9,131 research outputs found
A Decision Support System for Economic Viability and Environmental Impact Assessment of Vertical Farms
Vertical farming (VF) is the practice of growing crops or animals using the vertical dimension via multi-tier racks or vertically inclined surfaces. In this thesis, I focus on the emerging industry of plant-specific VF. Vertical plant farming (VPF) is a promising and relatively novel practice that can be conducted in buildings with environmental control and artificial lighting. However, the nascent sector has experienced challenges in economic viability, standardisation, and environmental sustainability. Practitioners and academics call for a comprehensive financial analysis of VPF, but efforts are stifled by a lack of valid and available data.
A review of economic estimation and horticultural software identifies a need for a decision support system (DSS) that facilitates risk-empowered business planning for vertical farmers. This thesis proposes an open-source DSS framework to evaluate business sustainability through financial risk and environmental impact assessments. Data from the literature, alongside lessons learned from industry practitioners, would be centralised in the proposed DSS using imprecise data techniques. These techniques have been applied in engineering but are seldom used in financial forecasting. This could benefit complex sectors which only have scarce data to predict business viability.
To begin the execution of the DSS framework, VPF practitioners were interviewed using a mixed-methods approach. Learnings from over 19 shuttered and operational VPF projects provide insights into the barriers inhibiting scalability and identifying risks to form a risk taxonomy. Labour was the most commonly reported top challenge. Therefore, research was conducted to explore lean principles to improve productivity.
A probabilistic model representing a spectrum of variables and their associated uncertainty was built according to the DSS framework to evaluate the financial risk for VF projects. This enabled flexible computation without precise production or financial data to improve economic estimation accuracy. The model assessed two VPF cases (one in the UK and another in Japan), demonstrating the first risk and uncertainty quantification of VPF business models in the literature. The results highlighted measures to improve economic viability and the viability of the UK and Japan case.
The environmental impact assessment model was developed, allowing VPF operators to evaluate their carbon footprint compared to traditional agriculture using life-cycle assessment. I explore strategies for net-zero carbon production through sensitivity analysis. Renewable energies, especially solar, geothermal, and tidal power, show promise for reducing the carbon emissions of indoor VPF. Results show that renewably-powered VPF can reduce carbon emissions compared to field-based agriculture when considering the land-use change.
The drivers for DSS adoption have been researched, showing a pathway of compliance and design thinking to overcome the ‘problem of implementation’ and enable commercialisation. Further work is suggested to standardise VF equipment, collect benchmarking data, and characterise risks. This work will reduce risk and uncertainty and accelerate the sector’s emergence
Gasificação direta de biomassa para produção de gás combustível
The excessive consumption of fossil fuels to satisfy the world necessities of
energy and commodities led to the emission of large amounts of greenhouse
gases in the last decades, contributing significantly to the greatest
environmental threat of the 21st century: Climate Change. The answer to this
man-made disaster is not simple and can only be made if distinct stakeholders
and governments are brought to cooperate and work together. This is
mandatory if we want to change our economy to one more sustainable and
based in renewable materials, and whose energy is provided by the eternal
nature energies (e.g., wind, solar). In this regard, biomass can have a main role
as an adjustable and renewable feedstock that allows the replacement of fossil
fuels in various applications, and the conversion by gasification allows the
necessary flexibility for that purpose. In fact, fossil fuels are just biomass that
underwent extreme pressures and heat for millions of years. Furthermore,
biomass is a resource that, if not used or managed, increases wildfire risks.
Consequently, we also have the obligation of valorizing and using this
resource.
In this work, it was obtained new scientific knowledge to support the
development of direct (air) gasification of biomass in bubbling fluidized bed
reactors to obtain a fuel gas with suitable properties to replace natural gas in
industrial gas burners. This is the first step for the integration and development
of gasification-based biorefineries, which will produce a diverse number of
value-added products from biomass and compete with current petrochemical
refineries in the future. In this regard, solutions for the improvement of the raw
producer gas quality and process efficiency parameters were defined and
analyzed. First, addition of superheated steam as primary measure allowed the
increase of H2 concentration and H2/CO molar ratio in the producer gas without
compromising the stability of the process. However, the measure mainly
showed potential for the direct (air) gasification of high-density biomass (e.g.,
pellets), due to the necessity of having char accumulation in the reactor bottom
bed for char-steam reforming reactions. Secondly, addition of refused derived
fuel to the biomass feedstock led to enhanced gasification products, revealing
itself as a highly promising strategy in terms of economic viability and
environmental benefits of future gasification-based biorefineries, due to the
high availability and low costs of wastes. Nevertheless, integrated techno economic and life cycle analyses must be performed to fully characterize the
process. Thirdly, application of low-cost catalyst as primary measure revealed
potential by allowing the improvement of the producer gas quality (e.g., H2 and
CO concentration, lower heating value) and process efficiency parameters with
distinct solid materials; particularly, the application of concrete, synthetic
fayalite and wood pellets chars, showed promising results. Finally, the
economic viability of the integration of direct (air) biomass gasification
processes in the pulp and paper industry was also shown, despite still lacking
interest to potential investors. In this context, the role of government policies
and appropriate economic instruments are of major relevance to increase the
implementation of these projects.O consumo excessivo de combustíveis fósseis para garantir as necessidades e
interesses da sociedade conduziu à emissão de elevadas quantidades de
gases com efeito de estufa nas últimas décadas, contribuindo
significativamente para a maior ameaça ambiental do século XXI: Alterações
Climáticas. A solução para este desastre de origem humana é de caráter
complexo e só pode ser atingida através da cooperação de todos os governos
e partes interessadas. Para isto, é obrigatória a criação de uma bioeconomia
como base de um futuro mais sustentável, cujas necessidades energéticas e
materiais sejam garantidas pelas eternas energias da natureza (e.g., vento,
sol). Neste sentido, a biomassa pode ter um papel principal como uma matéria prima ajustável e renovável que permite a substituição de combustíveis fósseis
num variado número de aplicações, e a sua conversão através da gasificação
pode ser a chave para este propósito. Afinal, na prática, os combustíveis
fósseis são apenas biomassa sujeita a elevada temperatura e pressão durante
milhões de anos. Além do mais, a gestão eficaz da biomassa é fundamental
para a redução dos riscos de incêndio florestal e, como tal, temos o dever de
utilizar e valorizar este recurso.
Neste trabalho, foi obtido novo conhecimento científico para suporte do
desenvolvimento das tecnologias de gasificação direta (ar) de biomassa em
leitos fluidizados borbulhantes para produção de gás combustível, com o
objetivo da substituição de gás natural em queimadores industriais. Este é o
primeiro passo para o desenvolvimento de biorrefinarias de gasificação, uma
potencial futura indústria que irá providenciar um variado número de produtos
de valor acrescentado através da biomassa e competir com a atual indústria
petroquímica. Neste sentido, foram analisadas várias medidas para a melhoria
da qualidade do gás produto bruto e dos parâmetros de eficiência do processo.
Em primeiro, a adição de vapor sobreaquecido como medida primária permitiu
o aumento da concentração de H2 e da razão molar H2/CO no gás produto sem
comprometer a estabilidade do processo. No entanto, esta medida somente
revelou potencial para a gasificação direta (ar) de biomassa de alta densidade
(e.g., pellets) devido à necessidade da acumulação de carbonizados no leito
do reator para a ocorrência de reações de reforma com vapor. Em segundo, a
mistura de combustíveis derivados de resíduos e biomassa residual florestal
permitiu a melhoria dos produtos de gasificação, constituindo desta forma uma
estratégia bastante promissora a nível económico e ambiental, devido à
elevada abundância e baixo custo dos resíduos urbanos. Contudo, devem ser
efetuadas análises técnico-económicas e de ciclo de vida para a completa
caraterização do processo. Em terceiro, a aplicação de catalisadores de baixo
custo como medida primária demonstrou elevado potencial para a melhoria do
gás produto (e.g., concentração de H2 e CO, poder calorífico inferior) e para o
incremento dos parâmetros de eficiência do processo; em particular, a
aplicação de betão, faialite sintética e carbonizados de pellets de madeira,
demonstrou resultados promissores. Finalmente, foi demonstrada a viabilidade
económica da integração do processo de gasificação direta (ar) de biomassa
na indústria da pasta e papel, apesar dos parâmetros determinados não serem
atrativos para potenciais investidores. Neste contexto, a intervenção dos
governos e o desenvolvimento de instrumentos de apoio económico é de
grande relevância para a implementação destes projetos.Este trabalho foi financiado pela The Navigator Company e por Fundos Nacionais através da Fundação para a Ciência e a Tecnologia (FCT).Programa Doutoral em Engenharia da Refinação, Petroquímica e Químic
Increased lifetime of Organic Photovoltaics (OPVs) and the impact of degradation, efficiency and costs in the LCOE of Emerging PVs
Emerging photovoltaic (PV) technologies such as organic photovoltaics (OPVs) and perovskites (PVKs) have the potential to disrupt the PV market due to their ease of fabrication (compatible with cheap roll-to-roll processing) and installation, as well as their significant efficiency improvements in recent years. However, rapid degradation is still an issue present in many emerging PVs, which must be addressed to enable their commercialisation. This thesis shows an OPV lifetime enhancing technique by adding the insulating polymer PMMA to the active layer, and a novel model for quantifying the impact of degradation (alongside efficiency and cost) upon levelized cost of energy (LCOE) in real world emerging PV installations.
The effect of PMMA morphology on the success of a ternary strategy was investigated, leading to device design guidelines. It was found that either increasing the weight percent (wt%) or molecular weight (MW) of PMMA resulted in an increase in the volume of PMMA-rich islands, which provided the OPV protection against water and oxygen ingress. It was also found that adding PMMA can be effective in enhancing the lifetime of different active material combinations, although not to the same extent, and that processing additives can have a negative impact in the devices lifetime.
A novel model was developed taking into account realistic degradation profile sourced from a literature review of state-of-the-art OPV and PVK devices. It was found that optimal strategies to improve LCOE depend on the present characteristics of a device, and that panels with a good balance of efficiency and degradation were better than panels with higher efficiency but higher degradation as well. Further, it was found that low-cost locations were more favoured from reductions in the degradation rate and module cost, whilst high-cost locations were more benefited from improvements in initial efficiency, lower discount rates and reductions in install costs
Flexible pressure sensors via engineering microstructures for wearable human-machine interaction and health monitoring applications
Flexible pressure sensors capable of transducing pressure stimuli into electrical signals have drawn extensive attention owing to their potential applications for human-machine interaction and healthcare monitoring. To meet these application demands, engineering microstructures in the pressure sensors are an efficient way to improve key sensing performances, such as sensitivity, linear sensing range, response time, hysteresis, and durability. In this review, we provide an overview of the recent advances in the fabrication and application of high-performance flexible pressure sensors via engineering microstructures. The implementation mechanisms and fabrication strategies of microstructures including micropatterned, porous, fiber-network, and multiple microstructures are systematically presented. The applications of flexible pressure sensors with microstructures in the fields of wearable human-machine interaction, and ex vivo and in vivo healthcare monitoring are comprehensively discussed. Finally, the outlook and challenges in the future improvement of flexible pressure sensors toward practical applications are presented
Addressing infrastructure challenges posed by the Harwich Formation through understanding its geological origins
Variable deposits known to make up the sequence of the Harwich Formation in London have been the subject of ongoing uncertainty within the engineering industry. Current stratigraphical subdivisions do not account for the systematic recognition of individual members in unexposed ground where recovered material is usually disturbed - fines are flushed out during the drilling process and loose materials are often lost or mixed with the surrounding layers.
Most engineering problems associated with the Harwich Formation deposits are down to their unconsolidated nature and irregular cementation within layers. The consequent engineering hazards are commonly reflected in high permeability, raised groundwater pressures, ground settlements - when found near the surface and poor stability - when exposed during excavations or tunnelling operations. This frequently leads to sudden design changes or requires contingency measures during construction. All of these can result in damaged equipment, slow progress, and unforeseen costs.
This research proposes a facies-based approach where the lithological facies assigned were identified based on reinterpretation of available borehole data from various ground investigations in London, supported by visual inspection of deposits in-situ and a selection of laboratory testing including Particle Size Distribution, Optical and Scanning Electron Microscopy and X-ray Diffraction analyses.
Two ground models were developed as a result: 1st a 3D geological model (MOVE model) of the stratigraphy found within the study area that explores the influence of local structural processes controlling/affecting these sediments pre-, syn- and post- deposition and 2nd a sequence stratigraphic model (Dionisos Flow model) unveiling stratal geometries of facies at various stages of accretion. The models present a series of sediment distribution maps, localised 3D views and cross-sections that aim to provide a novel approach to assist the geotechnical industry in predicting the likely distribution of the Harwich Formation deposits, decreasing the engineering risks associated with this stratum.Open Acces
The Adirondack Chronology
The Adirondack Chronology is intended to be a useful resource for researchers and others interested in the Adirondacks and Adirondack history.https://digitalworks.union.edu/arlpublications/1000/thumbnail.jp
Synthesis and Characterisation of Low-cost Biopolymeric/mineral Composite Systems and Evaluation of their Potential Application for Heavy Metal Removal
Heavy metal pollution and waste management are two major environmental problems faced in the world today. Anthropogenic sources of heavy metals, especially effluent from industries, are serious environmental and health concerns by polluting surface and ground waters. Similarly, on a global scale, thousands of tonnes of industrial and agricultural waste are discarded into the environment annually. There are several conventional methods to treat industrial effluents, including reverse osmosis, oxidation, filtration, flotation, chemical precipitation, ion exchange resins and adsorption. Among them, adsorption and ion exchange are known to be effective mechanisms for removing heavy metal pollution, especially if low-cost materials can be used.
This thesis was a study into materials that can be used to remove heavy metals from water using low-cost feedstock materials. The synthesis of low-cost composite matrices from agricultural and industrial by-products and low-cost organic and mineral sources was carried out. The feedstock materials being considered include chitosan (generated from industrial seafood waste), coir fibre (an agricultural by-product), spent coffee grounds (a by-product from coffee machines), hydroxyapatite (from bovine bone), and naturally sourced aluminosilicate minerals such as zeolite.
The novel composite adsorbents were prepared using commercially sourced HAp and bovine sourced HAp, with two types of adsorbents being synthesized, including two- and three-component composites. Standard synthetic methods such as precipitation were developed to synthesize these materials, followed by characterization of their structural, physical, and chemical properties (by using FTIR, TGA, SEM, EDX and XRD).
The synthesized materials were then evaluated for their ability to remove metal ions from solutions of heavy metals using single-metal ion type and two-metal ion type solution systems, using the model ion solutions, with quantification of their removal efficiency. It was followed by experimentation using the synthesized adsorbents for metal ion removal in complex systems such as an industrial input stream solution system obtained from a local timber treatment company.
Two-component composites were considered as control composites to compare the removal efficiency of the three-component composites against. The heavy metal removal experiments were conducted under a range of experimental conditions (e.g., pH, sorbent dose, initial metal ion concentration, time of contact). Of the four metal ion systems considered in this study (Cd2+, Pb2+, Cu2+ and Cr as chromate ions), Pb2+ ion removal by the composites was found to be the highest in single-metal and two-metal ion type solution systems, while chromate ion removal was found to be the lowest. The bovine bone-based hydroxyapatite (bHAp) composites were more efficient at removing the metal cations than composites formed from a commercially sourced hydroxyapatite (cHAp).
In industrial input stream solution systems (containing Cu, Cr and As), the Cu2+ ion removal was the highest, which aligned with the observations recorded in the single and two-metal ion type solution systems. Arsenate ion was removed to a higher extent than chromate ion using the three-component composites, while the removal of chromate ion was found to be higher than arsenate ion when using the two-component composites (i.e., the control system).
The project also aimed to elucidate the removal mechanisms of these synthesized composite materials by using appropriate adsorption and kinetic models. The adsorption of metal ions exhibited a range of adsorption behaviours as both the models (Langmuir and Freundlich) were found to fit most of the data recorded in different adsorption systems studied. The pseudo-second-order model was found to be the best fitted to describe the kinetics of heavy metal ion adsorption in all the composite adsorbent systems studied, in single-metal ion type and two-metal ion type solution systems. The ion-exchange mechanism was considered as one of the dominant mechanisms for the removal of cations (in single-metal and two-metal ion type solution systems) and arsenate ions (in industrial input stream solution systems) along with other adsorption mechanisms. In contrast, electrostatic attractions were considered to be the dominant mechanism of removal for chromate ions
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Novel delivery and sample mixing for synchrotron diffraction experiments using acoustic levitation with multi-transducer arrays
Acoustic levitation may utilise standing waves at ultrasonic frequencies to manipulate suspended substances and small objects in a contactless manner. These materials may be levitated in the positions in which the nodes are located, corresponding to positions of low acoustic pressure. In recent years, off the shelf transducer based acoustic levitators have been used for contactless manipulation of liquids. These systems benefit from requiring low power and low-cost components making acoustic levitation more accessible to the masses. Such a system was investigated in this work for presenting protein crystals, within their mother liquor, to the I24 beamline at Diamond Light Source for x-ray diffraction experiments. It was found that the crystals tended to sediment toward the bottom of the droplets, which were oblate in shape. The droplets which were levitated often became unstable and fell from their suspended position, or they would not detach from the pipette tip when they were being injected. To rectify this, a coating of silicone oil was added allowing the droplets to remain stable as well as limit the evaporation of the droplet whilst it was manually inserted and the area cleared of personnel before the x-ray beam was engaged. This silicone oil coating is non-crystalline and thus did not invalidate the results collected which showed the lysozyme crystal structure with a resolution of 1.69 A, confirming acoustic levitation as a good sample presentation method for these types of experiments. To remove the requirement for the silicone oil, a bespoke system was created named the DLS-Lev that allowed top-loading of the sample. The droplets of mother liquor which contained protein crystals were easily detached from the pipette tip into the traps within the DLS-Lev system owing to the increased strength of the traps in the modified design. This system, paired with an automated pipette, facilitated sample mixing experiments whilst the x-ray beam was engaged. The further development of the pipetting system was halted due to the COVID-19 pandemic. However, future work should see the permanent installation of these systems at the I24 beamline at Diamond Light Source, as well as additional bespoke acoustic levitators designed for the other beamlines specialising in the research of protein structure via x-ray scattering techniques
Hunting Wildlife in the Tropics and Subtropics
The hunting of wild animals for their meat has been a crucial activity in the evolution of humans. It continues to be an essential source of food and a generator of income for millions of Indigenous and rural communities worldwide. Conservationists rightly fear that excessive hunting of many animal species will cause their demise, as has already happened throughout the Anthropocene. Many species of large mammals and birds have been decimated or annihilated due to overhunting by humans. If such pressures continue, many other species will meet the same fate. Equally, if the use of wildlife resources is to continue by those who depend on it, sustainable practices must be implemented. These communities need to remain or become custodians of the wildlife resources within their lands, for their own well-being as well as for biodiversity in general. This title is also available via Open Access on Cambridge Core
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