Validity of the Law of Mass Action in Three-Dimensional Coagulation Processes

Diffusion-limited reactions are studied in detail on the classical coalescing process. We demonstrate how, with the aid of a recent renormalization group approach, fluctuations can be integrated systematically. We thereby obtain an exact relation between the microscopic physics (lattice structure and particle shape and size) and the macroscopic decay rate in the law of mass action. Moreover, we find a strong violation of the law of mass action. The corresponding term in the kinetic equations originates in longwavelength fluctuations and is a universal function of the macroscopic decay rate

Counting reducible, powerful, and relatively irreducible multivariate polynomials over finite fields

We present counting methods for some special classes of multivariate polynomials over a finite field, namely the reducible ones, the s-powerful ones (divisible by the s-th power of a nonconstant polynomial), and the relatively irreducible ones (irreducible but reducible over an extension field). One approach employs generating functions, another one uses a combinatorial method. They yield exact formulas and approximations with relative errors that essentially decrease exponentially in the input size.Comment: to appear in SIAM Journal on Discrete Mathematic

Ultralong Copper Phthalocyanine Nanowires with New Crystal Structure and Broad Optical Absorption

The development of molecular nanostructures plays a major role in emerging organic electronic applications, as it leads to improved performance and is compatible with our increasing need for miniaturisation. In particular, nanowires have been obtained from solution or vapour phase and have displayed high conductivity, or large interfacial areas in solar cells. In all cases however, the crystal structure remains as in films or bulk, and the exploitation of wires requires extensive post-growth manipulation as their orientations are random. Here we report copper phthalocyanine (CuPc) nanowires with diameters of 10-100 nm, high directionality and unprecedented aspect ratios. We demonstrate that they adopt a new crystal phase, designated eta-CuPc, where the molecules stack along the long axis. The resulting high electronic overlap along the centimetre length stacks achieved in our wires mediates antiferromagnetic couplings and broadens the optical absorption spectrum. The ability to fabricate ultralong, flexible metal phthalocyanine nanowires opens new possibilities for applications of these simple molecules

Adsorption in non interconnected pores open at one or at both ends: A reconsideration of the origin of the hysteresis phenomenon

We report on an experimental study of adsorption isotherme of nitrogen onto porous silicon with non interconnected pores open at one or at both ends in order to check for the first time the old (1938) but always current idea based on Cohan's description which suggests that the adsorption of gaz should occur reversibly in the first case and irreversibly in the second one. Hysteresis loops, the shape of which is usually associated to interconnections in porous media, are observed whether the pores are open at one or at both ends in contradiction with Cohan's model.Comment: 5 pages, 4 EPS figure

On the Sylow graph of a finite group

The final publication is available at Springer via http://dx.doi.org/10.1007/s11856-011-0138-xLet G be a finite group and Gp be a Sylow p-subgroup of G for a prime p in pi(G), the set of all prime divisors of the order of G. The automiser Ap(G) is defined to be the group NG(Gp)/GpCG(Gp). We define the Sylow graph gamma A(G) of the group G, with set of vertices pi(G), as follows: Two vertices p, q ¿ ¿(G) form an edge of ¿A(G) if either q ¿ ¿(Ap(G)) or p ¿ ¿(Aq(G)). The following result is obtained: Theorem: Let G be a finite almost simple group. Then the graph ¿A(G) is connected and has diameter at most 5. We also show how this result can be applied to derive information on the structure of a group from the normalizers of its Sylow subgroups.The second and third authors have been supported by Proyecto MTM2007-68010-C03-03 and Proyecto MTM2010-19938-C03-02, Ministerio de Educacion y Ciencia and FEDER, Spain.Kazarin, SL.; Martínez Pastor, A.; Pérez-Ramos, M. (2011). On the Sylow graph of a finite group. Israel Journal of Mathematics. 186(1):251-271. doi:10.1007/s11856-011-0138-xS2512711861Z. Arad and D. Chillag, Finite groups containing a nilpotent Hall subgroup of even order, Houston Journal of Mathematics 7 (1981), 23–32.H. Azad, Semi-simple elements of order 3 in finite Chevalley groups, Journal of Algebra 56 (1979), 481–498.A. Ballester-Bolinches, A. Martínez-Pastor, M. C. Pedraza-Aguilera and M. D. Pérez-Ramos, On nilpotent-like fitting formations, in Groups St. Andrews 2001 in Oxford, (C. M. Campbell et al., eds.) London Mathematical Society Lecture Note Series 304, Cambridge University Press, 2003, pp. 31–38.M. Bianchi, A. Gillio Berta Mauri and P. Hauck, On finite groups with nilpotent Sylow normalizers, Archiv der Mathematik 47 (1986), 193–197.A. Borel, R. Carter, C.W. Curtis, N. Iwahori, T. A. Springer, R. Steinberg, Seminar on Algebraic Groups and Related Finite Groups, Lecture Notes of Mathematics 131 Springer, Berlin, 1970.N. Bourbaki, Éléments de mathématique: Groupes et algèbres de Lie, Chapters IV, V, VI, Hermann, Paris, 1968.R. W. Carter, Simple groups of Lie type, Wiley, London, 1972.R. W. Carter, Conjugacy classes in the Weyl group, Compositio Mathematica 25 (1972), 1–59.R. W. Carter, Finite Groups of Lie Type: Conjugacy Classes and Complex Characters, Wiley, London, 1985.A. D’Aniello, C. De Vivo and G. Giordano, On certain saturated formations of finite groups, in Proceedings Ischia Group Theory 2006, (T. Hawkes, P. Longobardy and M. Maj, eds.) World Scientific, Hackensack, NJ, 2007, pp. 22–32.A. D’Aniello, C. De Vivo and G. Giordano, Lattice formations and Sylow normalizers: a conjecture, Atti del Seminario Matematico e Fisico dell’ Università di Modena e Reggio Emilia 55 (2007), 107–112.A. D’Aniello, C. De Vivo, G. Giordano and M. D. Pérez-Ramos, Saturated formations closed under Sylow normalizers, Communications in Algebra 33 (2005), 2801–2808.K. Doerk, T. Hawkes, Finite soluble groups, Walter De Gruyter, Berlin-New York, 1992.G. Glauberman, Prime-power factor groups of finite groups II, Mathematische Zeitschrift 117 (1970), 46–56.D. Gorenstein, R. Lyons, The local 2-structure of groups of characteristic 2 type, Memoirs of the American Mathematical Society 42, No. 276, Providence, RI, 1983.R. M. Guralnick, G. Malle and G. Navarro, Self-normalizing Sylow subgroups, Proceedings of the American Mathematical Society 132 (2004), 973–979.F. Menegazzo, M. C. Tamburini, A property of Sylow p-normalizers in simple groups, Quaderni del seminario Matematico di Brescia, n. 45/02 (2002).R. Steinberg, Lectures on Chevalley Groups, Yale University, New Haven, Conn., 1968.E. Stensholt, An application of Steinberg’s construction of twisted groups, Pacific Journal of Mathematics 55 (1974), 595–618.E. Stensholt, Certain embeddings among finite groups of Lie type, Journal of Algebra 53 (1978), 136–187.K. Zsigmondy, Zur Theorie der Potenzreste, Monatshefte für Mathematik and Physik 3 (1892), 265–284

On the order of an automorphism of a smooth hypersurface

In this paper we give an effective criterion as to when a positive integer q is the order of an automorphism of a smooth hypersurface of dimension n and degree d, for every d>2, n>1, (n,d)\neq (2,4), and \gcd(q,d)=\gcd(q,d-1)=1. This allows us to give a complete criterion in the case where q=p is a prime number. In particular, we show the following result: If X is a smooth hypersurface of dimension n and degree d admitting an automorphism of prime order p then p(d-1)^n then X is isomorphic to the Klein hypersurface, n=2 or n+2 is prime, and p=\Phi_{n+2}(1-d) where \Phi_{n+2} is the (n+2)-th cyclotomic polynomial. Finally, we provide some applications to intermediate jacobians of Klein hypersurfaces

Applying low-molecular weight supramolecular gelators in an environmental setting – self-assembled gels as smart materials for pollutant removal

This review explores supramolecular gels as materials for environmental remediation. These soft materials are formed by self-assembling low-molecular-weight building blocks, which can be programmed with molecular-scale information by simple organic synthesis. The resulting gels often have nanoscale ‘solid-like’ networks which are sample-spanning within a ‘liquid-like’ solvent phase. There is intimate contact between the solvent and the gel nanostructure, which has a very high effective surface area as a result of its dimensions. As such, these materials have the ability to bring a solid-like phase into contact with liquids in an environmental setting. Such materials can therefore remediate unwanted pollutants from the environment including: immobilisation of oil spills, removal of dyes, extraction of heavy metals or toxic anions, and the detection or removal of chemical weapons. Controlling the interactions between the gel nanofibres and pollutants can lead to selective uptake and extraction. Furthermore, if suitably designed, such materials can be recyclable and environmentally benign, while the responsive and tunable nature of the self-assembled network offers significant advantages over other materials solutions to problems caused by pollution in an environmental setting