Differentiation of the concentration of heavy metals and persistent organic pollutants in lake sediments depending on the catchment management (Lake Gopło case study)

This paper presents the results of the study on the concentration of heavy metals and persistent organic pollutants (POPs), including PAHs and PCBs, in the bottom sediments of Lake Gopło. This lake is significantly elongated (about 25 km); its longitudinal profile is diversified, and there are deeps and thresholds impeding the flow of water. The shoreline is varied, which is characteristic of tunnel valley lakes. The catchment has a typical agricultural character with a point arrangement of industrial centres. The analysis of the diversity of the concentration of heavy metals and POPs was based on 37 samples from two representative cores: one collected in the northern part of the lake, the catchment of which shows an industrial character, and the second one in the southern part where the catchment is agricultural in character. In the sediments, the content of the following heavy metals was analysed: Cu, Pb, Cd, Zn, Ni, Cr, Hg and As, as well as PAHs and PCBs. The sediment age was determined by the 210Pb dating method. In order to assess the contamination level of the bottom sediments with heavy metals, the contamination factor (CF) and degree of contamination (DC) were calculated. Moreover, the impact of the changes in the catchment’s land use over the past 100 years was determined. The results showed that the sediments from the industrial part of the lake significantly exceed the geochemical background for both the heavy metals from the group identified as industrial pollution and from the group of agricultural pollutants. The southern core shows only a slight increase in the amount of pollution from the agricultural group, lack of industrial pollution and a low degree of contamination. A slight increase in persistent organic pollutants is also recorded, without any apparent effect on the state of the deposited sediment. The 210PB dating enabled the main stages of human impact to be determined: the pre-industrial revolution, from the beginning of industrialisation to the 1950s, intensive human impact from the 1960s to the 1980s, and a gradual decrease in the human impact starting from the 1990s. In addition, attention was paid to the changing sedimentation rate

A chrysophyte-based quantitative reconstruction of winter severity from varved lake sediments in NE Poland during the past millennium and its relationship to natural climate variability

Chrysophyte cysts are recognized as powerful proxies of cold-season temperatures. In this paper we use the relationship between chrysophyte assemblages and the number of days below 4 °C (DB4 °C) in the epilimnion of a lake in northern Poland to develop a transfer function and to reconstruct winter severity in Poland for the last millennium. DB4 °C is a climate variable related to the length of the winter. Multivariate ordination techniques were used to study the distribution of chrysophytes from sediment traps of 37 low-land lakes distributed along a variety of environmental and climatic gradients in northern Poland. Of all the environmental variables measured, stepwise variable selection and individual Redundancy analyses (RDA) identified DB4 °C as the most important variable for chrysophytes, explaining a portion of variance independent of variables related to water chemistry (conductivity, chlorides, K, sulfates), which were also important. A quantitative transfer function was created to estimate DB4 °C from sedimentary assemblages using partial least square regression (PLS). The two-component model (PLS-2) had a coefficient of determination of R2cross=0.58, with root mean squared error of prediction (RMSEP, based on leave-one-out) of 3.41 days. The resulting transfer function was applied to an annually-varved sediment core from Lake Żabińskie, providing a new sub-decadal quantitative reconstruction of DB4 °C with high chronological accuracy for the period AD 1000-2010. During Medieval Times (AD 1180-1440) winters were generally shorter (warmer) except for a decade with very long and severe winters around AD 1260-1270 (following the AD 1258 volcanic eruption). The 16th and 17th centuries and the beginning of the 19th century experienced very long severe winters. Comparison with other European cold-season reconstructions and atmospheric indices for this region indicates that large parts of the winter variability (reconstructed DB4 °C) is due to the interplay between the oscillations of the zonal flow controlled by the North Atlantic Oscillation (NAO) and the influence of continental anticyclonic systems (Siberian High, East Atlantic/Western Russia pattern). Differences with other European records are attributed to geographic climatological differences between Poland and Western Europe (Low Countries, Alps). Striking correspondence between the combined volcanic and solar forcing and the DB4 °C reconstruction prior to the 20th century suggests that winter climate in Poland responds mostly to natural forced variability (volcanic and solar) and the influence of unforced variability is low

Linking the formation of varves in a eutrophic temperate lake to meteorological conditions and water column dynamics.

Despite varved sediments being widely used for paleolimnological studies, little information is available about how climate and meteorological signals are recorded in varves at sub-seasonal to annual scale. We investigate links between meteorological and limnological conditions and their influence on biochemical varve formation and preservation of sub-seasonal climate signals in the sediments. Our study site is postglacial Lake Żabińskie located in NE Poland, in which thick and complex varved sediments have been studied for the last decade. These sediments provide an excellent material for studying the influence of short-term weather conditions on geological records. For this, we use an almost decade-long (2012-2019) series of observational data (meteorological conditions, physicochemical water parameters, and modern sedimentation observations) to understand varve formation processes. Then we compare these results with a high-resolution biogeochemical proxy dataset based on μXRF and hyperspectral imaging (HSI) measurements of a varved sediment core spanning the same period. Here we show direct links between the meteorological and limnological conditions and varve formation processes This is particularly the case for air temperature which governs calcite laminae formation and primary production. We further show that calcite grain size is influenced by lake mixing intensity resulting from the wind activity, and that holomixis events lead to the formation of distinct manganese (Mn) peaks in the typically anoxic sediments. Our findings show that high-resolution non-destructive spectroscopy methods applied to complex biochemical varves, in combination with long observational limnological datasets, provide useful information for tracking meteorological and limnological processes in the past

Chironomid dataset from Mutterbergersee: A late-Holocene paleotemperature proxy record for the Central Eastern Alps, Austria

We present a dataset of subfossil chironomid assemblages in the MUT-10 sediment core obtained from the high alpine lake Mutterbergersee in the Austrian Alps in 2010. The data were presented in the research article by Ilyashuk et al. (2019) "The Little Ice Age signature in a 700-year high-resolution chironomid record of summer temperatures in the Central Eastern Alps". In addition to the results of the chironomid analysis of 100 sediment samples presented in this article, we also include chironomid assemblage data from an additional 48 sediment samples that complement this dataset. The data includes raw chironomid counts, percent abundance of chironomid taxa, as well as mean July air temperature estimates derived from the chironomid record based on a chironomid-temperature transfer function. We also provide information on age-dating of the sedimentary sequence. Given the high temporal resolution and the robust age-depth model of the record, the chironomid-based reconstruction of temperature since AD 1300 provides a detailed documentation of climate change in the Eastern Alps from the Little Ice Age onwards and can be used for comparison with other independent proxy-based climate reconstructions. In addition to the data, we detail the sample processing for subfossil chironomid analysis and provide a detailed description of the reconstruction technique used for producing chironomid-based quantitative temperature inferences

A chrysophyte-based quantitative reconstruction of winter severity from varved lake sediments in NE Poland during the past millennium and its relationship to natural climate variability

Chrysophyte cysts are recognized as powerful proxies of cold-season temperatures. In this paper we use the relationship between chrysophyte assemblages and the number of days below 4 °C (DB4 °C) in the epilimnion of a lake in northern Poland to develop a transfer function and to reconstruct winter severity in Poland for the last millennium. DB4 °C is a climate variable related to the length of the winter. Multivariate ordination techniques were used to study the distribution of chrysophytes from sediment traps of 37 low-land lakes distributed along a variety of environmental and climatic gradients in northern Poland. Of all the environmental variables measured, stepwise variable selection and individual Redundancy analyses (RDA) identified DB4 °C as the most important variable for chrysophytes, explaining a portion of variance independent of variables related to water chemistry (conductivity, chlorides, K, sulfates), which were also important. A quantitative transfer function was created to estimate DB4 °C from sedimentary assemblages using partial least square regression (PLS). The two-component model (PLS-2) had a coefficient of determination of View the MathML sourceRcross2 = 0.58, with root mean squared error of prediction (RMSEP, based on leave-one-out) of 3.41 days. The resulting transfer function was applied to an annually-varved sediment core from Lake Żabińskie, providing a new sub-decadal quantitative reconstruction of DB4 °C with high chronological accuracy for the period AD 1000–2010. During Medieval Times (AD 1180–1440) winters were generally shorter (warmer) except for a decade with very long and severe winters around AD 1260–1270 (following the AD 1258 volcanic eruption). The 16th and 17th centuries and the beginning of the 19th century experienced very long severe winters. Comparison with other European cold-season reconstructions and atmospheric indices for this region indicates that large parts of the winter variability (reconstructed DB4 °C) is due to the interplay between the oscillations of the zonal flow controlled by the North Atlantic Oscillation (NAO) and the influence of continental anticyclonic systems (Siberian High, East Atlantic/Western Russia pattern). Differences with other European records are attributed to geographic climatological differences between Poland and Western Europe (Low Countries, Alps). Striking correspondence between the combined volcanic and solar forcing and the DB4 °C reconstruction prior to the 20th century suggests that winter climate in Poland responds mostly to natural forced variability (volcanic and solar) and the influence of unforced variability is low

Long-Term Consequences of Water Pumping on the Ecosystem Functioning of Lake Sekšu, Latvia

Cultural eutrophication, the process by which pollution due to human activity speeds up natural eutrophication, is a widespread and consequential issue. Here, we present the 85-year history of a small, initially Lobelia–Isoëtes dominated lake. The lake’s ecological deterioration was intensified by water pumping station activities when it received replenishment water for more than 10 years from a eutrophic lake through a pipe. In this study, we performed a paleolimnological assessment to determine how the lake’s ecosystem functioning changed over time. A multi-proxy (pollen, Cladocera, diatoms, and Chironomidae) approach was applied alongside a quantitative reconstruction of total phosphorus using diatom and hypolimnetic dissolved oxygen with chironomid-based transfer functions. The results of the biotic proxy were supplemented with a geochemical analysis. The results demonstrated significant changes in the lake community’s structure, its sediment composition, and its redox conditions due to increased eutrophication, water level fluctuations, and erosion. The additional nutrient load, particularly phosphorus, increased the abundance of planktonic eutrophic–hypereutrophic diatoms, the lake water’s transparency decreased, and hypolimnetic anoxia occurred. Cladocera, Chironomidae, and diatoms species indicated a community shift towards eutrophy, while the low trophy species were suppressed or disappeared

Long-Term Consequences of Water Pumping on the Ecosystem Functioning of Lake Sekšu, Latvia

Cultural eutrophication, the process by which pollution due to human activity speeds up natural eutrophication, is a widespread and consequential issue. Here, we present the 85-year history of a small, initially Lobelia-Isoetes dominated lake. The lake's ecological deterioration was intensified by water pumping station activities when it received replenishment water for more than 10 years from a eutrophic lake through a pipe. In this study, we performed a paleolimnological assessment to determine how the lake's ecosystem functioning changed over time. A multi-proxy (pollen, Cladocera, diatoms, and Chironomidae) approach was applied alongside a quantitative reconstruction of total phosphorus using diatom and hypolimnetic dissolved oxygen with chironomid-based transfer functions. The results of the biotic proxy were supplemented with a geochemical analysis. The results demonstrated significant changes in the lake community's structure, its sediment composition, and its redox conditions due to increased eutrophication, water level fluctuations, and erosion. The additional nutrient load, particularly phosphorus, increased the abundance of planktonic eutrophic-hypereutrophic diatoms, the lake water's transparency decreased, and hypolimnetic anoxia occurred. Cladocera, Chironomidae, and diatoms species indicated a community shift towards eutrophy, while the low trophy species were suppressed or disappeared.Peer reviewe