A use-side trade margins matrix for the Andalusian economy

According to the National Accounting Systems proposed by United Nations (1993) and Eurostat (1996), use and make (or supply) matrices should be measured before goods and services are conveyed to the markets (basic values). Actually, the make table is defined in basic values (excluding trade and transport margins and net commodity taxes) whereas the use table is in purchasers' values (including them). This paper shows how these margins and taxes can be removed from the use table with the purpose of entering both of them in the so-called material balance equation. With respect to trade margins, our approach is based on the use-side procedure from the ESA-95 Input-Output Manual (Eurostat, 2002) and is also being applied to the forthcoming 2000 Andalusian Input-Output Framework.Input-output analysis, use and make matrices, trade margins, National Accounts

Dialogues of pedagogical leaders for the inclusion in processes of increase of professional capacities in their schools: The case of Atlántida Granada

La inclusión educativa es un reto aún lejos de nuestro alcance en un sistema acomodado en la dualización y el individualismo. La mejora educativa de calado sólo puede llegar desde una perspectiva crítica comprometida con el análisis profesional para la eliminación de todo tipo de barreras al éxito para todos y la promoción de una cultura de inclusión. La investigación señala que para garantizar la mejora educativa es necesario incrementar la capacidad de mejora de cada escuela como “comunidad profesional de aprendizaje”. Este trabajo muestra algunas claves emergentes de un estudio en proceso sobre el desarrollo del proyecto de desarrollo de capacidades profesionales docentes de Atlántida-Granada en contextos desafiantes. Utiliza un modelo de investigación dialógica y participativa. Se analiza el desarrollo de sesiones de trabajo entre directivos escolares que preparan, debaten y replantean los procesos de trabajo con su profesorado en sus respectivas escuelas. El estudio presenta limitaciones evidentes: la particularidad de los casos y el estar aún en proceso. Pese a ello, aporta al debate algunas pistas sobre la identidad de estos directivos los retos y las barreras para ejercer su liderazgo pedagógico, así como claves técnicas para desempeñar su labor profesional por la mejora y la inclusiónEducational inclusion is a challenge still far from our reach in a system accommodated in dualization and individualism. The educational improvement of depth can only come from a critical perspective committed to professional analysis for the elimination of all types of barriers to success for all and the promotion of a culture of inclusion. The research points out that in order to guarantee educational improvement it is necessary to increase the capacity for improvement of each school as a "professional learning community". This work shows some emerging keys of a study in process on the development of the project of development of professional teaching capacities of Atlántida-Granada in challenging contexts. It uses a dialogical and participative research model. It is analyzed the development of work sessions between school managers who prepare, discuss and rethink the work processes with their teachers in their respective schools. The study has obvious limitations: the particularity of the cases and the fact that they are still in the process. Despite this, it brings to the debate some clues about the identity of these managers, the challenges and barriers to exercise their pedagogical leadership, as well as technical keys to perform their professional work for improvement and inclusionEste estudio es parte del proyecto de investigación “Identidad de la dirección escolar: liderazgo, formación y profesionalización (Ref. EDU2016-78191-P), con la colaboración de la red RILME y del Proyecto Atlántid

Vertical Resolved Dust Mass Concentration and Backscatter Coefficient Retrieval of Asian Dust Plume Using Quartz Raman Channel in Lidar Measurements

In this work, we present a method for estimating vertical resolved mass concentration of dust immersed in Asian dust plume using Raman scattering of quartz (silicon dioxide, silica). During the Asian dust period of March 15, 16, and 21 in 2010, Raman lidar measurements detected the presence of quartz, and successfully showed the vertical profiles of the quartz backscatter coefficient. Since the Raman backscatter coefficient was connected with the Raman backscatter differential cross section and the number density of quartz molecules, the mass concentration of quartz in the atmosphere can be estimated from the quartz backscatter coefficient. The weight percentage from 40 to 70 % for quartz in the Asian dust was estimated from references. The vertical resolved mass concentration of dust was estimated by quartz mass concentration and weight percentage. We also present a retrieval method to obtain dust backscatter coefficient from the mixed Asian dust and pollutant layer. OPAC (Optical Properties of Aerosol and Clouds) simulations were conducted to calculate dust backscatter coefficient. The retrieved dust mass concentration was used as an input parameter for the OPAC calculations. These approaches in the study will be useful for characterizing the quartz dominated in the atmospheric aerosols and estimating vertical resolved mass concentration of dust. It will be especially applicable for optically distinguishing the dust and non-dust aerosols in studies on the mixing state of Asian dust plume. Additionally, the presented method combined with satellite observations is enable qualitative and quantitative monitoring for Asian dust

Competencias básicas

Recensión de:Bolívar, A. (coord.)(2010). Competencias básicas. Barcelona: Wolter Kluwer. ISBN: 978-84-692-5994-7

Power-law scaling behaviour of impedance signal time series of healthy subjects at rest

International audienc

Identification of fine (PM1) and coarse (PM10-1) sources of particulate matter in an urban environment

PM10 and PM1 samples were collected at an urban site in southeastern Spain during 2006-2010. The chemical composition of all samples has been determined and analyzed by Positive Matrix Factorization (PMF) technique for fine and coarse source identification. The PMF results have been analyzed for working and non-working days in order to evaluate the change in PM sources contribution and possible future abatement strategies. A decreasing trend in PM10 levels and in its constituents has been observed, being partly associated to a reduction in anthropogenic activities due to the economic crisis. The use of fine and coarse PM in the PMF analysis allowed us for the identification of additional sources that could not be identified using only one size fraction. The mineral dust source was identified in both fractions and comprised 36 and 22% of the total mass in the coarse and fine fractions, respectively. This high contribution of the mineral source to the fine fraction may be ascribed to contamination of the source profile. The regional re-circulation source was traced by secondary sulfate, V and Ni. It was the most important source concerning PM1 mass concentration (41% of the total mass in this fraction). Although V and Ni are commonly associated to fuel oil combustion the seasonality of this source with higher concentrations in summer compared with winter suggest that the most important part of this source can be ascribed to regional pollution episodes. A traffic exhaust source was identified but only in the fine fraction, comprising 29% of the fine mass. The celestite mines source associated with nearby open-pit mines was typified by strontium, sulfate and mineral matter. PM10-1 levels were higher in working days, whereas PM1 levels remained fairly constant throughout the whole week. As a conclusion, traffic seems to be the main source to target in Granada.This work was supported by the Andalusia Regional Government through projects P12-RNM-2409 and P10-RNM-6299, by the Spanish Ministry of Science and Technology through projects CGL2010-18782, CSD2007-00067, CGL2011-13580-E/CLI and CGL2011-15008-E; and by EU through ACTRIS project (EU INFRA-2010-1.1.16-262254)Titos was funded by Spanish Ministry of Economy and Competitiveness – Secretariat of Science, Innovation and Development under grant BES-2011-043721

Spatiotemporal changes in aerosol properties by hygroscopic growth and impacts on radiative forcing and heating rates during DISCOVER-AQ 2011

This research has been supported by the H2020 Marie Sklodowska-Curie Actions (grant no. 778349), the Spanish Ministry of Economy and Competitiveness (RTI2018101154.A.I00), and by the Russian Science Foundation (project 2117-00114, entitled Development of lidar retrieval algorithms).This work focuses on the characterization of vertically resolved aerosol hygroscopicity properties and their direct radiative effects through a unique combination of ground-based and airborne remote sensing measurements during the Column and Vertically Resolved Observations Relevant to Air Quality (DISCOVER-AQ) 2011 field campaign in the Baltimore-Washington DC metropolitan area. To that end, we combined aerosol measurements from a multiwavelength Raman lidar located at NASA Goddard Space Flight Center and the airborne NASA Langley High Spectral Resolution Lidar-1 (HSRL-1) lidar system. In situ measurements aboard the P-3B airplane and ground-based Aerosol Robotic Network - Distributed Regional Aerosol Gridded Observational Network (AERONET-DRAGON) served to validate and complement quantifications of aerosol hygroscopicity from lidar measurements and also to extend the study both temporally and spatially. The focus here is on 22 and 29 July 2011, which were very humid days and characterized by a stable atmosphere and increasing relative humidity with height in the planetary boundary layer (PBL). Combined lidar and radiosonde (temperature and water vapor mixing ratio) measurements allowed the retrieval of the Hanel hygroscopic growth factor which agreed with that obtained from airborne in situ measurements and also explained the significant increase of extinction and backscattering with height. Airborne measurements also confirmed aerosol hygroscopicity throughout the entire day in the PBL and identified sulfates and water-soluble organic carbon as the main species of aerosol particles. The combined Raman and HSRL-1 measurements permitted the inversion for aerosol microphysical properties revealing an increase of particle radius with altitude consistent with hygroscopic growth. Aerosol hygroscopicity pattern served as a possible explanation of aerosol optical depth increases during the day, particularly for fine-mode particles. Lidar measurements were used as input to the libRadtran radiative transfer code to obtain vertically resolved aerosol radiative effects and heating rates under dry and humid conditions, and the results reveal that aerosol hygroscopicity is responsible for larger cooling effects in the shortwave range (7-10 W m(-2) depending on aerosol load) near the ground, while heating rates produced a warming of 0.12 K d(-1) near the top of PBL where aerosol hygroscopic growth was highest.H2020 Marie Sklodowska-Curie Actions 778349Spanish Ministry of Economy and Competitiveness RTI2018101154.A.I00Russian Science Foundation (RSF) 2117-0011

Hardware transactional memory with software-defined conflicts

In this paper we propose conflict-defined blocks, a programming language construct that allows programmers to change the concept of conflict from one transaction to another, or even throughout the course of the same transaction. Defining conflicts in software makes possible the removal of dependencies which, though not necessary for the correct execution of the transactions, arise as a result of the coarse synchronization style encouraged by TM. Programmers take advantage of their knowledge about the problem and specify through confict-defined blocks what types of dependencies are superfluous in a certain part of the transaction, in order to extract more performance out of coarse-grained transactions without having to write minimally synchronized code. Our experiments with several transactional benchmarks reveal that using software-defined conflicts, the programmer achieves significant reductions in the number of aborted transactions and improve scalability.Peer ReviewedPostprint (author's final draft

Amending the anisotropy barrier and luminescence behavior of heterometallic trinuclear linear M-II-Ln(III)-M-II (Ln(III)=Gd, Tb, Dy; M-II=Mg/Zn) complexes by change from divalent paramagnetic to diamagnetic metal ions

The sequential reaction of a multisite coordinating compartmental ligand LH4 [2-(2-hydroxy-3-(hydroxymethyl)-5-methylbenzylideneamino)-2-methylpropane-1,3-diol] with appropriate lanthanide salts followed by the addition of Mg(NO3)2·6H2O or Zn(NO3)2·6H2O in a 4:1:2 stoichiometric ratio in the presence of triethylamine affords a series of isostructural heterometallic trinuclear complexes containing [Mg2Ln]3+ [Ln = Dy (1), Gd (2) and Tb (3)] and [Zn2Ln]3+ [Ln = Dy (4), Gd (5) and Tb (6)] cores. The formation of 1-6 is demonstrated by X-ray crystallography as well as ESI-MS spectra. All complexes are isostructural possessing a linear trimetallic core with a central lanthanide ion. In this article we have discussed the comprehensive studies, involving synthesis, structure, magnetism and photophysical properties on this family of trinuclear [Mg2Ln]3+ and [Zn2Ln]3+ heterometallic complexes. Complexes 1 and 4 show slow relaxation of the magnetization below 12 K under zero applied direct-current field, but without reaching a neat maximum which is due to the overlapping with a faster quantum tunnelling relaxation mediated through dipole-dipole and hyperfine interactions. Under a small applied direct-current field of 1000 Oe the quantum tunneling was almost suppressed and temperature and frequency dependent peaks were observed, thus confirming the SMM behavior of complexes 1 and 4. The fit of the high-temperature relaxation times to the Arrhenius equation affords an effective energy barrier for the reversal of the magnetization of Ueff =72(2) K with o = 8 x 10-9 s for the SR process and Ueff = 61(2) K with o = 4 x 10-7 s for the FR process for 1 whereas for 4, an effective energy barrier for the reversal of the magnetization Ueff = 67(3) K with o = 4.5 x 10-8 s. To rule out the involvement of intermolecular collaborative interactions in the dynamic of relaxation, we have performed ac susceptibility measurements on 1:10 Dy:Y magnetic diluted samples of of 1 and 4, named as 1' and 4'. Interestingly, the diluted compounds 1' and 4' exhibits SMM behavior under zero magnetic field, thus suggesting that their relaxation processes are single molecular in origin and arise from the M-Dy-M unit. Ab initio CASSCF+RASSI calculations carried out on 1 and 4 confirm that the magnetic anisotropy is axial along the M-Dy-M axis and that the relaxation process occurs through the first excited energy level. Furthermore, the chromophoric [LH3]2- ligand is able to act as an 'antenna' group which was found to be effective in the selective sensitization of the emissions of TbIII-based complexes 3 and 6. The emission quantum yields and the luminescence lifetimes at room temperature are 11.7 % and 0.606 ms for 3, 22.7 % and 0.799 ms for 6

Quantifying traffic, biomass burning and secondary source contributions to atmospheric particle number concentrations at urban and suburban sites

In this study, we propose a new approach to determine the contributions of primary vehicle exhaust (N-1(ff)), primary biomass burning (N-1(bb)) and secondary (N-2) particles to mode segregated particle number concentrations. We used simultaneous measurements of aerosol size distribution in the 12-600 nm size range and black carbon (BC) concentration obtained during winter period at urban and suburban sites influenced by biomass burning (BB) emissions. As expected, larger aerosol number concentrations in the 12-25 and 25-100 nm size ranges are observed at the urban site compared to the suburban site. However, similar concentrations of BC are observed at both sites due to the larger contribution of BB particles to the observed BC at suburban (34%) in comparison to urban site (23%). Due to this influence of BB emissions in our study area, the application of the Rodriguez and Cuevas (2007) method, which was developed for areas mainly influenced by traffic emissions, leads to an overestimation of the primary vehicle exhaust particles concentrations by 18% and 26% in urban and suburban sites, respectively, as compared to our new proposed approach. The results show that (1) N-2 is the main contributor in all size ranges at both sites, (2) N-1(ff) is the main contributor to primary particles (>70%) in all size ranges at both sites and (3) N-1(bb) contributes significantly to the primary particles in the 25-100 and 100-600 nm size ranges at the suburban (24% and 28%, respectively) and urban (13% and 20%, respectively) sites. At urban site, the N-1(ff) contribution shows a slight increase with the increase of total particle concentration, reaching a contribution of up to 65% at high ambient aerosol concentrations. New particle loination events are an important aerosol source during summer noon hours but, on average, these events do not implicate a considerable contribution to urban particles. (C) 2021 Elsevier B.V. All rights reserved.Peer reviewe