Tubes Possess a Constitutive Alkaline Band in the Clear Zone and a Growth-dependent Acidic Tip
Using both the proton selective vibrating electrode to probe the extracellular currents and ratiometric wide-field fluorescence microscopy with the indicator 2âČ,7âČ-bis-(2-carboxyethyl)-5-(and-6)-carboxyfluorescein (BCECF)-dextran to image the intracellular pH, we have examined the distribution and activity of protons (H+) associated with pollen tube growth. The intracellular images reveal that lily pollen tubes possess a constitutive alkaline band at the base of the clear zone and an acidic domain at the extreme apex. The extracellular observations, in close agreement, show a proton influx at the extreme apex of the pollen tube and an efflux in the region that corresponds to the position of the alkaline band. The ability to detect the intracellular pH gradient is strongly dependent on the concentration of exogenous buffers in the cytoplasm. Thus, even the indicator dye, if introduced at levels estimated to be of 1.0 ÎŒM or greater, will dissipate the gradient, possibly through shuttle buffering. The apical acidic domain correlates closely with the process of growth, and thus may play a direct role, possibly in facilitating vesicle movement and exocytosis. The alkaline band correlates with the position of the reverse fountain streaming at the base of the clear zone, and may participate in the regulation of actin filament formation through the modulation of pH-sensitive actin binding proteins. These studies not only demonstrate that proton gradients exist, but that they may be intimately associated with polarized pollen tube growth
Nutritional Asymmetries Are Related to Division of Labor in a Queenless Ant
Eusocial species exhibit pronounced division of labor, most notably between reproductive and non-reproductive castes, but also within non-reproductive castes via morphological specialization and temporal polyethism. For species with distinct worker and queen castes, age-related differences in behavior among workers (e.g. within-nest tasks versus foraging) appear to result from physiological changes such as decreased lipid content. However, we know little about how labor is divided among individuals in species that lack a distinct queen caste. In this study, we investigated how fat storage varied among individuals in a species of ant (Dinoponera australis) that lacks a distinct queen caste and in which all individuals are morphologically similar and capable of reproduction (totipotent at birth). We distinguish between two hypotheses, 1) all individuals are physiologically similar, consistent with the possibility that any non-reproductive may eventually become reproductive, and 2) non-reproductive individuals vary in stored fat, similar to highly eusocial species, where depletion is associated with foraging and non-reproductives have lower lipid stores than reproducing individuals. Our data support the latter hypothesis. Location in the nest, the probability of foraging, and foraging effort, were all associated with decreased fat storage
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