31,555 research outputs found
Fronthaul-Constrained Cloud Radio Access Networks: Insights and Challenges
As a promising paradigm for fifth generation (5G) wireless communication
systems, cloud radio access networks (C-RANs) have been shown to reduce both
capital and operating expenditures, as well as to provide high spectral
efficiency (SE) and energy efficiency (EE). The fronthaul in such networks,
defined as the transmission link between a baseband unit (BBU) and a remote
radio head (RRH), requires high capacity, but is often constrained. This
article comprehensively surveys recent advances in fronthaul-constrained
C-RANs, including system architectures and key techniques. In particular, key
techniques for alleviating the impact of constrained fronthaul on SE/EE and
quality of service for users, including compression and quantization,
large-scale coordinated processing and clustering, and resource allocation
optimization, are discussed. Open issues in terms of software-defined
networking, network function virtualization, and partial centralization are
also identified.Comment: 5 Figures, accepted by IEEE Wireless Communications. arXiv admin
note: text overlap with arXiv:1407.3855 by other author
Fluorescent Silicon Clusters and Nanoparticles
The fluorescence of silicon clusters is reviewed. Atomic clusters of silicon
have been at the focus of research for several decades because of the relevance
of size effects for material properties, the importance of silicon in
electronics and the potential applications in bio-medicine. To date numerous
examples of nanostructured forms of fluorescent silicon have been reported.
This article introduces the principles and underlying concepts relevant for
fluorescence of nanostructured silicon such as excitation, energy relaxation,
radiative and non-radiative decay pathways and surface passivation.
Experimental methods for the production of silicon clusters are presented. The
geometric and electronic properties are reviewed and the implications for the
ability to emit fluorescence are discussed. Free and pure silicon clusters
produced in molecular beams appear to have properties that are unfavourable for
light emission. However, when passivated or embedded in a suitable host, they
may emit fluorescence. The current available data show that both quantum
confinement and localised transitions, often at the surface, are responsible
for fluorescence. By building silicon clusters atom by atom, and by embedding
them in shells atom by atom, new insights into the microscopic origins of
fluorescence from nanoscale silicon can be expected.Comment: 5 figures, chapter in "Silicon Nanomaterials Sourcebook", editor
Klaus D. Sattler, CRC Press, August 201
Characterisation of Bombyx mori odorant-binding proteins reveals that a general odorant-binding protein discriminates between sex pheromone components
In many insect species, odorant-binding proteins (OBPs) are thought to be responsible for the transport of pheromones and other semiochemicals across the sensillum lymph to the olfactory receptors (ORs) within the antennal sensilla. In the silkworm Bombyx mori, the OBPs are subdivided into three main subfamilies; pheromone-binding proteins (PBPs), general odorant-binding proteins (GOBPs) and antennal-binding proteins (ABPs). We used the MotifSearch algorithm to search for genes encoding putative OBPs in B. mori and found 13, many fewer than are found in the genomes of fruit flies and mosquitoes. The 13 genes include seven new ABP-like OBPs as well as the previously identified PBPs (three), GOBPs (two) and ABPx. Quantitative examination of transcript levels showed that BmorPBP1, BmorGOBP1, BmorGOBP2 and BmorABPx are expressed at very high levels in the antennae and so could be involved in olfaction. A new two-phase binding assay, along with other established assays, showed that BmorPBP1, BmorPBP2, BmorGOBP2 and BmorABPx all bind to the B. mori sex pheromone component (10E,12Z)-hexadecadien-1-ol (bombykol). BmorPBP1, BmorPBP2 and BmorABPx also bind the pheromone component (10E,12Z)-hexadecadienal (bombykal) equally well, whereas BmorGOBP2 can discriminate between bombykol and bombykal. X-ray structures show that when bombykol is bound to BmorGOBP2 it adopts a different conformation from that found when it binds to BmorPBP1. Binding to BmorGOBP2 involves hydrogen bonding to Arg110 rather than to Ser56 as found for BmorPBP1
Direct Observation of Early-stage Quantum Dot Growth Mechanisms with High-temperature Ab Initio Molecular Dynamics
Colloidal quantum dots (QDs) exhibit highly desirable size- and
shape-dependent properties for applications from electronic devices to imaging.
Indium phosphide QDs have emerged as a primary candidate to replace the more
toxic CdSe QDs, but production of InP QDs with the desired properties lags
behind other QD materials due to a poor understanding of how to tune the growth
process. Using high-temperature ab initio molecular dynamics (AIMD)
simulations, we report the first direct observation of the early stage
intermediates and subsequent formation of an InP cluster from separated indium
and phosphorus precursors. In our simulations, indium agglomeration precedes
formation of In-P bonds. We observe a predominantly intercomplex pathway in
which In-P bonds form between one set of precursor copies while the carboxylate
ligand of a second indium precursor in the agglomerated indium abstracts a
ligand from the phosphorus precursor. This process produces an indium-rich
cluster with structural properties comparable to those in bulk zinc-blende InP
crystals. Minimum energy pathway characterization of the AIMD-sampled reaction
events confirms these observations and identifies that In-carboxylate
dissociation energetics solely determine the barrier along the In-P bond
formation pathway, which is lower for intercomplex (13 kcal/mol) than
intracomplex (21 kcal/mol) mechanisms. The phosphorus precursor chemistry, on
the other hand, controls the thermodynamics of the reaction. Our observations
of the differing roles of precursors in controlling QD formation strongly
suggests that the challenges thus far encountered in InP QD synthesis
optimization may be attributed to an overlooked need for a cooperative tuning
strategy that simultaneously addresses the chemistry of both indium and
phosphorus precursors.Comment: 40 pages, 9 figures, submitted for publicatio
A new family of high nuclearity CoII/DyIII coordination clusters possessing robust and unseen topologies
Mixing Co(NO3)2·6H2O/Dy(NO3)3·6H2O/(E)-4-(2-hydroxy-3-methoxybenzylideneamino)-2,3-dimethyl-1-phenyl-1,2-dihydropyrazol-5-one (HL)/pivalic acid/Et3N in various solvents results in the synthesis of seven compounds formulated as [CoII2DyIII2(μ3-MeO)2(L)2(piv)4(NO3)2] (3), [CoIIDyIII3(μ3-MeO)2(μ2-MeO)2(L)2(piv)2(NO3)3]·2(CH3OH) (4·2CH3OH), 2[CoII4DyIII4(μ2-O)2(μ3-OH)4(L)4(piv)8][CoII2DyIII5(μ3-OH)6(L)2(piv)8(NO3)4] (5), [CoII4DyIII4(μ2-O)2(μ3-OH)4(L)4(piv)8]·2(CH3CN) (6·2CH3CN), [CoII2DyIII5(μ3-OH)6(L)2(piv)8(NO3)4]·4(CH3CN) (7·4CH3CN), [CoII2DyIII2(μ3-OH)2(L)2(piv)2(NO3)2(EtOH)2(H2O)2](NO3)2·(EtOH) (8·EtOH) and [CoII4DyIII4(μ2-O)2(μ3-OH)4(L)4(piv)8] (9) with robust and unseen topologies. These show that the temperature and reaction time influence the formation of the final product. Preliminary magnetic studies, performed for 6 and 7 in the temperature range 2-300 K, are indicative of Single Molecule Magnet (SMM) behaviour. Moreover, analysis of the catalytic properties of compound 3 as an efficient catalyst for the synthesis of trans-4,5-diaminocyclopent-2-enones from 2-furaldehyde and primary amines has been carried out
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Cryo-EM Studies of TMEM16F Calcium-Activated Ion Channel Suggest Features Important for Lipid Scrambling.
As a Ca2+-activated lipid scramblase and ion channel that mediates Ca2+ influx, TMEM16F relies on both functions to facilitate extracellular vesicle generation, blood coagulation, and bone formation. How a bona fide ion channel scrambles lipids remains elusive. Our structural analyses revealed the coexistence of an intact channel pore and PIP2-dependent protein conformation changes leading to membrane distortion. Correlated to the extent of membrane distortion, many tightly bound lipids are slanted. Structure-based mutagenesis studies further reveal that neutralization of some lipid-binding residues or those near membrane distortion specifically alters the onset of lipid scrambling, but not Ca2+ influx, thus identifying features outside of channel pore that are important for lipid scrambling. Together, our studies demonstrate that membrane distortion does not require open hydrophilic grooves facing the membrane interior and provide further evidence to suggest separate pathways for lipid scrambling and ion permeation
Functionalisation of colloidal transition metal sulphides nanocrystals: A fascinating and challenging playground for the chemist
Metal sulphides, and in particular transition metal sulphide colloids, are a broad, versatile and exciting class of inorganic compounds which deserve growing interest and attention ascribable to the functional properties that many of them display. With respect to their oxide homologues, however, they are characterised by noticeably different chemical, structural and hence functional features. Their potential applications span several fields, and in many of the foreseen applications (e.g., in bioimaging and related fields), the achievement of stable colloidal suspensions of metal sulphides is highly desirable or either an unavoidable requirement to be met. To this aim, robust functionalisation strategies should be devised, which however are, with respect to metal or metal oxides colloids, much more challenging. This has to be ascribed, inter alia, also to the still limited knowledge of the sulphides surface chemistry, particularly when comparing it to the better established, though multifaceted, oxide surface chemistry. A ground-breaking endeavour in this field is hence the detailed understanding of the nature of the complex surface chemistry of transition metal sulphides, which ideally requires an integrated experimental and modelling approach. In this review, an overview of the state-of-the-art on the existing examples of functionalisation of transition metal sulphides is provided, also by focusing on selected case studies, exemplifying the manifold nature of this class of binary inorganic compounds
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