Probing the chemistry of CdS paints in The Scream by in situ noninvasive spectroscopies and synchrotron radiation x-ray techniques

The degradation of cadmium sulfide (CdS)-based oil paints is a phenomenon potentially threatening the iconic painting The Scream (ca. 1910) by Edvard Munch (Munch Museum, Oslo) that is still poorly understood. Here, we provide evidence for the presence of cadmium sulfate and sulfites as alteration products of the original CdS-based paint and explore the external circumstances and internal factors causing this transformation. Macroscale in situ noninvasive spectroscopy studies of the painting in combination with synchrotron-radiation x-ray microspectroscopy investigations of a microsample and artificially aged mock-ups show that moisture and mobile chlorine compounds are key factors for promoting the oxidation of CdS, while light (photodegradation) plays a less important role. Furthermore, under exposure to humidity, parallel/secondary reactions involving dissolution, migration through the paint, and recrystallization of water-soluble phases of the paint are associated with the formation of cadmium sulfates

Unmixing and pigment identification using visible and short-wavelength infrared: Reflectance vs logarithm reflectance hyperspaces

Hyperspectral imaging has recently consolidated as a useful technique for pigment mapping and identification, although it is commonly supported by additional non-invasive analytical methods. Since it is relatively rare to find pure pigments in aged paintings, spectral unmixing can be helpful in facilitating pigment identification if suitable mixing models and endmember extraction procedures are chosen. In this study, a subtractive mixing model is assumed, and two approaches are compared for endmember extraction: one based on a linear mixture model, and the other, nonlinear and Deep-Learning based. Two spectral hyperspaces are used: the spectral reflectance (R hyperspace) and the -log(R) hyperspace, for which the subtractive model becomes additive. The performance of unmixing is evaluated by the similarity of the estimated reflectance to the measured data, and pigment identification accuracy. Two spectral ranges (400 to 1000 nm and 900 to 1700 nm) and two objects (a laboratory sample and an aged painting, both on copper) are tested. The main conclusion is that unmixing in the -log(R) hyperspace with a linear mixing model is better than for the non-linear model in R hyperspace, and that pigment identification is generally better in R hyperspace, improving by merging the results in both spectral ranges.MCIN/AEI/10.13039/501100011033 and by “ERDF A way of making Europe” [grant number PID2021-124446NB-100]Ministry of Universities (Spain) [grant number FPU2020-05532

Comparing the effectiveness of hyperspectral imaging and Raman spectroscopy:A case study on Armenian manuscripts

Additional file 1. Additional Figures S1–S5 and Tables S1, S2

Authentication of Amadeo de Souza-Cardoso Paintings and Drawings With Deep Learning

Art forgery has a long-standing history that can be traced back to the Roman period and has become more rampant as the art market continues prospering. Reports disclosed that uncountable artworks circulating on the art market could be fake. Even some principal art museums and galleries could be exhibiting a good percentage of fake artworks. It is therefore substantially important to conserve cultural heritage, safeguard the interest of both the art market and the artists, as well as the integrity of artists’ legacies. As a result, art authentication has been one of the most researched and well-documented fields due to the ever-growing commercial art market in the past decades. Over the past years, the employment of computer science in the art world has flourished as it continues to stimulate interest in both the art world and the artificial intelligence arena. In particular, the implementation of Artificial Intelligence, namely Deep Learning algorithms and Neural Networks, has proved to be of significance for specialised image analysis. This research encompassed multidisciplinary studies on chemistry, physics, art and computer science. More specifically, the work presents a solution to the problem of authentication of heritage artwork by Amadeo de Souza-Cardoso, namely paintings, through the use of artificial intelligence algorithms. First, an authenticity estimation is obtained based on processing of images through a deep learning model that analyses the brushstroke features of a painting. Iterative, multi-scale analysis of the images is used to cover the entire painting and produce an overall indication of authenticity. Second, a mixed input, deep learning model is proposed to analyse pigments in a painting. This solves the image colour segmentation and pigment classification problem using hyperspectral imagery. The result is used to provide an indication of authenticity based on pigment classification and correlation with chemical data obtained via XRF analysis. Further algorithms developed include a deep learning model that tackles the pigment unmixing problem based on hyperspectral data. Another algorithm is a deep learning model that estimates hyperspectral images from sRGB images. Based on the established algorithms and results obtained, two applications were developed. First, an Augmented Reality mobile application specifically for the visualisation of pigments in the artworks by Amadeo. The mobile application targets the general public, i.e., art enthusiasts, museum visitors, art lovers or art experts. And second, a desktop application with multiple purposes, such as the visualisation of pigments and hyperspectral data. This application is designed for art specialists, i.e., conservators and restorers. Due to the special circumstances of the pandemic, trials on the usage of these applications were only performed within the Department of Conservation and Restoration at NOVA University Lisbon, where both applications received positive feedback.A falsificação de arte tem uma história de longa data que remonta ao período romano e tornou-se mais desenfreada à medida que o mercado de arte continua a prosperar. Relatórios revelaram que inúmeras obras de arte que circulam no mercado de arte podem ser falsas. Mesmo alguns dos principais museus e galerias de arte poderiam estar exibindo uma boa porcentagem de obras de arte falsas. Por conseguinte, é extremamente importante conservar o património cultural, salvaguardar os interesses do mercado da arte e dos artis- tas, bem como a integridade dos legados dos artistas. Como resultado, a autenticação de arte tem sido um dos campos mais pesquisados e bem documentados devido ao crescente mercado de arte comercial nas últimas décadas.Nos últimos anos, o emprego da ciência da computação no mundo da arte floresceu à medida que continua a estimular o interesse no mundo da arte e na arena da inteligência artificial. Em particular, a implementação da Inteligência Artificial, nomeadamente algoritmos de aprendizagem profunda (ou Deep Learning) e Redes Neuronais, tem-se revelado importante para a análise especializada de imagens.Esta investigação abrangeu estudos multidisciplinares em química, física, arte e informática. Mais especificamente, o trabalho apresenta uma solução para o problema da autenticação de obras de arte patrimoniais de Amadeo de Souza-Cardoso, nomeadamente pinturas, através da utilização de algoritmos de inteligência artificial. Primeiro, uma esti- mativa de autenticidade é obtida com base no processamento de imagens através de um modelo de aprendizagem profunda que analisa as características de pincelada de uma pintura. A análise iterativa e multiescala das imagens é usada para cobrir toda a pintura e produzir uma indicação geral de autenticidade. Em segundo lugar, um modelo misto de entrada e aprendizagem profunda é proposto para analisar pigmentos em uma pintura. Isso resolve o problema de segmentação de cores de imagem e classificação de pigmentos usando imagens hiperespectrais. O resultado é usado para fornecer uma indicação de autenticidade com base na classificação do pigmento e correlação com dados químicos obtidos através da análise XRF. Outros algoritmos desenvolvidos incluem um modelo de aprendizagem profunda que aborda o problema da desmistura de pigmentos com base em dados hiperespectrais. Outro algoritmo é um modelo de aprendizagem profunda estabelecidos e nos resultados obtidos, foram desenvolvidas duas aplicações. Primeiro, uma aplicação móvel de Realidade Aumentada especificamente para a visualização de pigmentos nas obras de Amadeo. A aplicação móvel destina-se ao público em geral, ou seja, entusiastas da arte, visitantes de museus, amantes da arte ou especialistas em arte. E, em segundo lugar, uma aplicação de ambiente de trabalho com múltiplas finalidades, como a visualização de pigmentos e dados hiperespectrais. Esta aplicação é projetada para especialistas em arte, ou seja, conservadores e restauradores. Devido às circunstâncias especiais da pandemia, os ensaios sobre a utilização destas aplicações só foram realizados no âmbito do Departamento de Conservação e Restauro da Universidade NOVA de Lisboa, onde ambas as candidaturas receberam feedback positivo

The brushstroke and materials of Amadeo de Souza-Cardoso combined in an authentication tool

Nowadays, authentication studies for paintings require a multidisciplinary approach, based on the contribution of visual features analysis but also on characterizations of materials and techniques. Moreover, it is important that the assessment of the authorship of a painting is supported by technical studies of a selected number of original artworks that cover the entire career of an artist. This dissertation is concerned about the work of modernist painter Amadeo de Souza-Cardoso. It is divided in three parts. In the first part, we propose a tool based on image processing that combines information obtained by brushstroke and materials analysis. The resulting tool provides qualitative and quantitative evaluation of the authorship of the paintings; the quantitative element is particularly relevant, as it could be crucial in solving authorship controversies, such as judicial disputes. The brushstroke analysis was performed by combining two algorithms for feature detection, namely Gabor filter and Scale Invariant Feature Transform. Thanks to this combination (and to the use of the Bag-of-Features model), the proposed method shows an accuracy higher than 90% in distinguishing between images of Amadeo’s paintings and images of artworks by other contemporary artists. For the molecular analysis, we implemented a semi-automatic system that uses hyperspectral imaging and elemental analysis. The system provides as output an image that depicts the mapping of the pigments present, together with the areas made using materials not coherent with Amadeo’s palette, if any. This visual output is a simple and effective way of assessing the results of the system. The tool proposed based on the combination of brushstroke and molecular information was tested in twelve paintings obtaining promising results. The second part of the thesis presents a systematic study of four selected paintings made by Amadeo in 1917. Although untitled, three of these paintings are commonly known as BRUT, Entrada and Coty; they are considered as his most successful and genuine works. The materials and techniques of these artworks have never been studied before. The paintings were studied with a multi-analytical approach using micro-Energy Dispersive X-ray Fluorescence spectroscopy, micro-Infrared and Raman Spectroscopy, micro-Spectrofluorimetry and Scanning Electron Microscopy. The characterization of Amadeo’s materials and techniques used on his last paintings, as well as the investigation of some of the conservation problems that affect these paintings, is essential to enrich the knowledge on this artist. Moreover, the study of the materials in the four paintings reveals commonalities between the paintings BRUT and Entrada. This observation is supported also by the analysis of the elements present in a photograph of a collage (conserved at the Art Library of the Calouste Gulbenkian Foundation), the only remaining evidence of a supposed maquete of these paintings. The final part of the thesis describes the application of the image processing tools developed in the first part of the thesis on a set of case studies; this experience demonstrates the potential of the tool to support painting analysis and authentication studies. The brushstroke analysis was used as additional analysis on the evaluation process of four paintings attributed to Amadeo, and the system based on hyperspectral analysis was applied on the painting dated 1917. The case studies therefore serve as a bridge between the first two parts of the dissertation

Spectral information to get beyond color in the analysis of water‑soluble varnish degradation

Spectral images were captured of paper samples varnished with two water-soluble materials: gum arabic and egg white. The samples were submitted to degradation processes that partially or totally eliminated the varnish from the substrate (water immersion and ageing). The spectral information was used to obtain average color data and to characterize the spatial and color inhomogeneity across pixels, showing that the pixel spectral data are critical for an accurate characterization of the degradation process of the varnishes. Since the varnishes typically become yellower with ageing, this study introduces two novel and simple-to-compute yellowness indices based on the spectral information, which are validated against a standard colorimetric index (ASTM-E313 2015). The potential uses of spectral information are demonstrated with several pieces of a real antique map sample by comparing the spectral information measured before and after cleaning the sample. To sum up, the main contributions of this study are the characterization of the spatial homogeneity through pixel-based spectral and color information and the proposal of spectral-based yellowing indices for two critical applications (ageing process follow-up and effect of cleaning), as demonstrated with synthetic and historical samples of varnished paper respectively.Spanish Ministry of Economy and Competitiveness, under research Grant DPI2015-64571-R. Spanish State Agency of Research (AEI) and the Ministry for Economy, Industry and Competitiveness (MIMECO) by means of the Grant Number FIS2017-89258-P with European Union FEDER (European Regional Development Funds) support

TECHNART 2017. Non-destructive and microanalytical techniques in art and cultural heritage. Book of abstracts

440 p.TECHNART2017 is the international biannual congress on the application of Analytical Techniques in Art and Cultural Heritage. The aim of this European conference is to provide a scientific forum to present and promote the use of analytical spectroscopic techniques in cultural heritage on a worldwide scale to stimulate contacts and exchange experiences, making a bridge between science and art. This conference builds on the momentum of the previous TECHNART editions of Lisbon, Athens, Berlin, Amsterdam and Catania, offering an outstanding and unique opportunity for exchanging knowledge on leading edge developments. Cultural heritage studies are interpreted in a broad sense, including pigments, stones, metal, glass, ceramics, chemometrics on artwork studies, resins, fibers, forensic applications in art, history, archaeology and conservation science. The meeting is focused in different aspects: - X-ray analysis (XRF, PIXE, XRD, SEM-EDX). - Confocal X-ray microscopy (3D Micro-XRF, 3D Micro-PIXE). - Synchrotron, ion beam and neutron based techniques/instrumentation. - FT-IR and Raman spectroscopy. - UV-Vis and NIR absorption/reflectance and fluorescence. - Laser-based analytical techniques (LIBS, etc.). - Magnetic resonance techniques. - Chromatography (GC, HPLC) and mass spectrometry. - Optical imaging and coherence techniques. - Mobile spectrometry and remote sensing

Digital Techniques for Documenting and Preserving Cultural Heritage

In this unique collection the authors present a wide range of interdisciplinary methods to study, document, and conserve material cultural heritage. The methods used serve as exemplars of best practice with a wide variety of cultural heritage objects having been recorded, examined, and visualised. The objects range in date, scale, materials, and state of preservation and so pose different research questions and challenges for digitization, conservation, and ontological representation of knowledge. Heritage science and specialist digital technologies are presented in a way approachable to non-scientists, while a separate technical section provides details of methods and techniques, alongside examples of notable applications of spatial and spectral documentation of material cultural heritage, with selected literature and identification of future research. This book is an outcome of interdisciplinary research and debates conducted by the participants of the COST Action TD1201, Colour and Space in Cultural Heritage, 2012–16 and is an Open Access publication available under a CC BY-NC-ND licence.https://scholarworks.wmich.edu/mip_arc_cdh/1000/thumbnail.jp

Digital Techniques for Documenting and Preserving Cultural Heritage

This book presents interdisciplinary approaches to the examination and documentation of material cultural heritage, using non-invasive spatial and spectral optical technologies