Modelling and data validation for the energy analysis of absorption refrigeration systems

Data validation and reconciliation techniques have been extensively used in the process industry to improve the data accuracy. These techniques exploit the redundancy in the measurements in order to obtain a set of adjusted measurements that satisfy the plant model. Nevertheless, not many applications deal with closed cycles with complex connectivity and recycle loops, as in absorption refrigeration cycles. This thesis proposes a methodology for the steady-state data validation of absorption refrigeration systems. This methodology includes the identification of steady-state, resolution of the data reconciliation and parameter estimation problems and the detection and elimination of gross errors. The methodology developed through this thesis will be useful for generating a set of coherent measurements and operation parameters of an absorption chiller for downstream applications: performance calculation, development of empirical models, optimisation, etc. The methodology is demonstrated using experimental data of different types of absorption refrigeration systems with different levels of redundancy.Los procedimientos de validación y reconciliación de datos se han utilizado en la industria de procesos para mejorar la precisión de los datos. Estos procedimientos aprovechan la redundancia enlas mediciones para obtener un conjunto de datos ajustados que satisfacen el modelo de la planta. Sin embargo, no hay muchas aplicaciones que traten con ciclos cerrados, y configuraciones complejas, como los ciclos de refrigeración por absorción. Esta tesis propone una metodología para la validación de datos en estado estacionario de enfriadoras de absorción. Estametodología incluye la identificación del estado estacionario, la resolución de los problemas de reconciliación de datos y estimación de parámetrosy la detección de errores sistemáticos. Esta metodología será útil para generar un conjunto de medidas coherentes para aplicaciones como: cálculo de prestaciones, desarrollo de modelos empíricos, optimización, etc. La metodología es demostrada utilizando datos experimentales de diferentes enfriadoras de absorción, con diferentes niveles de redundancia

The Optimal Implementation of On-Line Optimization for Chemical and Refinery Processes.

On-line optimization is an effective approach for process operation and economic improvement and source reduction in chemical and refinery processes. On-line optimization involves three steps of work as: data validation, parameter estimation, and economic optimization. This research evaluated statistical algorithms for gross error detection, data reconciliation, and parameter estimation, and developed an open-form steady state process model for the Monsanto designed sulfuric acid process of IMC Agrico Company. The plant model was used to demonstrate improved economics and reduced emissions from on-line optimization and to test the methodology of on-line optimization. Also, a modified compensation strategy was proposed to improve the misrectification of data reconciliation algorithms and it was compared with measurement test method. In addition, two ways to conduct on-line optimization were studied. One required two separated optimization problems to update parameters, and the other combined data validation and parameter estimation into one optimization problem. Two-step estimation demonstrated a better performance in estimation accuracy than one-step estimation for sulfuric acid process, while one-step estimation required less computation time. The measurement test method, Tjoa-Biegler\u27 contaminated Gaussian distribution method, and robust method were evaluated theoretically and numerically to compare the performance of these methods. Results from these evaluation were used to recommend the best way to conduct on-line optimization. The optimal procedure is to conduct combined gross error detection and data reconciliation to detect and rectify gross errors in plant data from DCS using Tjoa-Biegler\u27s method or robust method. This step generates a set of measurements containing only random errors which is used for simultaneous data reconciliation and parameter estimation using the least squares method (the normal distribution). Updated parameters are used in the plant model for economic optimization that generates optimal set points for DCS. Applying this procedure to the Monsanto sulfuric acid plant had an increased profit of 3% over current operating condition and an emission reduction of 10% which is consistent with other reported applications. Also, this optimal procedure to conduct on-line optimization has been incorporated into an interactive on-line optimization program which used a window interface developed with Visual Basic and GAMS to solve the nonlinear optimization problems. This program is to be available through the EPA Technology Tool Program

Dynamic Modeling, Sensor Placement Design, and Fault Diagnosis of Nuclear Desalination Systems

Fault diagnosis of sensors, devices, and equipment is an important topic in the nuclear industry for effective and continuous operation of nuclear power plants. All the fault diagnostic approaches depend critically on the sensors that measure important process variables. Whenever a process encounters a fault, the effect of the fault is propagated to some or all the process variables. The ability of the sensor network to detect and isolate failure modes and anomalous conditions is crucial for the effectiveness of a fault detection and isolation (FDI) system. However, the emphasis of most fault diagnostic approaches found in the literature is primarily on the procedures for performing FDI using a given set of sensors. Little attention has been given to actual sensor allocation for achieving the efficient FDI performance. This dissertation presents a graph-based approach that serves as a solution for the optimization of sensor placement to ensure the observability of faults, as well as the fault resolution to a maximum possible extent. This would potentially facilitate an automated sensor allocation procedure. Principal component analysis (PCA), a multivariate data-driven technique, is used to capture the relationships in the data, and to fit a hyper-plane to the data. The fault directions for different fault scenarios are obtained from the prediction errors, and fault isolation is then accomplished using new projections on these fault directions. The effectiveness of the use of an optimal sensor set versus a reduced set for fault detection and isolation is demonstrated using this technique. Among a variety of desalination technologies, the multi-stage flash (MSF) processes contribute substantially to the desalinating capacity in the world. In this dissertation, both steady-state and dynamic simulation models of a MSF desalination plant are developed. The dynamic MSF model is coupled with a previously developed International Reactor Innovative and Secure (IRIS) model in the SIMULINK environment. The developed sensor placement design and fault diagnostic methods are illustrated with application to the coupled nuclear desalination system. The results demonstrate the effectiveness of the newly developed integrated approach to performance monitoring and fault diagnosis with optimized sensor placement for large industrial systems

A hierarchy for modeling high speed propulsion systems

General research efforts on reduced order propulsion models for control systems design are overviewed. Methods for modeling high speed propulsion systems are discussed including internal flow propulsion systems that do not contain rotating machinery, such as inlets, ramjets, and scramjets. The discussion is separated into four areas: (1) computational fluid dynamics models for the entire nonlinear system or high order nonlinear models; (2) high order linearized models derived from fundamental physics; (3) low order linear models obtained from the other high order models; and (4) low order nonlinear models (order here refers to the number of dynamic states). Included in the discussion are any special considerations based on the relevant control system designs. The methods discussed are for the quasi-one-dimensional Euler equations of gasdynamic flow. The essential nonlinear features represented are large amplitude nonlinear waves, including moving normal shocks, hammershocks, simple subsonic combustion via heat addition, temperature dependent gases, detonations, and thermal choking. The report also contains a comprehensive list of papers and theses generated by this grant

Enhancement of Industrial Energy Efficiency and Sustainability

Industrial energy efficiency has been recognized as a major contributor, in the broader set of industrial resources, to improved sustainability and circular economy. Nevertheless, the uptake of energy efficiency measures and practices is still quite low, due to the existence of several barriers. Research has broadly discussed them, together with their drivers. More recently, many researchers have highlighted the existence of several benefits, beyond mere energy savings, stemming from the adoption of such measures, for several stakeholders involved in the value chain of energy efficiency solutions. Nevertheless, a deep understanding of the relationships between the use of the energy resource and other resources in industry, together with the most important factors for the uptake of such measures—also in light of the implications on the industrial operations—is still lacking. However, such understanding could further stimulate the adoption of solutions for improved industrial energy efficiency and sustainability

A state space approach to chemical plant fault detection

Imperial Users onl

Sensor Placement Algorithms for Process Efficiency Maximization

Even though the senor placement problem has been studied for process plants, it has been done for minimizing the number of sensors, minimizing the cost of the sensor network, maximizing the reliability, or minimizing the estimation errors. In the existing literature, no work has been reported on the development of a sensor network design (SND) algorithm for maximizing efficiency of the process. The SND problem for maximizing efficiency requires consideration of the closed-loop system, which is unlike the open-loop systems that have been considered in previous works. In addition, work on the SND problem for a large fossil energy plant such as an integrated gasification combined cycle (IGCC) power plant with CO2 capture is rare.;The objective of this research is to develop a SND algorithm for maximizing the plant performance using criteria such as efficiency in the case of an estimator-based control system. The developed algorithm will be particularly useful for sensor placement in IGCC plants at the grassroots level where the number, type, and location of sensors are yet to be identified. In addition, the same algorithm can be further enhanced for use in retrofits, where the objectives could be to upgrade (addition of more sensors) and relocate existing sensors to different locations. The algorithms are developed by considering the presence of an optimal Kalman Filter (KF) that is used to estimate the unmeasured and noisy measurements given the process model and a set of measured variables. The designed algorithms are able to determine the location and type of the sensors under constraints on budget and estimation accuracy. In this work, three SND algorithms are developed: (a) steady-state SND algorithm, (b) dynamic model-based SND algorithm, and (c) nonlinear model-based SND algorithm. These algorithms are implemented in an acid gas removal (AGR) unit as part of an IGCC power plant with CO2 capture. The AGR process involves extensive heat and mass integration and therefore, is very suitable for the study of the proposed algorithm in the presence of complex interactions between process variables