Hot-carrier photocurrent effects at graphene-metal interfaces

Photoexcitation of graphene leads to an interesting sequence of phenomena, some of which can be exploited in optoelectronic devices based on graphene. In particular, the efficient and ultrafast generation of an electron distribution with an elevated electron temperature and the concomitant generation of a photo-thermoelectric voltage at symmetry-breaking interfaces is of interest for photosensing and light harvesting. Here, we experimentally study the generated photocurrent at the graphene-metal interface, focusing on the time-resolved photocurrent, the effects of photon energy, Fermi energy and light polarization. We show that a single framework based on photo-thermoelectric photocurrent generation explains all experimental results

Is it cheating or learning the craft of writing? Using Turnitin to help students avoid plagiarism

Plagiarism is a growing problem for universities, many of which are turning to software detection for help in detecting and dealing with it. This paper explores issues around plagiarism and reports on a study of the use of Turnitin in a new university. The purpose of the study was to inform the senior management team about the plagiarism policy and the use of Turnitin. The study found that staff and students largely understood the university’s policy and Turnitin’s place within it, and were very supportive of the use of Turnitin in originality checking. Students who had not used Turnitin were generally keen to do so. The recommendation to the senior management team, which was implemented, was that the use of Turnitin for originality checking should be made compulsory where possible - at the time of the study the use of Turnitin was at the discretion of programme directors. A further aim of the study was to contribute to the sector’s body of knowledge. Prevention of plagiarism through education is a theme identified by Badge and Scott (2009) who conclude an area lacking in research is "investigation of the impact of these tools on staff teaching practices". Although a number of recent studies have considered educational use of Turnitin they focus on individual programmes or subject areas rather than institutions as a whole and the relationship with policy

Generation of photovoltage in graphene on a femtosecond time scale through efficient carrier heating

Graphene is a promising material for ultrafast and broadband photodetection. Earlier studies addressed the general operation of graphene-based photo-thermoelectric devices, and the switching speed, which is limited by the charge carrier cooling time, on the order of picoseconds. However, the generation of the photovoltage could occur at a much faster time scale, as it is associated with the carrier heating time. Here, we measure the photovoltage generation time and find it to be faster than 50 femtoseconds. As a proof-of-principle application of this ultrafast photodetector, we use graphene to directly measure, electrically, the pulse duration of a sub-50 femtosecond laser pulse. The observation that carrier heating is ultrafast suggests that energy from absorbed photons can be efficiently transferred to carrier heat. To study this, we examine the spectral response and find a constant spectral responsivity between 500 and 1500 nm. This is consistent with efficient electron heating. These results are promising for ultrafast femtosecond and broadband photodetector applications.Comment: 6 pages, 4 figure

A cardinal role for cathepsin D in co-ordinating the host-mediated apoptosis of macrophages and killing of pneumococci

The bactericidal function of macrophages against pneumococci is enhanced by their apoptotic demise, which is controlled by the anti-apoptotic protein Mcl-1. Here, we show that lysosomal membrane permeabilization (LMP) and cytosolic translocation of activated cathepsin D occur prior to activation of a mitochondrial pathway of macrophage apoptosis. Pharmacological inhibition or knockout of cathepsin D during pneumococcal infection blocked macrophage apoptosis. As a result of cathepsin D activation, Mcl-1 interacted with its ubiquitin ligase Mule and expression declined. Inhibition of cathepsin D had no effect on early bacterial killing but inhibited the late phase of apoptosis-associated killing of pneumococci in vitro. Mice bearing a cathepsin D-/- hematopoietic system demonstrated reduced macrophage apoptosis in vivo, with decreased clearance of pneumococci and enhanced recruitment of neutrophils to control pulmonary infection. These findings establish an unexpected role for a cathepsin D-mediated lysosomal pathway of apoptosis in pulmonary host defense and underscore the importance of apoptosis-associated microbial killing to macrophage function

Intrinsic Plasmon-Phonon Interactions in Highly Doped Graphene: A Near-Field Imaging Study.

Author's accepted versionFinal version available from ACS via the DOI in this recordAs a two-dimensional semimetal, graphene offers clear advantages for plasmonic applications over conventional metals, such as stronger optical field confinement, in situ tunability, and relatively low intrinsic losses. However, the operational frequencies at which plasmons can be excited in graphene are limited by the Fermi energy EF, which in practice can be controlled electrostatically only up to a few tenths of an electronvolt. Higher Fermi energies open the door to novel plasmonic devices with unprecedented capabilities, particularly at mid-infrared and shorter-wave infrared frequencies. In addition, this grants us a better understanding of the interaction physics of intrinsic graphene phonons with graphene plasmons. Here, we present FeCl3-intercalated graphene as a new plasmonic material with high stability under environmental conditions and carrier concentrations corresponding to EF > 1 eV. Near-field imaging of this highly doped form of graphene allows us to characterize plasmons, including their corresponding lifetimes, over a broad frequency range. For bilayer graphene, in contrast to the monolayer system, a phonon-induced dipole moment results in increased plasmon damping around the intrinsic phonon frequency. Strong coupling between intrinsic graphene phonons and plasmons is found, supported by ab initio calculations of the coupling strength, which are in good agreement with the experimental data.FJGA and PA-G acknowledge support from the Spanish Ministry of Economy and Competitiveness through the national programs MAT2014-59096-P and FIS2014-60195-JIN, respectively. MFC and SR acknowledge support from EPSRC (Grant no. EP/J000396/1, 281 EP/K017160/1, EP/K010050/1, EPG036101/1, EP/M001024/1, EPM- 002438/1), from Royal Society International Exchanges Scheme 2012/R3 and 2013/R2 and from European Commission (FP7-ICT-2013-613024-GRASP). SD, DNB and MF acknowledge support of ONR N00014-15-1-2671. DNB is the Moore Investigator in Quantum Materials funded by the Gordon and Betty Moore Foundation’s EPiQS Initiative through Grant GBMF4533

Spatial correlation of aftershock locations and on-fault main shock properties

[1] We quantify the correlation between spatial patterns of aftershock hypocenter locations and the distribution of coseismic slip and stress drop on a main shock fault plane using two nonstandard statistical tests. Test T1 evaluates if aftershock hypocenters are located in low‐slip regions (hypothesis H1), test T2 evaluates if aftershock hypocenters occur in regions of increased shear stress (hypothesis H2). In the tests, we seek to reject the null hypotheses H0: Aftershock hypocenters are not correlated with (1) low‐slip regions or (2) regions of increased shear stress, respectively. We tested the hypotheses on four strike‐slip events for which multiple earthquake catalogs and multiple finite fault source models of varying accuracy exist. Because we want to retain earthquake clustering as the fundamental feature of aftershock seismicity, we generate slip distributions using a random spatial field model and derive the stress drop distributions instead of generating seismicity catalogs. We account for uncertainties in the aftershock locations by simulating them within their location error bounds. Our findings imply that aftershocks are preferentially located in regions of low‐slip (u ≤ equation imageu max) and of increased shear stress (Δσ < 0). In particular, the correlation is more significant for relocated than for general network aftershock catalogs. However, the results show that stress drop patterns provide less information content on aftershock locations. This implies that static shear stress change of the main shock may not be the governing process for aftershock genesis.ISSN:2169-9313ISSN:0148-0227ISSN:2169-935

Aftershock Sequences Modeled with 3-D Stress Heterogeneity and Rate-State Seismicity Equations: Implications for Crustal Stress Estimation

In this paper, we present a model for studying aftershock sequences that integrates Coulomb static stress change analysis, seismicity equations based on rate-state friction nucleation of earthquakes, slip of geometrically complex faults, and fractal-like, spatially heterogeneous models of crustal stress. In addition to modeling instantaneous aftershock seismicity rate patterns with initial clustering on the Coulomb stress increase areas and an approximately 1/t diffusion back to the pre-mainshock background seismicity, the simulations capture previously unmodeled effects. These include production of a significant number of aftershocks in the traditional Coulomb stress shadow zones and temporal changes in aftershock focal mechanism statistics. The occurrence of aftershock stress shadow zones arises from two sources. The first source is spatially heterogeneous initial crustal stress, and the second is slip on geometrically rough faults, which produces localized positive Coulomb stress changes within the traditional stress shadow zones. Temporal changes in simulated aftershock focal mechanisms result in inferred stress rotations that greatly exceed the true stress rotations due to the main shock, even for a moderately strong crust (mean stress 50 MPa) when stress is spatially heterogeneous. This arises from biased sampling of the crustal stress by the synthetic aftershocks due to the non-linear dependence of seismicity rates on stress changes. The model indicates that one cannot use focal mechanism inversion rotations to conclusively demonstrate low crustal strength (≤10 MPa); therefore, studies of crustal strength following a stress perturbation may significantly underestimate the mean crustal stress state for regions with spatially heterogeneous stress

NMRDyn: A Program for NMR Relaxation Studies of Protein Association

Self-association is an important biological phenomenon that is associated with many cellular processes. NMR relaxation measurements provide data about protein molecular dynamics at the atomic level and are sensitive to changes induced by self-association. Thus, measurements and analysis of NMR relaxation data can provide structurally resolved information on self-association that would not be accessible otherwise. Here, we present a computer program, NMRdyn, which analyses relaxation data to provide parameters defining protein self-association. Unlike existing relaxation analysis software, NMRdyn can explicitly model the monomer-oligomer equilibrium while fitting measured relaxation data. Additionally, the program is packaged with a user-friendly interface, which is important because relaxation data can often be large and complex. NMRdyn is available from http://research1t.imb.uq.edu.au/nmr/NMRdyn

All-Optical Generation of Surface Plasmons in Graphene

27 pages, 12 figures, includes supplementary materialarXiv is an e-print service in the fields of physics, mathematics, computer science, quantitative biology, quantitative finance and statistics.Here we present an all-optical plasmon coupling scheme, utilising the intrinsic nonlinear optical response of graphene. We demonstrate coupling of free-space, visible light pulses to the surface plasmons in a planar, un-patterned graphene sheet by using nonlinear wave mixing to match both the wavevector and energy of the surface wave. By carefully controlling the phase-matching conditions, we show that one can excite surface plasmons with a defined wavevector and direction across a large frequency range, with an estimated photon efficiency in our experiments approaching $10^{-5}$

Statistical properties of seismicity of fault zones at different evolutionary stages

We perform a systematic parameter space study of the seismic response of a large fault with different levels of heterogeneity, using a 3-D elastic framework within the continuum limit. The fault is governed by rate-and-state friction and simulations are performed for model realizations with frictional and large scale properties characterized by different ranges of size scales. We use a number of seismicity and stress functions to characterize different types of seismic responses and test the correlation between hypocenter locations and the employed distributions of model parameters. The simulated hypocenters are found to correlate significantly with small L values of the rate-and-state friction. The final sizes of earthquakes are correlated with physical properties at their nucleation sites. The obtained stacked scaling relations are overall self-similar and have good correspondence with properties of natural earthquakes