84 research outputs found

    Effect of disorder on the magnetic and electronic structure of a prospective spin-gapless semiconductor MnCrVAl

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    Recent discovery of a new class of materials, spin-gapless semiconductors (SGS), has attracted considerable attention in the last few years, primarily due to potential applications in the emerging field of spin-based electronics (spintronics). Here, we investigate structural, electronic, and magnetic properties of one potential SGS compound, MnCr-VAl, using various experimental and theoretical techniques. Our calculations show that this material exhibits β‰ˆ 0.5 eV band gap for the majority-spin states, while for the minority-spin it is nearly gapless. The calculated magnetic moment for the com- pletely ordered structure is 2.9 ΞΌB/f.u., which is different from our experimentally measured value of almost zero. This discrepancy is explained by the structural disorder. In particular, A2 type disorder, where Mn or Cr atoms exchange their positions with Al atoms, results in induced antiferromagnetic exchange coupling, which, at a certain level of disorder, effectively reduces the total magnetic moment to zero. This is consistent with our x-ray diffraction measurements which indicate the presence of A2 disorder in all of our samples. In addition, we also show that B2 disorder does not result in antiferromagnetic exchange coupling and therefore does not significantly reduce the total magnetic moment

    Magnetic and magnetocaloric properties of Co2-xFexVGa Heusler alloys

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    The magnetic and magnetocaloric properties of iron-substituted Co2VGa alloys, Co2-xFexVGa (x = 0, 0.1, 0.15, 0.2, 0.3), were investigated. The Fe-substituted samples, prepared by arc melting, melt spinning, and annealing, crystallized in the L21 Heusler structure, without any secondary phases. The Curie temperature and highfield magnetization at 50 K decreased from 345 K and 44 emu/g (1.90 ΞΌB/f.u.) for Co2VGa to 275 K and 39 emu/g (1.66 ΞΌB/f.u.) for Co1.7Fe0.3VGa, respectively, but the maximum entropy change remained almost insensitive to Fe concentration for x ≀ 0.2, the highest value being 3.3 J/kgK at 7 T for Co1.85Fe0.15VGa. First-principle calculations show that Co2VGa retains its half-metallic band structure until at least 30% of the cobalt atoms are replaced by Fe atoms. The wide operating temperature window near room temperature and the lack of thermal and magnetic hysteresis are the interesting features of these materials for application in room-temperature magnetic refrigeration

    EMF 35 JMIP study for Japan’s long-term climate and energy policy: scenario designs and key findings

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    In June, 2019, Japan submitted its mid-century strategy to the United Nations Framework Convention on Climate Change and pledged 80% emissions cuts by 2050. The strategy has not gone through a systematic analysis, however. The present study, Stanford Energy Modeling Forum (EMF) 35 Japan Model Intercomparison project (JMIP), employs five energy-economic and integrated assessment models to evaluate the nationally determined contribution and mid-century strategy of Japan. EMF 35 JMIP conducts a suite of sensitivity analyses on dimensions including emissions constraints, technology availability, and demand projections. The results confirm that Japan needs to deploy all of its mitigation strategies at a substantial scale, including energy efficiency, electricity decarbonization, and end-use electrification. Moreover, they suggest that with the absence of structural changes in the economy, heavy industries will be one of the hardest to decarbonize. Partitioning of the sum of squares based on a two-way analysis of variance (ANOVA) reconfirms that mitigation strategies, such as energy efficiency and electrification, are fairly robust across models and scenarios, but that the cost metrics are uncertain. There is a wide gap of policy strength and breadth between the current policy instruments and those suggested by the models. Japan should strengthen its climate action in all aspects of society and economy to achieve its long-term target

    Effect of Fe substitution on the structural, magnetic and electron-transport properties of half-metallic Co2TiSi

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    The structural, magnetic and electron-transport properties of Co2Ti1-xFexSi (x = 0, 0.25, 0.5) ribbons prepared by arc-melting and melt-spinning were investigated. The rapidly quenched Co2Ti0.5Fe0.5Si crystallized in the cubic L21 structure whereas Co2Ti0.75Fe0.25Si and Co2TiFe0Si showed various degrees of B2-type disorder. At room temperature, all the samples are ferromagnetic, and the Curie temperature increased from 360 K for Co2TiSi to about 800 K for Co2Ti0.5Fe0.5Si. The measured magnetization also increased due to partial substitution of Fe for Ti atoms. The ribbons are moderately conducting and show positive temperature coefficient of resistivity with the room temperature resistivity being between 360 ¡Ωcm and 440 ¡Ωcm. The experimentally observed structural and magnetic properties are consistent with the results of first-principle calculations. Our calculations also indicate that the Co2Ti1-xFexSi compound remains nearly half-metallic for x ≀ 0.5. The predicted large band gaps and high Curie temperatures much above room temperature make these materials promising for room temperature spintronic and magnetic applications

    Effect of disorder on the magnetic and electronic structure of a prospective spin-gapless semiconductor MnCrVAl

    Get PDF
    Recent discovery of a new class of materials, spin-gapless semiconductors (SGS), has attracted considerable attention in the last few years, primarily due to potential applications in the emerging field of spin-based electronics (spintronics). Here, we investigate structural, electronic, and magnetic properties of one potential SGS compound, MnCrVAl, using various experimental and theoretical techniques. Our calculations show that this material exhibits β‰ˆ 0.5 eV band gap for the majority-spin states, while for the minority-spin it is nearly gapless. The calculated magnetic moment for the completely ordered structure is 2.9 Β΅B/f.u., which is different from our experimentally measured value of almost zero. This discrepancy is explained by the structural disorder. In particular, A2 type disorder, where Mn or Cr atoms exchange their positions with Al atoms, results in induced antiferromagnetic exchange coupling, which, at a certain level of disorder, effectively reduces the total magnetic moment to zero. This is consistent with our x-ray diffraction measurements which indicate the presence of A2 disorder in all of our samples. In addition, we also show that B2 disorder does not result in antiferromagnetic exchange coupling and therefore does not significantly reduce the total magnetic moment

    Magnetic and magnetocaloric properties of Co2-xFexVGa Heusler alloys

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    The magnetic and magnetocaloric properties of iron-substituted Co2VGa alloys, Co2-xFexVGa (x = 0, 0.1, 0.15, 0.2, 0.3), were investigated. The Fe-substituted samples, prepared by arc melting, melt spinning, and annealing, crystallized in the L2(1) Heusler structure, without any secondary phases. The Curie temperature and high-field magnetization at 50 K decreased from 345 K and 44 emu/g (1.90 mu(B)/f.u.) for Co2VGa to 275 K and 39 emu/g (1.66 mu(B)/f.u.) for Co1.7Fe0.3VGa, respectively, but the maximum entropy change remained almost insensitive to Fe concentration for x 1.85Fe0.15VGa. First-principle calculations show that Co2VGa retains its half-metallic band structure until at least 30% of the cobalt atoms are replaced by Fe atoms. The wide operating temperature window near room temperature and the lack of thermal and magnetic hysteresis are the interesting features of these materials for application in room-temperature magnetic refrigeration. (c) 2018 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). https://doi.org/10.1063/1.500664

    C14ORF39/SIX6OS1 is a constituent of the synaptonemal complex and is essential for mouse fertility

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    Meiotic recombination generates crossovers between homologous chromosomes that are essential for genome haploidization. The synaptonemal complex is a β€˜zipper’-like protein assembly that synapses homologue pairs together and provides the structural framework for processing recombination sites into crossovers. Humans show individual differences in the number of crossovers generated across the genome. Recently, an anonymous gene variant in C14ORF39/SIX6OS1 was identified that influences the recombination rate in humans. Here we show that C14ORF39/SIX6OS1 encodes a component of the central element of the synaptonemal complex. Yeast two-hybrid analysis reveals that SIX6OS1 interacts with the well-established protein synaptonemal complex central element 1 (SYCE1). Mice lacking SIX6OS1 are defective in chromosome synapsis at meiotic prophase I, which provokes an arrest at the pachytene-like stage and results in infertility. In accordance with its role as a modifier of the human recombination rate, SIX6OS1 is essential for the appropriate processing of intermediate recombination nodules before crossover formation.This work was supported by BFU_2014-59307-R, MEIONet and JCyLe (CSI052U16). LGH and NFM are supported by European Social Fund/JCyLe grants (EDU/1083/2013 and EDU/310/2015). ORD is a Sir Henry Dale Fellow jointly funded by the Wellcome Trust and Royal Society (Grant Number 104158/Z/14/Z). RB is funded by DFG (grant Be1168/8-1). AT and ID were supported by DFG grants TO421/8-2 and TO421/6-1, respectively.Peer reviewe

    Interplay between Synaptonemal Complex, Homologous Recombination, and Centromeres during Mammalian Meiosis

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    The intimate synapsis of homologous chromosome pairs (homologs) by synaptonemal complexes (SCs) is an essential feature of meiosis. In many organisms, synapsis and homologous recombination are interdependent: recombination promotes SC formation and SCs are required for crossing-over. Moreover, several studies indicate that initiation of SC assembly occurs at sites where crossovers will subsequently form. However, recent analyses in budding yeast and fruit fly imply a special role for centromeres in the initiation of SC formation. In addition, in budding yeast, persistent SC–dependent centromere-association facilitates the disjunction of chromosomes that have failed to become connected by crossovers. Here, we examine the interplay between SCs, recombination, and centromeres in a mammal. In mouse spermatocytes, centromeres do not serve as SC initiation sites and are invariably the last regions to synapse. However, centromeres are refractory to de-synapsis during diplonema and remain associated by short SC fragments. Since SC–dependent centromere association is lost before diakinesis, a direct role in homolog segregation seems unlikely. However, post–SC disassembly, we find evidence of inter-centromeric connections that could play a more direct role in promoting homolog biorientation and disjunction. A second class of persistent SC fragments is shown to be crossover-dependent. Super-resolution structured-illumination microscopy (SIM) reveals that these structures initially connect separate homolog axes and progressively diminish as chiasmata form. Thus, DNA crossing-over (which occurs during pachynema) and axis remodeling appear to be temporally distinct aspects of chiasma formation. SIM analysis of the synapsis and crossover-defective mutant Sycp1βˆ’/βˆ’ implies that SCs prevent unregulated fusion of homolog axes. We propose that SC fragments retained during diplonema stabilize nascent bivalents and help orchestrate local chromosome reorganization that promotes centromere and chiasma function

    Phosphorylation of Chromosome Core Components May Serve as Axis Marks for the Status of Chromosomal Events during Mammalian Meiosis

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    Meiotic recombination and chromosome synapsis between homologous chromosomes are essential for proper chromosome segregation at the first meiotic division. While recombination and synapsis, as well as checkpoints that monitor these two events, take place in the context of a prophase I-specific axial chromosome structure, it remains unclear how chromosome axis components contribute to these processes. We show here that many protein components of the meiotic chromosome axis, including SYCP2, SYCP3, HORMAD1, HORMAD2, SMC3, STAG3, and REC8, become post-translationally modified by phosphorylation during the prophase I stage. We found that HORMAD1 and SMC3 are phosphorylated at a consensus site for the ATM/ATR checkpoint kinase and that the phosphorylated forms of HORMAD1 and SMC3 localize preferentially to unsynapsed chromosomal regions where synapsis has not yet occurred, but not to synapsed or desynapsed regions. We investigated the genetic requirements for the phosphorylation events and revealed that the phosphorylation levels of HORMAD1, HORMAD2, and SMC3 are dramatically reduced in the absence of initiation of meiotic recombination, whereas BRCA1 and SYCP3 are required for normal levels of phosphorylation of HORMAD1 and HORMAD2, but not of SMC3. Interestingly, reduced HORMAD1 and HORMAD2 phosphorylation is associated with impaired targeting of the MSUC (meiotic silencing of unsynapsed chromatin) machinery to unsynapsed chromosomes, suggesting that these post-translational events contribute to the regulation of the synapsis surveillance system. We propose that modifications of chromosome axis components serve as signals that facilitate chromosomal events including recombination, checkpoint control, transcription, and synapsis regulation
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