Charge ordering induces a smectic phase in oblate ionic liquid crystals

We report a computer simulation study of an electroneutral mixture of oppositely charged oblate ellipsoids of revolution with aspect ratio A = 1/3. In contrast to hard or soft repulsive ellipsoids, which are purely nematic, this system exhibits a smectic-A phase in which charges of equal sign are counterintuitively packed in layers perpendicular to the nematic director

Hydrodynamic interactions in colloidal ferrofluids: A lattice Boltzmann study

We use lattice Boltzmann simulations, in conjunction with Ewald summation methods, to investigate the role of hydrodynamic interactions in colloidal suspensions of dipolar particles, such as ferrofluids. Our work addresses volume fractions $\phi$ of up to 0.20 and dimensionless dipolar interaction parameters $\lambda$ of up to 8. We compare quantitatively with Brownian dynamics simulations, in which many-body hydrodynamic interactions are absent. Monte Carlo data are also used to check the accuracy of static properties measured with the lattice Boltzmann technique. At equilibrium, hydrodynamic interactions slow down both the long-time and the short-time decays of the intermediate scattering function $S(q,t)$, for wavevectors close to the peak of the static structure factor $S(q)$, by a factor of roughly two. The long-time slowing is diminished at high interaction strengths whereas the short-time slowing (quantified via the hydrodynamic factor $H(q)$) is less affected by the dipolar interactions, despite their strong effect on the pair distribution function arising from cluster formation. Cluster formation is also studied in transient data following a quench from $\lambda = 0$; hydrodynamic interactions slow the formation rate, again by a factor of roughly two

Are Land‐Use Change Emissions in Southeast Asia Decreasing or Increasing?

This is the final version. Available on open access from the American Geophysical Union via the DOI in this recordData Availability Statement: TRENDY data for this research are available through Le Quéré, Andrew, Friedlingstein, Sitch, Hauck, et al. (2018), ACTM data are through Saeki and Patra (2017), NICAM-TM data are through Niwa et al. (2012), JMA inversion data are through Maki et al. (2010), H&N data are through Houghton and Nassikas (2017), and BLUE data are through Hansis et al. (2015), respectively.Southeast Asia is a region known for active land-use changes (LUC) over the past 60 years; yet, how trends in net CO2 uptake and release resulting from LUC activities (net LUC flux) have changed through past decades remains uncertain. The level of uncertainty in net LUC flux from process-based models is so high that it cannot be concluded that newer estimates are necessarily more reliable than older ones. Here, we examined net LUC flux estimates of Southeast Asia for the 1980s−2010s from older and newer sets of Dynamic Global Vegetation Model simulations (TRENDY v2 and v7, respectively), and forcing data used for running those simulations, along with two book-keeping estimates (H&N and BLUE). These estimates yielded two contrasting historical LUC transitions, such that TRENDY v2 and H&N showed a transition from increased emissions from the 1980s to 1990s to declining emissions in the 2000s, while TRENDY v7 and BLUE showed the opposite transition. We found that these contrasting transitions originated in the update of LUC forcing data, which reduced the loss of forest area during the 1990s. Further evaluation of remote sensing studies, atmospheric inversions, and the history of forestry and environmental policies in Southeast Asia supported the occurrence of peak emissions in the 1990s and declining thereafter. However, whether LUC emissions continue to decline in Southeast Asia remains uncertain as key processes in recent years, such as conversion of peat forest to oil-palm plantation, are yet to be represented in the forcing data, suggesting a need for further revision

Recovery of release cloud from laser shock-loaded graphite and hydrocarbon targets: in search of diamonds

This work presents first insights into the dynamics of free-surface release clouds from dynamically compressed polystyrene and pyrolytic graphite at pressures up to 200 GPa, where they transform into diamond or lonsdaleite, respectively. These ejecta clouds are released into either vacuum or various types of catcher systems, and are monitored with high-speed recordings (frame rates up to 10 MHz). Molecular dynamics simulations are used to give insights to the rate of diamond preservation throughout the free expansion and the catcher impact process, highlighting the challenges of diamond retrieval. Raman spectroscopy data show graphitic signatures on a catcher plate confirming that the shock-compressed PS is transformed. First electron microscopy analyses of solid catcher plates yield an outstanding number of different spherical-like objects in the size range between ten(s) up to hundreds of nanometres, which are one type of two potential diamond candidates identified. The origin of some objects can unambiguously be assigned, while the history of others remains speculative

Bookkeeping estimates of the net land-use change flux – a sensitivity study with the CMIP6 land-use dataset

The carbon flux due to land-use and land-cover change (net LULCC flux) historically contributed to a large fraction of anthropogenic carbon emissions while at the same time being associated with large uncertainties. This study aims to compare the contribution of several sensitivities underlying the net LULCC flux by assessing their relative importance in a bookkeeping model (Bookkeeping of Land Use Emissions, BLUE) based on a LULCC dataset including uncertainty estimates (the Land-Use Harmonization 2 (LUH2) dataset). The sensitivity experiments build upon the approach of Hurtt et al. (2011) and compare the impacts of LULCC uncertainty (a high, baseline and low land-use estimate), the starting time of the bookkeeping model simulation (850, 1700 and 1850), net area transitions versus gross area transitions (shifting cultivation) and neglecting wood harvest on estimates of the net LULCC flux. Additional factorial experiments isolate the impact of uncertainty from initial conditions and transitions on the net LULCC flux. Finally, historical simulations are extended with future land-use scenarios to assess the impact of past LULCC uncertainty in future projections. Over the period 1850–2014, baseline and low LULCC scenarios produce a comparable cumulative net LULCC flux, while the high LULCC estimate initially produces a larger net LULCC flux which decreases towards the end of the period and even becomes smaller than in the baseline estimate. LULCC uncertainty leads to slightly higher sensitivity in the cumulative net LULCC flux (up to 22 %; references are the baseline simulations) compared to the starting year of a model simulation (up to 15 %). The contribution from neglecting wood harvest activities (up to 28 % cumulative net LULCC flux) is larger than that from LULCC uncertainty, and the implementation of land-cover transitions (gross or net transitions) exhibits the smallest sensitivity (up to 13 %). At the end of the historical LULCC dataset in 2014, the LULCC uncertainty retains some impact on the net LULCC flux (±0.15 PgC yr−1 at an estimate of 1.7 PgC yr−1). Of the past uncertainties in LULCC, a small impact persists in 2099, mainly due to uncertainty of harvest remaining in 2014. However, compared to the uncertainty range of the LULCC flux estimated today, the estimates in 2099 appear to be indistinguishable. These results, albeit from a single model, are important for CMIP6 as they compare the relative importance of starting year, uncertainty of LULCC, applying gross transitions and wood harvest on the net LULCC flux. For the cumulative net LULCC flux over the industrial period, the uncertainty of LULCC is as relevant as applying wood harvest and gross transitions. However, LULCC uncertainty matters less (by about a factor of 3) than the other two factors for the net LULCC flux in 2014, and historical LULCC uncertainty is negligible for estimates of future scenarios