51 research outputs found

    Child rights jurisprudence without borders: developments in extraterritorial jurisdiction

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    Effective Protection of Fundamental Rights in a pluralist worl

    International children’s rights in polycrisis: interconnected pathways to social justice and a sustainable future

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    Inaugural Lecture by Prof. dr. Ann Marie Skelton on the acceptance of her position as Chair in Children’s Rights in a Sustainable World at Leiden University on 12 April 2024Inaugural Lecture by Prof. dr. Ann Marie Skelton on the acceptance of her position as Chair in Children’s Rights in a Sustainable World at Leiden University on 12 April 2024Effective Protection of Fundamental Rights in a pluralist worl

    Tracing the Use of the Family Management Framework and Measure: A Scoping Review

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    This article reports the results of a scoping review of research applications of the Family Management Style Framework (FMSF) and the Family Management Measure (FaMM). We identified 32 studies based on the FMSF and 41 studies in which the FaMM was used, 17 of which were based on the FMSF. Both the framework and measure have been used by investigators in multiple countries, with most applications of the FaMM outside the United States. Although the FMSF and FaMM were originally developed for use with families in which there was a child with a chronic physical condition, both have been applied to a broader range of health conditions and to studies focusing on families with an adult member facing a health challenge. Based on our findings, we make recommendations for how researchers can more fully address all aspects of the FMSF

    Anisotropy studies around the galactic centre at EeV energies with the Auger Observatory

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    Data from the Pierre Auger Observatory are analyzed to search for anisotropies near the direction of the Galactic Centre at EeV energies. The exposure of the surface array in this part of the sky is already significantly larger than that of the fore-runner experiments. Our results do not support previous findings of localized excesses in the AGASA and SUGAR data. We set an upper bound on a point-like flux of cosmic rays arriving from the Galactic Centre which excludes several scenarios predicting sources of EeV neutrons from Sagittarius AA. Also the events detected simultaneously by the surface and fluorescence detectors (the `hybrid' data set), which have better pointing accuracy but are less numerous than those of the surface array alone, do not show any significant localized excess from this direction.Comment: Matches published versio

    Coronavirus disease 2019 (COVID-19) research agenda for healthcare epidemiology

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    This SHEA white paper identifies knowledge gaps and challenges in healthcare epidemiology research related to coronavirus disease 2019 (COVID-19) with a focus on core principles of healthcare epidemiology. These gaps, revealed during the worst phases of the COVID-19 pandemic, are described in 10 sections: epidemiology, outbreak investigation, surveillance, isolation precaution practices, personal protective equipment (PPE), environmental contamination and disinfection, drug and supply shortages, antimicrobial stewardship, healthcare personnel (HCP) occupational safety, and return to work policies. Each section highlights three critical healthcare epidemiology research questions with detailed description provided in supplementary materials. This research agenda calls for translational studies from laboratory-based basic science research to well-designed, large-scale studies and health outcomes research. Research gaps and challenges related to nursing homes and social disparities are included. Collaborations across various disciplines, expertise and across diverse geographic locations will be critical

    Anionic Cyclometalated Platinum(II) Tetrazolato Complexes as Viable Photoredox Catalysts

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    The synthesis, characterization, photophysical and photocatalytic studies of anionic platinum(II) tetrazolato complexes, with the general structure [TBA][Pt(CNC)TzR], are reported, where CNC2- represents a doubly cyclometalated 2,4,6-triphenylpyridine, TzR- is an anionic 5-substituted tetrazolato ligand (with a variable R functional group), and TBA+ is the tetrabutylammonium countercation. The complexes were prepared by substitution of the DMSO ligand in [Pt(CNC)(DMSO)] with the corresponding tetrazolato ligand. No emission from the platinum(II) complexes was detected at room temperature in solution, but the photophysical properties could be assessed in the solid state, where all the complexes display emission bands attributed to aggregates. The platinum(II) complexes were found to facilitate a range of fundamental classes of visible-light-mediated photoredox-catalyzed reactions, including \u3b1-amino C-H functionalization processes, such as Povarov-type reactions and the addition of \u3b1-amino C-H bonds across Michael acceptors, in addition to ATRA chemistry, and a hydrodeiodination. With the exception of the hydrodeiodination process, the best Pt(II) catalysts provided turnover numbers of 150-175 in each of these transformations
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