Variability of the nighttime OH layer and mesospheric ozone at high latitudes during northern winter: influence of meteorology

Abstract. Analyses of OH zonal means, recorded at boreal high latitudes by the Aura Microwave Limb Sounder (MLS) in winters of 2005–2009, have shown medium- (weeks) and short- (days) term variability of the nighttime OH layer. Because of the exceptional descent of air from the mesosphere-lower thermosphere (MLT) region, medium-term variability occurred during February 2006 and February/March 2009. The layer normally situated at about 82 km descended by about 5–7 km, and its density increased to more than twice January values. In these periods and location the abundance of the lowered OH layer is comparable to the OH values induced by Solar Energetic Particle (SEP) forcing (e.g., SEP events of January 2005) at the same altitudes. In both years, the descent of the OH layer was coupled with increased mesospheric temperatures, elevated carbon monoxide and an almost complete disappearance of ozone at the altitude of the descended layer (which was not observed in other years). Moreover, under these exceptional atmospheric conditions, the third ozone peak, normally at about 72 km, is shown to descend about 5 km to lower altitude and increase in magnitude, with maximum values recorded during February 2009. Short-term variability occurred during Sudden Stratospheric Warming (SSW) events, in particular in January 2006, February 2008 and January 2009, when dynamics led to a smaller abundance of the OH layer at its typical altitude. During these periods, there was an upward displacement of the OH layer coupled to changes in ozone and carbon monoxide. These perturbations were the strongest during the SSW of January 2009; coincident upper mesospheric temperatures were the lowest recorded over the late winters of 2005–2009. Finally, the series of SSW events that occurred in late January/February 2008 induced noticeable short-term variability in ozone at altitudes of both the ozone minimum and the third ozone peak. These phenomena, confined inside the polar vortex, are an additional tool that can be used to investigate mesospheric vortex dynamics

Ground-based stratospheric O3 and HNO3 measurements at Thule, Greenland: An intercomparison with Aura MLS observations

In response to the need for improving our understanding of the evolution and the interannual variability of the winter Arctic stratosphere, in January 2009 a Ground-Based Millimeter-wave Spectrometer (GBMS) was installed at the Network for the Detection of Atmospheric Composition Change (NDACC) site in Thule (76.5° N, 68.8° W), Greenland. In this work, stratospheric GBMS O3 and HNO3 vertical profiles obtained from Thule during the winters 2010 (HNO3 only), 2011 and 2012 are characterized and intercompared with co-located measurements of the Aura Microwave Limb Sounder (MLS) experiment. Using a recently developed algorithm based on Optimal Estimation, we find that the GBMS O3 retrievals show good sensitivity (> 80%) to atmospheric variations between ~ 17 and ~ 50 km, where their 1σ uncertainty is estimated to be the larger of ~ 11% or 0.2 ppmv. Similarly, HNO3 profiles can be considered for scientific use between ~ 17 and ~ 45 km altitude, with a 1σ uncertainty that amounts to the larger of 15% or 0.2 ppbv. Comparisons with Aura MLS version 3.3 observations show that, on average, GBMS O3 mixing ratios are biased negatively with respect to MLS throughout the stratosphere, with differences ranging between ~ 0.3 ppmv (8%) and 0.9 ppmv (18%) in the 17–50 km vertical range. GBMS HNO3 values display instead a positive bias with respect to MLS up to 26 km, reaching a maximum of ~ 1 ppbv (10%) near the mixing ratio profile peak. O3 and HNO3 values from the two datasets prove to be well correlated at all altitudes, although their correlations worsen at the lower end of the altitude ranges considered. Column contents of GBMS and MLS O3 (from 20 km upwards) and HNO3 (from 17 km upwards) correlate very well and indicate that GBMS measurements can provide valuable estimates of column interannual and seasonal variations for these compounds

EOS MLS observations of dehydration in the 2004-2005 polar winters

We prove various estimates for the first eigenvalue of the magnetic Dirichlet Laplacian on a bounded domain in two dimensions. When the magnetic field is constant, we give lower and upper bounds in terms of geometric quantities of the domain. We furthermore prove a lower bound for the first magnetic Neumann eigenvalue in the case of constant field.Comment: 19 page

The UARS microwave limb sounder version 5 data set: Theory, characterization, and validation

Nitric acid (HNO3) is a major player in processes controlling the springtime depletion of polar ozone. It is the main constituent of the Polar Stratospheric Clouds (PSCs) and a primary reservoir for reactive nitrogen. Potential variations in the stratospheric circulation and temperature may alter the extent and duration of PSCs activity, influencing the future ozone levels significantly. Monitoring HNO3 and its long-term variability, especially in polar region, is then crucial for better understanding issues related to ozone decline and expected recovery. In this study we present an intercomparison between ground based HNO3 measurements, carried out by means of the Ground-Based Millimeter-wave Spectrometer (GBMS), and two satellite data sets produced by the two NASA/JPL Microwave Limb Sounder (MLS) experiments. In particular, we compare UARS MLS measurements (1991-1999) with those carried out by the GBMS at South Pole, Antarctica (90°S), Fall of 1993 and 1995. A similar intercomparison is made between Aura MLS HNO3 observations (2004 - to date) and GBMS measurements obtained during the period February 2004 - March 2007, at the mid-latitudes/high altitudes station of Testa Grigia (45.9° N, 7.7° E, elev. 3500 m), and during polar winters 2008/09 and 2009/2010 at Thule Air Base (76.5°N 68.8°W), Greenland. We assess systematic differences between GBMS and both UARS and Aura HNO3 data sets at seven potential temperature levels (θ) spanning the range 465 – 960 K. The UARS data set advected to the South Pole shows a low bias, within 20% for all θ levels but the 960 K, with respect to GBMS measurements. A very good agreement, within 5%, is obtained between Aura and GBMS observations at Testa Grigia, while larger differences, possibly due to latitude dependent effects, are observed over Thule. These differences are under further investigations but a preliminary comparison over Thule among MLS v3, GBMS, and ACE-FTS measurements suggests that GBMS measurements carried out during winter 2009 might not be reliable. These comparisons have been performed in the framework of the NASA JPL GOZCARDS project, which is aimed at developing a long-term, global data record of the relevant stratospheric constituents in the context of ozone decline. GBMS has been selected in GOZCARDS since its HNO3 dataset, although sampling different latitudes in different years, is the only one spanning a sufficiently long time interval for cross-calibrating HNO3 measurements by the UARS and Aura MLS experiments

Intercomparison between Aura MLS and ground-based millimeter-wave observations of stratospheric O3 and HNO3 from Thule (76.5° N, 68.7° W)

The Ground-Based Millimeter-wave Spectrometer (GBMS) measures rotational emission spectra of middle atmospheric trace gases, with a spectral window of 600 MHz tunable between approximately 230 and 280 GHz and a resolution of up to 65 kHz. It was designed and built at the State University of New York at Stony Brook in the early 90’s and since then has been regularly upgraded and operated at a variety of sites in both hemispheres, at polar and mid-latitudes. In view of a growing need for long-term data sets of stratospheric constituents, in January 2009 we resolved to establish a long-term GBMS observation site at the Arctic station of Thule Air Base (76.5°N, 68.8°W), Greenland, in order to track the long- and short-term interactions between the changing climate and the seasonal processes tied to the ozone depletion phenomenon. Since then three winter campaigns were carried out from Thule during the period January-March 2009, 2010 and 2011. Observations of O3, HNO3, CO and N2O were performed, mostly on a daily basis, except during periods characterized by poor weather conditions. In this study we compare GBMS stratospheric O3 and HNO3 measurements obtained during these three winter periods at Thule with colocated satellite observations from the Aura Microwave Limb Sounder (MLS) experiment. The Version 3.3 Aura MLS O3 and HNO3 data sets have a resolution of about 2.5 km and 3-4 km, respectively, in the stratosphere. The MLS precisions range from 0.1 to 0.6 ppmv for O3 and about 0.6-0.7 ppbv for HNO3 throughout the stratosphere. Based on preliminary comparisons with correlative data sets and on results obtained for v2.2, systematic uncertainties are estimated to lead to HNO3 measurements biases that vary between ±0.5 and ±2 ppbv and multiplicative errors of ±5 –15% throughout most of the stratosphere. Similarly, a systematic uncertainty of the order of 5-10% has been assessed for O3 data. As for the GBMS, the O3 pure rotational transition line at 276.923 GHz is observed with a ~1.5-hour integration, while the weaker HNO3 spectrum, represented by a cluster of superimposed emission lines centered at 269.1 GHz, needs about 4 hours of integration. Taking advantage of the dependence of the line broadening on atmospheric pressure, inversion techniques allow the retrieval of vertical profiles from approximately 15 to 50 km. In the past, GBMS O3 and HNO3 spectra were deconvolved using a Chahine-Twomey (C-T) and an iterative constrained Matrix Inversion (MI) technique, respectively. More recently, the GBMS retrieval algorithm has been updated to an Optimal Estimation Method (OEM) in order to conform to the standard of the NDACC microwave group, and to easily provide retrievals with a set of averaging kernels that grants more straightforward comparisons with other data sets. The nominal vertical resolution of the retrieved profiles (defined as the FWHM of averaging kernels) is ~8 km for O3 and ~ 12 km for HNO3, although the inversion technique locates the maximum of the mixing ratio profile of both species with a much better accuracy (i.e., ~ ±1 km). The 1σ uncertainty of O3 and HNO3 mixing ratio vertical profiles depends on altitude and is estimated at ~15% or 0.3 ppbv, whichever is larger. Each GBMS profile is compared to the closest MLS profile, with coincidence criteria of ±10° longitude, ±2.5° latitude and ±12 h. In order to avoid of severely compromising the comparison between GBMS and Aura MLS observations due to the much higher resolution of the satellite-derived data sets, we ‘convolved’ the MLS profiles using the GBMS averaging kernels before directly comparing the two data sets. For both species a fairly good agreement between MLS and GBMS profiles is observed, with the GBMS showing, however, a ~10-15% low bias at the mixing ratio peak

Record-breaking ozone loss in the Arctic winter 2010/2011: comparison with 1996/1997

We present a detailed discussion of the chemical and dynamical processes in the Arctic winters 1996/1997 and 2010/2011 with high resolution chemical transport model (CTM) simulations and space-based observations. In the Arctic winter 2010/2011, the lower stratospheric minimum temperatures were below 195 K for a record period of time, from December to mid-April, and a strong and stable vortex was present during that period. Simulations with the Mimosa-Chim CTM show that the chemical ozone loss started in early January and progressed slowly to 1 ppmv (parts per million by volume) by late February. The loss intensified by early March and reached a record maximum of ~2.4 ppmv in the late March–early April period over a broad altitude range of 450–550 K. This coincides with elevated ozone loss rates of 2–4 ppbv sh^(−1) (parts per billion by volume/sunlit hour) and a contribution of about 30–55% and 30–35% from the ClO-ClO and ClO-BrO cycles, respectively, in late February and March. In addition, a contribution of 30–50% from the HO_x cycle is also estimated in April. We also estimate a loss of about 0.7–1.2 ppmv contributed (75%) by the NO_x cycle at 550–700 K. The ozone loss estimated in the partial column range of 350–550 K exhibits a record value of ~148 DU (Dobson Unit). This is the largest ozone loss ever estimated in the Arctic and is consistent with the remarkable chlorine activation and strong denitrification (40–50%) during the winter, as the modeled ClO shows ~1.8 ppbv in early January and ~1 ppbv in March at 450–550 K. These model results are in excellent agreement with those found from the Aura Microwave Limb Sounder observations. Our analyses also show that the ozone loss in 2010/2011 is close to that found in some Antarctic winters, for the first time in the observed history. Though the winter 1996/1997 was also very cold in March–April, the temperatures were higher in December–February, and, therefore, chlorine activation was moderate and ozone loss was average with about 1.2 ppmv at 475–550 K or 42 DU at 350–550 K, as diagnosed from the model simulations and measurements

IRTM brightness temperature maps of the Martian south polar region during the polar night: The cold spots don't move

A series of infrared thermal mapper (IRTM) south polar brightness temperature maps obtained by Viking Orbiter 2 during a 35-day period during the southern fall season in 1978 was examined. The maps show a number of phenomena that have been identified in previous studies, including day to day brightness temperature variations in individual low temperature regions and the tendency for IRTM 11-micron channel brightness temperatures to also decrease in regions where low 20-micron channel brightness temperatures are observed. The maps also show new phenomena, the most striking of which is a clear tendency for the low brightness temperature regions to occur at fixed geographic regions. During this season, the coldest low brightness temperatures appear to be concentrated in distinct regions, with spatial scales ranging from 50 to 300 km. There are approximately a dozen of these concentrations, with the largest centered near the location of the south residual polar cap. Other concentrations are located at Cavi Angusti and close to the craters Main, South, Lau, and Dana. Broader, less intense regions appear to be well correlated with the boundaries of the south polar layered deposits and the Mountains of Mitchell. No evidence for horizontal motion of any of these regions has been detected