Electron Impact Studies on Halogen Containing Molecules

The work described in this thesis has been divided into three sections, namely: 1. "The Latent Heat of Sublimation of Carbon and the Heat of Dissociation of Nitrogen." 2. "The Mass Spectra of Camphor and Some of its Halogen Derivatives." 3. "Electron Impact Studies on some Chlorinated Benzaldehydes." In Section 1 a study of the ionization and dissoc-riation of the molecules CX4 (X = F,Cl,Br); CHX3, CH2X2, CH3X (X = Cl,Br) and NH3 was undertaken. Appearance potentials of some of the positive ions produced under electron bombardment were obtained for each compound, while a suitable method was devised for the generation of some of the corresponding free radicals and the measure-sment of their ionization potentials. Dissociation processes were then selected to account for the formation of each ion. Combination of the experimental data in the appropriate equations then gave a series of bond dissoc-siation energies from which the heat of atomization of each compound was obtained. Substitution of this heat of atomization in a suitable thermochemical cycle then all:owed a value for the latent heat of carbon (Lc) or the heat of dissociation of nitrogen, D(N2), to be estimated. Prom the results it was concluded that Lc = 7.386 eV., and D(N2) = 9.756 eV. are most likely to be correct. In Section 2, the "Cracking Patterns" of camphor, alpha-bromo-, alpha-chloro-, beta-bromo-, beta-iodo-, alpha:alpha-dibromo- and alpha:beta-dibromo camphors are recorded. An attempt was then made to explain the occurrence of the principal peaks of each spectrum in terms of the current theories of the origin of mass spectra and to interpret the differences in the spectra of the seven compounds with the variation in molecular structure. This has been fulfilled with some modicum of success. Plausible mechanisms, based on such generalizations as facile allylic bond fission, ready elimination of CO and the occurrence of rearrange:ments promoted by the relative stabilities of the fragment ions, have been proposed for the production of the more prominent ions observed. It is emphasized that the results of the present work can only give an indication rather than a conclusive proof of the behaviour of the camphor skeleton under electron impact. In Section 3, the appearance and ionization potentials of some of the ions produced in the electron impact induced dissociation of o-, m- and p- chlorobenzalde-:hydes are recorded. The dissociation energies of the bond between CHO and the aromatic nucleus, D(Ar-CHO), was measured in each case, and compared with that of benzaldehyde itself. It was then possible to interpret the results in terms of the Inductive and Conjugative effects of the substituent chlorine atom. The dissociation energies of the corresponding bond in the molecule ion, D(Ar+-CHO), were also obtained. The relationship between D(Ar-CHO) and D(Ar+-CHO) was discussed, resulting in the tentative proposal that a benzaldehyde type molecule ion may undergo ring expansion to give an ionized derivative of tropone

A New Giant Stellar Structure in the Outer Halo of M31

The Sloan Digital Sky Survey has revealed an overdensity of luminous red giant stars ~ 3 degrees (40 projected kpc) to the northeast of M31, which we have called Andromeda NE. The line-of-sight distance to Andromeda NE is within approximately 50 kpc of M31; Andromeda NE is not a physically unrelated projection. Andromeda NE has a g-band absolute magnitude of ~ -11.6 and central surface brightness of ~ 29 mag/sq.arcsec, making it nearly two orders of magnitude more diffuse than any known Local Group dwarf galaxy at that luminosity. Based on its distance and morphology, Andromeda NE is likely undergoing tidal disruption. Andromeda NE's red giant branch color is unlike that of M31's present-day outer disk or the stellar stream reported by Ibata et al. (2001), arguing against a direct link between Andromeda NE and these structures. However, Andromeda NE has a red giant branch color similar to that of the G1 clump; it is possible that these structures are both material torn off of M31's disk in the distant past, or that these are both part of one ancient stellar stream.Comment: 11 pages, 3 figures; ApJ Letters accepted versio

New insights on the Draco dwarf spheroidal galaxy from SDSS: a larger radius and no tidal tails

We have investigated the spatial extent and structure of the Draco dwarf spheroidal galaxy using deep wide-field multicolor CCD photometry from the Sloan Digital Sky Survey (SDSS). Our study covers an area of 27 square degrees around the center of the Draco dwarf. We show that the spatial distribution of Draco's red giants, red horizontal branch stars and subgiants down to i=21.7 mag does not provide evidence for the existence of tidally induced tails or a halo of unbound stars. The radial profile can be fit by King models as well as by a generalized exponential. The core radius and the limiting (or tidal) radius along the major axis are 7.7' and 40.1', respectively, making Draco 40% larger than previously measured. Down to our magnitude limit tidal effects can only exist at a level of 10^-3 of the central surface density of Draco or below. The regular structure of Draco found from the new data argues against it being a portion of an unbound tidal stream and lends support to the assumption of dynamical equilibrium. We estimate Draco's total mass to be 2.2 - 3.5 times 10^7 solar masses. We obtain an overall mass-to-light ratio of 146+-42 or 92+-28 solar masses depending on the details of the mass and luminosity estimates. In summary, our results strengthen the case for a strongly dark matter dominated, bound stellar system. (Abstract strongly abridged).Comment: 30 pages, 11 figures (in part with degraded resolution). Accepted for publication in the Astronomical Journa

The Multi-Object, Fiber-Fed Spectrographs for SDSS and the Baryon Oscillation Spectroscopic Survey

We present the design and performance of the multi-object fiber spectrographs for the Sloan Digital Sky Survey (SDSS) and their upgrade for the Baryon Oscillation Spectroscopic Survey (BOSS). Originally commissioned in Fall 1999 on the 2.5-m aperture Sloan Telescope at Apache Point Observatory, the spectrographs produced more than 1.5 million spectra for the SDSS and SDSS-II surveys, enabling a wide variety of Galactic and extra-galactic science including the first observation of baryon acoustic oscillations in 2005. The spectrographs were upgraded in 2009 and are currently in use for BOSS, the flagship survey of the third-generation SDSS-III project. BOSS will measure redshifts of 1.35 million massive galaxies to redshift 0.7 and Lyman-alpha absorption of 160,000 high redshift quasars over 10,000 square degrees of sky, making percent level measurements of the absolute cosmic distance scale of the Universe and placing tight constraints on the equation of state of dark energy. The twin multi-object fiber spectrographs utilize a simple optical layout with reflective collimators, gratings, all-refractive cameras, and state-of-the-art CCD detectors to produce hundreds of spectra simultaneously in two channels over a bandpass covering the near ultraviolet to the near infrared, with a resolving power R = \lambda/FWHM ~ 2000. Building on proven heritage, the spectrographs were upgraded for BOSS with volume-phase holographic gratings and modern CCD detectors, improving the peak throughput by nearly a factor of two, extending the bandpass to cover 360 < \lambda < 1000 nm, and increasing the number of fibers from 640 to 1000 per exposure. In this paper we describe the original SDSS spectrograph design and the upgrades implemented for BOSS, and document the predicted and measured performances.Comment: 43 pages, 42 figures, revised according to referee report and accepted by AJ. Provides background for the instrument responsible for SDSS and BOSS spectra. 4th in a series of survey technical papers released in Summer 2012, including arXiv:1207.7137 (DR9), arXiv:1207.7326 (Spectral Classification), and arXiv:1208.0022 (BOSS Overview

Sloan Digital Sky Survey Imaging of Low Galactic Latitude Fields: Technical Summary and Data Release

The Sloan Digital Sky Survey (SDSS) mosaic camera and telescope have obtained five-band optical-wavelength imaging near the Galactic plane outside of the nominal survey boundaries. These additional data were obtained during commissioning and subsequent testing of the SDSS observing system, and they provide unique wide-area imaging data in regions of high obscuration and star formation, including numerous young stellar objects, Herbig-Haro objects and young star clusters. Because these data are outside the Survey regions in the Galactic caps, they are not part of the standard SDSS data releases. This paper presents imaging data for 832 square degrees of sky (including repeats), in the star-forming regions of Orion, Taurus, and Cygnus. About 470 square degrees are now released to the public, with the remainder to follow at the time of SDSS Data Release 4. The public data in Orion include the star-forming region NGC 2068/NGC 2071/HH24 and a large part of Barnard's loop.Comment: 31 pages, 9 figures (3 missing to save space), accepted by AJ, in press, see http://photo.astro.princeton.edu/oriondatarelease for data and paper with all figure

The Fifth Data Release of the Sloan Digital Sky Survey

This paper describes the Fifth Data Release (DR5) of the Sloan Digital Sky Survey (SDSS). DR5 includes all survey quality data taken through June 2005 and represents the completion of the SDSS-I project (whose successor, SDSS-II will continue through mid-2008). It includes five-band photometric data for 217 million objects selected over 8000 square degrees, and 1,048,960 spectra of galaxies, quasars, and stars selected from 5713 square degrees of that imaging data. These numbers represent a roughly 20% increment over those of the Fourth Data Release; all the data from previous data releases are included in the present release. In addition to "standard" SDSS observations, DR5 includes repeat scans of the southern equatorial stripe, imaging scans across M31 and the core of the Perseus cluster of galaxies, and the first spectroscopic data from SEGUE, a survey to explore the kinematics and chemical evolution of the Galaxy. The catalog database incorporates several new features, including photometric redshifts of galaxies, tables of matched objects in overlap regions of the imaging survey, and tools that allow precise computations of survey geometry for statistical investigations.Comment: ApJ Supp, in press, October 2007. This paper describes DR5. The SDSS Sixth Data Release (DR6) is now public, available from http://www.sdss.or

The Eighth Data Release of the Sloan Digital Sky Survey: First Data from SDSS-III

The Sloan Digital Sky Survey (SDSS) started a new phase in August 2008, with new instrumentation and new surveys focused on Galactic structure and chemical evolution, measurements of the baryon oscillation feature in the clustering of galaxies and the quasar Ly alpha forest, and a radial velocity search for planets around ~8000 stars. This paper describes the first data release of SDSS-III (and the eighth counting from the beginning of the SDSS). The release includes five-band imaging of roughly 5200 deg^2 in the Southern Galactic Cap, bringing the total footprint of the SDSS imaging to 14,555 deg^2, or over a third of the Celestial Sphere. All the imaging data have been reprocessed with an improved sky-subtraction algorithm and a final, self-consistent photometric recalibration and flat-field determination. This release also includes all data from the second phase of the Sloan Extension for Galactic Understanding and Evolution (SEGUE-2), consisting of spectroscopy of approximately 118,000 stars at both high and low Galactic latitudes. All the more than half a million stellar spectra obtained with the SDSS spectrograph have been reprocessed through an improved stellar parameters pipeline, which has better determination of metallicity for high metallicity stars.Comment: Astrophysical Journal Supplements, in press (minor updates from submitted version

The Seventh Data Release of the Sloan Digital Sky Survey

This paper describes the Seventh Data Release of the Sloan Digital Sky Survey (SDSS), marking the completion of the original goals of the SDSS and the end of the phase known as SDSS-II. It includes 11663 deg^2 of imaging data, with most of the roughly 2000 deg^2 increment over the previous data release lying in regions of low Galactic latitude. The catalog contains five-band photometry for 357 million distinct objects. The survey also includes repeat photometry over 250 deg^2 along the Celestial Equator in the Southern Galactic Cap. A coaddition of these data goes roughly two magnitudes fainter than the main survey. The spectroscopy is now complete over a contiguous area of 7500 deg^2 in the Northern Galactic Cap, closing the gap that was present in previous data releases. There are over 1.6 million spectra in total, including 930,000 galaxies, 120,000 quasars, and 460,000 stars. The data release includes improved stellar photometry at low Galactic latitude. The astrometry has all been recalibrated with the second version of the USNO CCD Astrograph Catalog (UCAC-2), reducing the rms statistical errors at the bright end to 45 milli-arcseconds per coordinate. A systematic error in bright galaxy photometr is less severe than previously reported for the majority of galaxies. Finally, we describe a series of improvements to the spectroscopic reductions, including better flat-fielding and improved wavelength calibration at the blue end, better processing of objects with extremely strong narrow emission lines, and an improved determination of stellar metallicities. (Abridged)Comment: 20 pages, 10 embedded figures. Accepted to ApJS after minor correction

The 2.5 m Telescope of the Sloan Digital Sky Survey

We describe the design, construction, and performance of the Sloan Digital Sky Survey Telescope located at Apache Point Observatory. The telescope is a modified two-corrector Ritchey-Chretien design which has a 2.5-m, f/2.25 primary, a 1.08-m secondary, a Gascoigne astigmatism corrector, and one of a pair of interchangeable highly aspheric correctors near the focal focal plane, one for imaging and the other for spectroscopy. The final focal ratio is f/5. The telescope is instrumented by a wide-area, multiband CCD camera and a pair of fiber-fed double spectrographs. Novel features of the telescope include: (1) A 3 degree diameter (0.65 m) focal plane that has excellent image quality and small geometrical distortions over a wide wavelength range (3000 to 10,600 Angstroms) in the imaging mode, and good image quality combined with very small lateral and longitudinal color errors in the spectroscopic mode. The unusual requirement of very low distortion is set by the demands of time-delay-and-integrate (TDI) imaging; (2) Very high precision motion to support open loop TDI observations; and (3) A unique wind baffle/enclosure construction to maximize image quality and minimize construction costs. The telescope had first light in May 1998 and began regular survey operations in 2000.Comment: 87 pages, 27 figures. AJ (in press, April 2006

The Second Data Release of the Sloan Digital Sky Survey

The Sloan Digital Sky Survey (SDSS) has validated and made publicly available its Second Data Release. This data release consists of 3324 deg2 of five-band (ugriz) imaging data with photometry for over 88 million unique objects, 367,360 spectra of galaxies, quasars, stars, and calibrating blank sky patches selected over 2627 deg2 of this area, and tables of measured parameters from these data. The imaging data reach a depth of r ≈ 22.2 (95% completeness limit for point sources) and are photometrically and astrometrically calibrated to 2% rms and 100 mas rms per coordinate, respectively. The imaging data have all been processed through a new version of the SDSS imaging pipeline, in which the most important improvement since the last data release is fixing an error in the model fits to each object. The result is that model magnitudes are now a good proxy for point-spread function magnitudes for point sources, and Petrosian magnitudes for extended sources. The spectroscopy extends from 3800 to 9200 Å at a resolution of 2000. The spectroscopic software now repairs a systematic error in the radial velocities of certain types of stars and has substantially improved spectrophotometry. All data included in the SDSS Early Data Release and First Data Release are reprocessed with the improved pipelines and included in the Second Data Release. Further characteristics of the data are described, as are the data products themselves and the tools for accessing them