213 research outputs found
POWTEX Neutron Diffractometer at FRM II - new perspectives for in-situ rock deformation analysis
EGU2012-13521
In Geoscience quantitative texture analysis here defined as the quantitative analysis of the crystallographic preferred orientation (CPO), is a common tool for the investigation of fabric development in mono- and polyphase rocks, their deformation histories and kinematics. Bulk texture measurements also allow the quantitative characterisation of the anisotropic physical properties of rock materials. A routine tool to measure bulk sample volumes is neutron texture diffraction, as neutrons have large penetration capabilities of several cm in geological sample materials.
The new POWTEX (POWder and TEXture) Diffractometer at the neutron research reactor FRM II in Garching, Germany is designed as a high-intensity diffractometer by groups from the RWTH Aachen, Forschungszentrum Jülich and the University of Göttingen. Complementary to existing neutron diffractometers (SKAT at Dubna, Russia; GEM at ISIS, UK; HIPPO at Los Alamos, USA; D20 at ILL, France; and the local STRESS-SPEC and SPODI at FRM II) the layout of POWTEX is focused on fast time-resolved experiments and the measurement of larger sample series as necessary for the study of large scale geological structures. POWTEX is a dedicated beam line for geoscientific research.
Effective texture measurements without sample tilting and rotation are possible firstly by utilizing a range of neutron wavelengths simultaneously (Time-of-Flight technique) and secondly by the high detector coverage (9.8 sr) and a high flux (�~1x10 7 n/cm2s) at the sample. Furthermore the instrument and the angular detector resolution is designed also for strong recrystallisation textures as well as for weak textures of polyphase rocks. These instrument characteristics allow in-situ time-resolved texture measurements during deformation experiments on rocksalt, ice and other materials as large sample environments will be implemented at POWTEX.
The in-situ deformation apparatus is operated by a uniaxial spindle drive with a maximum axial load of 250 kN, which will be redesigned to minimize shadowing effects inside the cylindrical detector. The HT deformatione experiments will be carried out in uniaxial compression or extension and an upgrade to triaxial deformation conditions is envisaged. The load frame can alternatively be used for ice deformation by inserting a cryostat cell for temperatures down to 77 K with a triaxial apparatus allowing also simple shear experiments on ice. Strain rates range between 10-8 and 10-3 s-1 reaching to at least 50% axial strain. The deformation apparatus is designed for continuous long-term deformation experiments and can be exchanged between in-situ and ex-situ placements during continuous operation inside and outside the neutron detector
Formation of porous gas hydrates from ice powders: Diffraction experiments and multistage model
Gas hydrates grown at gas-ice interfaces were examined by electron microscopy and found to have a submicron porous structure. In situ observations of the formation of porous CH4- and CO2-gas hydrates from deuterated ice Ih powders were made, using time-resolved neutron diffraction on the high-flux diffractometer D20 (ILL, Grenoble) at different pressures and temperatures. For the first time neutron diffraction experiments were also performed with methane in hydrogenated samples. The isotopic differences between H2O and D2O are found insignificant concerning the clathrate formation kinetics. At similar excess fugacities, the reaction of CO2 was distinctly faster than that of CH4. The transient formation of the CO2-hydrate crystal structure II was also observed in coexistence with the usual type-I hydrate reaching a maximum of 5% after 5 h of the reaction at 272 K. A phenomenological model for the kinetics of the gas hydrate formation from ice powders is developed with special account of sample consolidation effects. It describes the initial stage (I) of hydrate film spreading over the ice surface and the two subsequent stages which are limited (II) by the clathration reaction at the ice-hydrate interface and (III) by the gas and water transport (diffusion) through the hydrate shells surrounding the shrinking ice cores. Comparable activation energies are found for stage II of the CH4-hydrate formation in deuterated and hydrogenated ice with 8.1 and 9.5 kcal/mol, respectively. In the case of a diffusion-limited clathration (stage III) the activation energy in D2O-ice powders can be estimated as 14.3 kcal/mol
Kinetics of CO2 hydrate formation from water frost at low temperatures: Experimental results and theoretical model
The gas hydrate growth from frostlike powders composed of micrometer-sized ice particles does not start with hydrate shell formation, because the initial hydrate film thickness established in earlier work exceeds the ice particle dimensions. In this limiting case, the ice grains are directly consumed by a growing nucleus created on the particle surface. The conventional Johnson-Mehl-Avrami-Kolmogorov (JMAK) model,(1)which considers (re-) crystallization reactions phenomenologically in terms of the constituent nucleation and subsequent growth processes, cannot be directly applied to the hydrate formation from frost due to the assumption of an infinitely large domain of crystallization. We present here a modified approach to account for the small particle sizes of the starting material and extend the existing theory of gas hydrate formation from monodisperse ice powders(3-5)to the low-temperature and low-ice-particle-size limit. This approach may also prove to be very useful for applying chemical reactions starting on the surface of nanomaterials. In situ neutron scattering was used to obtain the experimental degree of transformation as a function of temperature between 185 and 195 K. The data were analyzed with the modified JMAK model constrained by information from cryo-SEM and BET measurements. Based on the obtained activation energies for hydrate nucleation and growth, an estimate is given for the probability of formation of CO2 hydrates at conditions relevant for Mars; a direct reaction of CO2 gas with water frost is considered to be very unlikely on the Martian surface under current conditions. © 2011 American Chemical Society
An Experimental and Theoretical Study of the Variation of 4f Hybridization Across the La1-xCexIn3 Series
Crystal structures of a series of La1-xCexIn3 (x = 0.02, 0.2, 0.5, or 0.8)
intermetallic compounds have been investigated by both neutron and X-ray
diffraction, and their physical properties have been characterized by magnetic
susceptibility and specific heat measurements. Our results emphasize atypical
atomic displacement parameters (ADP) for the In and the rare-earth sites.
Depending on the x value, the In ADP presents either an "ellipsoidal"
elongation (La-rich compounds) or a "butterfly-like" distortion (Ce-rich
compounds). These deformations have been understood by theoretical techniques
based on the band theory and are the result of hybridization between conduction
electrons and 4f-electrons.Comment: 7 pages, 8 figure
Ice XII in its second regime of metastability
We present neutron powder diffraction results which give unambiguous evidence
for the formation of the recently identified new crystalline ice phase[Lobban
et al.,Nature, 391, 268, (1998)], labeled ice XII, at completely different
conditions. Ice XII is produced here by compressing hexagonal ice I_h at T =
77, 100, 140 and 160 K up to 1.8 GPa. It can be maintained at ambient pressure
in the temperature range 1.5 < T < 135 K. High resolution diffraction is
carried out at T = 1.5 K and ambient pressure on ice XII and accurate
structural properties are obtained from Rietveld refinement. At T = 140 and 160
K additionally ice III/IX is formed. The increasing amount of ice III/IX with
increasing temperature gives an upper limit of T ~ 150 K for the successful
formation of ice XII with the presented procedure.Comment: 3 Pages of RevTeX, 3 tables, 3 figures (submitted to Physical Review
Letters
Acute escitalopram treatment inhibits REM sleep rebound and activation of MCH-expressing neurons in the lateral hypothalamus after long term selective REM sleep deprivation.
RATIONALE: Selective rapid eye movement sleep (REMS) deprivation using the platform-on-water ("flower pot") method causes sleep rebound with increased REMS, decreased REMS latency, and activation of the melanin-concentrating hormone (MCH) expressing neurons in the hypothalamus. MCH is implicated in the pathomechanism of depression regarding its influence on mood, feeding behavior, and REMS. OBJECTIVES: We investigated the effects of the most selective serotonin reuptake inhibitor escitalopram on sleep rebound following REMS deprivation and, in parallel, on the activation of MCH-containing neurons. METHODS: Escitalopram or vehicle (10 mg/kg, intraperitoneally) was administered to REMS-deprived (72 h) or home cage male Wistar rats. During the 3-h-long "rebound sleep", electroencephalography was recorded, followed by an MCH/Fos double immunohistochemistry. RESULTS: During REMS rebound, the time spent in REMS and the number of MCH/Fos double-labeled neurons in the lateral hypothalamus increased markedly, and REMS latency showed a significant decrease. All these effects of REMS deprivation were significantly attenuated by escitalopram treatment. Besides the REMS-suppressing effects, escitalopram caused an increase in amount of and decrease in latency of slow wave sleep during the rebound. CONCLUSIONS: These results show that despite the high REMS pressure caused by REMS deprivation procedure, escitalopram has the ability to suppress REMS rebound, as well as to diminish the activation of MCH-containing neurons, in parallel. Escitalopram caused a shift from REMS to slow wave sleep during the rebound. Furthermore, these data point to the potential connection between the serotonergic system and MCH in sleep regulation, which can be relevant in depression and in other mood disorders
Human Papillomavirus Antibodies And Future Risk Of Anogenital Cancer: A Nested Case-control Study In The European Prospective Investigation Into Cancer And Nutrition Study
Purpose: Human papillomavirus (HPV) type 16 (HPV16) causes cancer at several anatomic sites. In the European Prospective Investigation Into Cancer and Nutrition study, HPV16 E6 seropositivity was present more than 10 years before oropharyngeal cancer diagnosis and was nearly absent in controls. The current study sought to evaluate the extent to which HPV16 E6 antibodies are present before diagnosis of anogenital cancers within the same cohort. Methods: Four hundred incident anogenital cancers (273 cervical, 24 anal, 67 vulvar, 12 vaginal, and 24 penile cancers) with prediagnostic blood samples (collected on average 3 and 8 years before diagnosis for cervix and noncervix cancers, respectively) and 718 matched controls were included. Plasma was analyzed for antibodies against HPV16 E6 and multiple other HPV proteins and genotypes and evaluated in relation to risk using unconditional logistic regression. Results: HPV16 E6 seropositivity was present in 29.2% of individuals (seven of 24 individuals) who later developed anal cancer compared with 0.6% of controls (four of 718 controls) who remained cancer free (odds ratio [OR], 75.9; 95% CI, 17.9 to 321). HPV16 E6 seropositivity was less common for cancers of the cervix (3.3%), vagina (8.3%), vulva (1.5%), and penis (8.3%). No associations were seen for non-type 16 HPV E6 antibodies, apart from anti-HPV58 E6 and anal cancer (OR, 6.8; 95% CI, 1.4 to 33.1). HPV16 E6 seropositivity tended to increase in blood samples drawn closer in time to cancer diagnosis. Conclusion: HPV16 E6 seropositivity is relatively common before diagnosis of anal cancer but rare for other HPV-related anogenital cancers
Recommended reading list of early publications on atomic layer deposition-Outcome of the "Virtual Project on the History of ALD"
Atomic layer deposition (ALD), a gas-phase thin film deposition technique based on repeated, self-terminating gas-solid reactions, has become the method of choice in semiconductor manufacturing and many other technological areas for depositing thin conformal inorganic material layers for various applications. ALD has been discovered and developed independently, at least twice, under different names: atomic layer epitaxy (ALE) and molecular layering. ALE, dating back to 1974 in Finland, has been commonly known as the origin of ALD, while work done since the 1960s in the Soviet Union under the name "molecular layering" (and sometimes other names) has remained much less known. The virtual project on the history of ALD (VPHA) is a volunteer-based effort with open participation, set up to make the early days of ALD more transparent. In VPHA, started in July 2013, the target is to list, read and comment on all early ALD academic and patent literature up to 1986. VPHA has resulted in two essays and several presentations at international conferences. This paper, based on a poster presentation at the 16th International Conference on Atomic Layer Deposition in Dublin, Ireland, 2016, presents a recommended reading list of early ALD publications, created collectively by the VPHA participants through voting. The list contains 22 publications from Finland, Japan, Soviet Union, United Kingdom, and United States. Up to now, a balanced overview regarding the early history of ALD has been missing; the current list is an attempt to remedy this deficiency. (C) 2016 Author(s).Peer reviewe
Ice structures, patterns, and processes: A view across the ice-fields
We look ahead from the frontiers of research on ice dynamics in its broadest
sense; on the structures of ice, the patterns or morphologies it may assume,
and the physical and chemical processes in which it is involved. We highlight
open questions in the various fields of ice research in nature; ranging from
terrestrial and oceanic ice on Earth, to ice in the atmosphere, to ice on other
solar system bodies and in interstellar space
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