Kinetics of Polymerization of Isobutyl Vinyl Ether Catalysed by Anhydrous Zinc Chloride

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Evidence of microscopic effects in fragment mass distribution in heavy ion induced fusion-fission reactions

Our measurements of variances ($\sigma_{m}^2$) in mass distributions of fission fragments from fusion-fission reactions of light projectiles (C, O and F) on deformed thorium targets exhibit a sharp anomalous increase with energy near the Coulomb barrier, in contrast to the smooth variation of $\sigma_{m}^2$ for the spherical bismuth target. This departure from expectation based on a statistical description is explained in terms of microscopic effects arising from the orientational dependence in the case of deformed thorium targets.Comment: Replaced with revised version, to appear in Phys. Lett.

Observation of multiple doubly degenerate bands in ¹⁹⁵Tl

The High-spin states in 195 Tl, populated through the 185,187 Re( 13 C, xn) fusion evaporation reaction at the beam energy of 75 MeV, were studied using the Indian National Gamma Array (INGA). More than 50 new γ transitions have been placed in the proposed level scheme which is extended up to the excitation energy of ≈ 5.6 MeV and spin =22.5ħ . Two pairs of degenerate bands based on two different quasi-particle configurations have been identified in this nucleus indicating the first observation of such bands in an odd- A nucleus in A∼190 region and signify the first evidence of multiple chiral bands in a nucleus in this region. The total Routhian surface calculations predict triaxial shapes for both the configurations and thereby, support the experimental observation. The importance of multiple neutron holes in the i13/2 orbital and the stability of shapes for these two configurations have been discussed.Financial support of Department of Science & Technology, Govt. of India for clover detectors of INGA (Grant No. IR/S2/PF-03/2003-II) is greatfully acknowledged. One of the authors (S. Bhattacharya) acknowledges with thanks the financial support received as Raja Ramanna Fellowship from the Department of Atomic Energy, Govt. of India. T.R and Md. A.A acknowledge with thanks the financial support received as research fellows from the Department of Atomic Energy (DAE), Govt. of India

LAMBDA: Large Area Modular BaF2 Detector Array for the measurement of high energy gamma rays

A large BaF2 detector array along with its dedicated CAMAC electronics and VME based data acquisition system has been designed, constructed and installed successfully at VECC, Kolkata for studying high energy gamma rays (E>8 MeV). The array consists of 162 detector elements. The detectors were fabricated from bare barium fluoride crystals (each measuring 35 cm in length and having cross-sectional area of 3.5 cm X 3.5 cm X 35.0 cm). The basic properties of the detectors (energy resolution, time resolution, efficiency, uniformity, fast to slow ratio etc.) were studied exhaustively. Complete GEANT3 monte carlo simulations were performed to optimize the detector design and also to generate the response function. The detector system has been used successfully to measure high energy photons from 113Sb, formed by bombarding 145 and 160 MeV 20Ne beams on a 93Nb target. The measured experimental spectra are in good agreement with those from a modified version of the statistical model code CASCADE. In this paper, we present the complete description of this detector array along with its in-beam performance.Comment: 18 pages, 14 figures, accepted in NIM

Topological Defects in the Random-Field XY Model and the Pinned Vortex Lattice to Vortex Glass Transition in Type-II Superconductors

As a simplified model of randomly pinned vortex lattices or charge-density waves, we study the random-field XY model on square ($d=2$) and simple cubic ($d=3$) lattices. We verify in Monte Carlo simulations, that the average spacing between topological defects (vortices) diverges more strongly than the Imry-Ma pinning length as the random field strength, $H$, is reduced. We suggest that for $d=3$ the simulation data are consistent with a topological phase transition at a nonzero critical field, $H_c$, to a pinned phase that is defect-free at large length-scales. We also discuss the connection between the possible existence of this phase transition in the random-field XY model and the magnetic field driven transition from pinned vortex lattice to vortex glass in weakly disordered type-II superconductors.Comment: LATEX file; 5 Postscript figures are available from [email protected]

Aspects of Two-Photon Physics at Linear e+e- Colliders

We discuss various reactions at future e+e- and gamma-gamma colliders involving real (beamstrahlung or backscattered laser) or quasi--real (bremsstrahlung) photons in the initial state and hadrons in the final state. The production of two central jets with large pT is described in some detail; we give distributions for the rapidity and pT of the jets as well as the di--jet invariant mass, and discuss the relative importance of various initial state configurations and the uncertainties in our predictions. We also present results for `mono--jet' production where one jet goes down a beam pipe, for the production of charm, bottom and top quarks, and for single production of W and Z bosons. Where appropriate, the two--photon processes are compared with annihilation reactions leading to similar final states. We also argue that the behaviour of the total inelastic gamma-gamma cross section at high energies will probably have little impact on the severity of background problems caused by soft and semi--hard (`minijet') two--photon reactions. We find very large differences in cross sections for all two--photon processes between existing designs for future e+e- colliders, due to the different beamstrahlung spectra; in particular, both designs with >1 events per bunch crossing exist.Comment: 51 pages, 13 figures(not included

Modelling soil water balance and root water uptake in cotton grown under different soil conservation practices in the Indo-Gangetic Plain

Although soil conservation practices are being promoted as better environmental protection technologies than traditional farmers’ practice, limited information is available on how these practices affect soil water balance and root water uptake. The root water uptake (RWU) patterns of cotton grown under soil conservation practices and soil water balance in cotton (Gossypium hirsutum L.) fieldsunder a cotton-wheat (Triticum aestivum L.) cropping system were analyzed using the Hydrus-2D model. The treatments were: conventional tillage (CT), zero tillage (ZT), permanent narrow beds (PNB), permanent broad beds (PBB), ZT with residue (ZT+R), PNB with residue (PNB+R) and PBB with residue (PBB+R). Results in the third year of the cotton crop indicated that the surface (0–15cm layer) field saturated hydraulic conductivity in both PNB and PBB plots were similar and were significantly higher than in the ZT plots. Computed potential transpiration rates (Trp) under CT were lower than in other treatments, due to less radiation interception and lower Leaf Area Index (LAI). Both PNB and PBB plots had higher Trp and crop yields than CT plots, which were further improved by residue retention. Predicted soil water content (SWC) patterns during the simulation periods of third and fourth years showed strong correlation (R2=0.88, n=105, P<0.001, the root mean square error (RMSE)=0.025, and the average relative error (AVE)=7.5% for the third year and R2=0.81, n=105, P<0.001, RMSE=0.021, and AVE=9% for the fourth year) with the actual field measured SWCs. Cumulative RWU (mm) were in the order: ZT (143

Developing a core outcome set for future infertility research : An international consensus development study

STUDY QUESTION: Can a core outcome set to standardize outcome selection, collection and reporting across future infertility research be developed? SUMMARY ANSWER: A minimum data set, known as a core outcome set, has been developed for randomized controlled trials (RCTs) and systematic reviews evaluating potential treatments for infertility. WHAT IS KNOWN ALREADY: Complex issues, including a failure to consider the perspectives of people with fertility problems when selecting outcomes, variations in outcome definitions and the selective reporting of outcomes on the basis of statistical analysis, make the results of infertility research difficult to interpret. STUDY DESIGN, SIZE, DURATION: A three-round Delphi survey (372 participants from 41 countries) and consensus development workshop (30 participants from 27 countries). PARTICIPANTS/MATERIALS, SETTING, METHODS: Healthcare professionals, researchers and people with fertility problems were brought together in an open and transparent process using formal consensus science methods. MAIN RESULTS AND THE ROLE OF CHANCE: The core outcome set consists of: viable intrauterine pregnancy confirmed by ultrasound (accounting for singleton, twin and higher multiple pregnancy); pregnancy loss (accounting for ectopic pregnancy, miscarriage, stillbirth and termination of pregnancy); live birth; gestational age at delivery; birthweight; neonatal mortality; and major congenital anomaly. Time to pregnancy leading to live birth should be reported when applicable. LIMITATIONS, REASONS FOR CAUTION: We used consensus development methods which have inherent limitations, including the representativeness of the participant sample, Delphi survey attrition and an arbitrary consensus threshold. WIDER IMPLICATIONS OF THE FINDINGS: Embedding the core outcome set within RCTs and systematic reviews should ensure the comprehensive selection, collection and reporting of core outcomes. Research funding bodies, the Standard Protocol Items: Recommendations for Interventional Trials (SPIRIT) statement, and over 80 specialty journals, including the Cochrane Gynaecology and Fertility Group, Fertility and Sterility and Human Reproduction, have committed to implementing this core outcome set. STUDY FUNDING/COMPETING INTEREST(S): This research was funded by the Catalyst Fund, Royal Society of New Zealand, Auckland Medical Research Fund and Maurice and Phyllis Paykel Trust. The funder had no role in the design and conduct of the study, the collection, management, analysis or interpretation of data, or manuscript preparation. B.W.J.M. is supported by a National Health and Medical Research Council Practitioner Fellowship (GNT1082548). S.B. was supported by University of Auckland Foundation Seelye Travelling Fellowship. S.B. reports being the Editor-in-Chief of Human Reproduction Open and an editor of the Cochrane Gynaecology and Fertility group. J.L.H.E. reports being the Editor Emeritus of Human Reproduction. J.M.L.K. reports research sponsorship from Ferring and Theramex. R.S.L. reports consultancy fees from Abbvie, Bayer, Ferring, Fractyl, Insud Pharma and Kindex and research sponsorship from Guerbet and Hass Avocado Board. B.W.J.M. reports consultancy fees from Guerbet, iGenomix, Merck, Merck KGaA and ObsEva. C.N. reports being the Co Editor-in-Chief of Fertility and Sterility and Section Editor of the Journal of Urology, research sponsorship from Ferring, and retains a financial interest in NexHand. A.S. reports consultancy fees from Guerbet. E.H.Y.N. reports research sponsorship from Merck. N.L.V. reports consultancy and conference fees from Ferring, Merck and Merck Sharp and Dohme. The remaining authors declare no competing interests in relation to the work presented. All authors have completed the disclosure form