148 research outputs found

    Charcoal evidence that rising atmospheric oxygen terminated Early Jurassic ocean anoxia

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    This is the final version of the article. Available from Springer Nature via the DOI in this record.The Toarcian Oceanic Anoxic Event (T-OAE) was characterized by a major disturbance to the global carbon(C)-cycle, and depleted oxygen in Earth’s oceans resulting in marine mass extinction. Numerical models predict that increased organic carbon burial should drive a rise in atmospheric oxygen (pO2) leading to termination of an OAE after ∌1 Myr. Wildfire is highly responsive to changes in pO2 implying that fire-activity should vary across OAEs. Here we test this hypothesis by tracing variations in the abundance of fossil charcoal across the T-OAE. We report a sustained ∌800 kyr enhancement of fire-activity beginning ∌1 Myr after the onset of the T-OAE and peaking during its termination. This major enhancement of fire occurred across the timescale of predicted pO2 variations, and we argue this was primarily driven by increased pO2. Our study provides the first fossil-based evidence suggesting that fire-feedbacks to rising pO2 may have aided in terminating the T-OAE.We thank the Natural Environment Research Council for funding through a studentship grant NE/L501669/1 to S.J.B. C.M.B. acknowledges funding via an ERC Starter Grant ERC-2013-StG-335891-ECOFLAM. S.P.H., T.M.L. and C.M.B. acknowledge funding from the NERC ‘JET’ grant NE/N018508/1, as well as a Royal Society Wolfson Research Merit Award supporting T.M.L

    Palynological, geochemical, and mineralogical characteristics of the Early Jurassic Liasidium Event in the Cleveland Basin, Yorkshire, UK

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    This is the final version. Available on open access from Borntraeger Science Publishers via the DOI in this record.A previously proposed hyperthermal episode in the Early Jurassic (mid- Sinemurian) is investigated from the shallow marine succession at Robin Hood’s Bay, Cleveland Basin, Yorkshire, UK. Palynological study confirms that the stratigraphical extent of the distinctive dinoflagellate cyst Liasidium variabile corresponds very closely to the oxynotum Zone. The range of Liasidium variabile also corresponds to an overall negative excursion in carbon-isotopes measured in bulk organic matter, which here exhibits a double spike in the middle oxynotum Zone. Additionally, Liasidium variabile abundances track overall transgressive-regressive facies trends with peak abundance of dinoflagellate cysts corresponding to deepest water facies and maximum flooding. Lithological cycles (parasequences), defined by visual description and hand-held X-ray fluorescence analysis of powdered samples, match previously suggested short eccentricity cycles, and allow a total duration for the event of at least one million years to be suggested. Changes in clay mineralogy throughout the section determined by whole rock X-ray diffraction and scanning electron microscopy are shown to be largely related to authigenic 33 processes, and neither support nor refute the proposition of coeval palaeoclimate changes. The combined characteristics of the Liasidium Event described from Robin Hood’s Bay are similar to, but much less extreme than, the Early Jurassic Toarcian Oceanic Anoxic Event albeit, at this locality, there is no evidence for the development of significant bottom water deoxygenation.Natural Environment Research Council (NERC)University of OxfordBritish Geological Survey (BGS)Leopoldina, German National Academy of Science

    Late Eocene to middle Miocene (33 to 13 million years ago) vegetation and climate development on the North American Atlantic Coastal Plain (IODP Expedition 313, Site M0027)

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    ArticleWe investigated the palynology of sediment cores from Site M0027 of IODP (Integrated Ocean Drilling Program) Expedition 313 on the New Jersey shallow shelf to examine vegetation and climate dynamics on the east coast of North America between 33 and 13 million years ago and to assess the impact of over-regional climate events on the region. Palynological results are complemented with pollen-based quantitative climate reconstructions. Our results indicate that the hinterland vegetation of the New Jersey shelf was characterized by oak–hickory forests in the lowlands and conifer-dominated vegetation in the highlands from the early Oligocene to the middle Miocene. The Oligocene witnessed several expansions of conifer forest, probably related to cooling events. The pollen-based climate data imply an increase in annual temperatures from ∌11.5 °C to more than 16 °C during the Oligocene. The Mi-1 cooling event at the onset of the Miocene is reflected by an expansion of conifers and mean annual temperature decrease of ∌4 °C, from ∌16 °C to ∌12 °C around 23 million years before present. Relatively low annual temperatures are also recorded for several samples during an interval around ∌20 million years before present, which may reflect the Mi-1a and the Mi-1aa cooling events. Generally, the Miocene ecosystem and climate conditions were very similar to those of the Oligocene. Miocene grasslands, as known from other areas in the USA during that time period, are not evident for the hinterland of the New Jersey shelf, possibly reflecting moisture from the proto-Gulf Stream. The palaeovegetation data reveal stable conditions during the mid-Miocene climatic optimum at ∌15 million years before present, with only a minor increase in deciduous–evergreen mixed forest taxa and a decrease in swamp forest taxa. Pollen-based annual temperature reconstructions show average annual temperatures of ∌14 °C during the mid-Miocene climatic optimum, ∌2 °C higher than today, but ∌1.5 °C lower than preceding and following phases of the Miocene. We conclude that vegetation and regional climate in the hinterland of the New Jersey shelf did not react as sensitively to Oligocene and Miocene climate changes as other regions in North America or Europe due to the moderating effects of the North Atlantic. An additional explanation for the relatively low regional temperatures reconstructed for the mid-Miocene climatic optimum could be an uplift of the Appalachian Mountains during the Miocene, which would also have influenced the catchment area of our pollen record.We thank the entire IODP Expedition 313 Scientific Party for input, and the IODP staff for support. We thank M. Drljepan, R. Zanatta, V. Menke, K. Reichel, and S. Namyslo for their assistance with preparing and processing the samples, and during photographing. Discussions with C. Bjerrum, J. Browning, T. Donders, L. Fang, M. Katz, Y. Milker, K. Miller, and P. Sugarman are gratefully acknowledged. Input from K. DybkjĂŠr and anonymous reviewers was very much appreciated and contributed to a significant condensing of the manuscript. The German Science Foundation supported the research (DFG project KO 3944/3-1 to U. Kotthoff). Funding was also provided by NSERC Discovery Grants to F. M. G. McCarthy and to D. R. Greenwood respectively. NERC supported work by S. P. Hesselbo. This research used samples and/or data provided by the Integrated Ocean Drilling Program (IODP)

    Total organic carbon and pyrolysis analysis of the Lower Cretaceous in Compton Bay and Atherfield, Isle of Wight (England)

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    This is the author accepted manuscript. The final version is available from the publisher via the DOI in this recordThe Wessex Basin (United Kingdom) includes hundreds of meters of Lower Cretaceous clays, silts, and sands deposited in a wide range of depositional environments. Studies have investigated these depositional systems from the organic matter (OM) perspective. However, questions remain concerning the composition, source, and the overall depositional constraints on the distribution of sedimentary OM in this area. Elemental (carbonate % and total organic carbon - TOC) and pyrolysis analyses were conducted on representative lithofacies of the Lower Cretaceous from the Wessex Basin at the Compton Bay and Atherfield sections, Isle of Wight. The highest TOC contents were determined in the upper part of the Ferruginous Sands and Sandrock formations. These elevated TOC intervals are associated with predominantly estuarine deposition. Except for one sample from the Vectis Formation, Hydrogen Index (HI) in all studied units is low and indicates Type IV kerogen assemblages, interpreted to be linked with strongly variable climates (with pronounced dry periods) and significant water table fluctuations in the source area and during transport. The one sample with a Type II-III kerogen assemblage from the lagoonal Vectis Formation supports previous studies which suggested that OM in the Vectis Formation varied vertically as a function of fluvial sediment and terrestrial organic matter input to the lagoonal environment with changes in salinity, sediment resuspension, and turbulence as a result controlling the abundance of dinoflagellate cysts

    Ichnology, sedimentology, and orbital cycles in the hemipelagic Early Jurassic Laurasian Seaway (Pliensbachian, Cardigan Bay Basin, UK)

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    This is the final version. Available on open access from Elsevier via the DOI in this recordAn uncommonly continuous Lower Jurassic (uppermost Sinemurian and Pliensbachian) section (Llanbedr (Mochras Farm) Borehole, Cardigan Bay Basin, UK) comprises hemipelagic calcareous mudstone, wackestone/siltstone and subordinate packstone/sandstone. Some beds show bigradational grading, and their sedimentary structures are typical of contourite drift facies. On the basis of the long-term persistence and stability of the currents that formed these deposits, sedimentation was likely controlled by thermohaline-driven geostrophic contour currents circulating between the Boreal ocean and Peri-Tethys through the narrow and relatively deep Cardigan Bay Basin (Cardigan Bay Strait). Trace fossils are strongly dominated by Phycosiphon incertum, which was produced by opportunistic colonizers. Thalassinoides, Schaubcylindrichnus and Teichichnus are common, accompanied by less common Zoophycos, Planolites, Palaeophycus, Trichichnus and dwelling structures such as cf. Polykladichnus, Siphonichnus and Skolithos. The ichnofabrics are usually simple, which results from generally high rates of deposition, unstable, water-saturated soft-ground substrate, and the domination of well-adapted Phycosiphon, but there are also cyclic appearances of more complex ichnofabrics with dwelling structures, reflecting more stable bottom conditions. A new detailed analysis of the core has allowed cycles to be distinguished based on combination of ichnological and sedimentological features, pointing to distinct cyclicity of oceanographic mechanisms influenced by orbital forcing and driving the inferred fluctuations in benthic life conditions, controlled mainly by variation in contour current intensity and oxygenation of bottom water reflected by trace fossils. The ichnological cycles show four-order hierarchy, which can be attributed to the orbital cycles: precession and obliquity (4th order), short eccentricity (3rd order), and long eccentricity (2nd order). The longest (~ 2.5 Myr) 1st order cyclicity is attributable to the longer ‟grand orbital cycles” (period related to the Earth–Mars secular resonance), with long-term impacts on palaeoclimatic and oceanic circulation dynamics, and is recorded in large-scale changes in ichnodiversity, correlating with long-term changes of clay minerals and carbonate content. Possibly, there is also ~ 9 Myr cyclicity, expressed in observed modulation of frequency of precession cycles by eccentricity. Harmonic analysis of the cyclicity gives high confidence of orbital signals and allows refined estimation of duration of the Pliensbachian (~8.4 Myr) and the jamesoni (~2.8 Myr), ibex (~ 2.0 Myr), davoei (~ 0.47 Myr), margaritatus (~ 2.33 Myr) and spinatum zones (~ 0.8 Myr) with an overall stable sedimentation rate of 4.5–5.1 cm/kyr. Obtained durations show improved fit between 2nd–4th and 1st order cycle and removes the problem of an anomalously long duration and resulting much lower sedimentation rate for the spinatum Zone, previously obtained by other methods. A higher diversity of trace fossils is noticed in intervals enriched in smectite; most likely, this clay mineral occluded pore spaces and limited the competition from the opportunist Phycosiphon makers, allowing development of other, more specialized forms. The continuous, expanded ichnological record of deep-water hemipelagic/contour drift sediments is sensitive to climatic and oceanographic changes controlled by orbital cycles. The Cardigan Bay Strait played an important role in the Early Jurassic (at least Pliensbachian) oceanic circulation, providing a major link between the northern and southern part of the Laurasian Seaway (and in general between the Boreal and Peri-Tethys domains), funneling currents flowing from the north to the south.National Science Centre, PolandInternal Polish Geological InstituteNatural Environment Research Council (NERC

    The wider context of the Lower Jurassic Toarcian oceanic anoxic event in Yorkshire coastal outcrops, UK

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    This is the author accepted manuscript. The final version is available from Elsevier via the DOI in this record.The Toarcian Oceanic Anoxic Event (T-OAE, ∌183 Ma) was characterized by enhanced carbon burial, a prominent negative carbon-isotope excursion (CIE) in marine carbonate and organic matter, and numerous geochemical anomalies. A precursor excursion has also been documented at the Pliensbachian/Toarcian boundary, but its possible causes are less constrained. The T-OAE is intensively studied in the Cleveland Basin, Yorkshire, UK, whose sedimentary deposits have been litho-, bio- and chemostratigraphically characterised. Here, we present new elemental data produced by hand-held X-ray fluorescence analysis to test the expression of redox-sensitive trace metals and detrital elements across the upper Pliensbachian to mid-Toarcian of the Cleveland Basin. Detrital elemental concentrations (Al, Si, Ti, Zr) are used as proxies for siliciclastic grain content and thus, sea-level change, which match previous sequence stratigraphic interpretations from the Cleveland Basin. The timescale of the event is debated, though our new elemental proxies of relative sea level change show evidence for a cyclicity of 350 cm that may be indicative of ∌405 kyr eccentricity cycles in Yorkshire. Trends in total organic carbon and redox-sensitive elements (S, Fe, Mo, As) confirm scenarios of widespread ocean deoxygenation across the T-OAE. The correlation of comparable trends in Mo across the T-OAE in Yorkshire and the Paris Basin suggests a similar oceanic drawdown of this element accompanying widespread anoxia in the two basins. Data from Yorkshire point to a transgressive trend at the time of the Mo drawdown, which contradicts the “basin restriction” model for the euxinic conditions that characterise the CIE interval.The Carlsberg Foundation (project 2011-01-0737 to CK) and the Danish Council for Independent Research-Natural Sciences (project 09-072715 to CK) are acknowledged for contributions to financing this project

    Facies architecture of Miocene subaqueous clinothems of the New Jersey passive margin: Results from IODP-ICDP Expedition 313

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    Understanding the history, causes, and impact of sea-level changes is a challenge for our societies that face accelerated global sea-level rise. In this context, improvement of our knowledge of sea-level changes and shoreline migration at geological time scales is critical. The preserved, laterally correlative sedimentary record of continental erosion on passive margins has been used to reconstruct past sea level. However, the detailed nature of a basic clinothem progradational pattern observed on many of these margins is still poorly known. This paper describes the sedimentary facies and interprets the depositional environments and the architecture of the clinothems of the New Jersey shelf (offshore northeastern USA) to depict the origin and controls of the distribution of the sediment on the margin. We analyze 612 cores totaling 1311 m in length collected at three sites 60 km offshore Atlantic City, New Jersey, during International Ocean Discovery Program–International Continental Scientific Drilling Program (IODP-ICDP) Expedition 313. The three sites sampled the lower to middle Miocene passive margin sediments of the New Jersey shelf clinothems. We also collected wireline logs at the three sites and tied the sedimentary architecture to the geometry observed on seismic profiles. The observed sediment distribution in the clinoform complex differs from that of current models based on seismic data, which predict a progressive increase in mud and decrease in sand contents in a seaward direction. In contrast, we observe that the clinoforms are largely composed of muds, with sands and coarser material concentrated at the rollover, the bottomset, and the toe of the slope. The shelf clinothem topsets are storm-influenced mud whereas the foreset slope is composed of a mud wedge largely dominated by density current deposits (e.g., low-density turbidites and debrites). The architecture of the clinothem complex includes a composite stack of ~30-m-thick clinothem units each made up of four systems tracts (Transgressive, Highstand, Forced-Regres­sive, and Lowstand Systems Tract) building individual transgressive-regres­sive sequences. The presence of mud-rich facies deposited during highstands on the topset of the clinoform, 40–60 km offshore from the sand-prone shoreface deposit (observed in the New Jersey onshore delta plain), and the lack of subaerial erosion (and continental depositional environments) point to a depositional model involving a subaerial delta (onshore) feeding a distant subaqueous delta. During forced regressions, shelf-edge deltas periodically overstep the stacks of flood-influenced, offshore-marine mud wedges of the New Jersey subaqueous delta, bringing sand to the rollover and building up the large-scale shelf-prism clinothems. The clinothem complex develops on a gently dipping platform with a ramp-like morphology (apparent dip of 0.75°–0.5°) below mean storm wave base, in 30–50 m of water depth, 40–60 km seaward of the coastal area. Its shape depends on the balance between accom­mo­da­tion and sedimentation rates. Subaqueous deltas show higher accumulation rates than their subaerial counterparts and prograde three times further and faster than their contemporaneous shoreline. The increase in the intensity of waves (height and recurrence intervals) favors the separation between subaqueous and subaerial deltas, and as a consequence, the formation of a flat topset geometry, a decrease in flood events and fluvial discharge, an overall progressive decrease in sediment grain size (from sequence m5.45, ca. 17.8–17.7 Ma, onwards), as well as an increase in sedimentation rates on the foresets of the clinoforms. All of these are recognized as preliminary signals that might characterize the entry into the Neogene icehouse world

    Geochemistry of macrofossil, bulk rock and secondary calcite in the Early Jurassic strata of the Llanbedr (Mochras Farm) drill core, Cardigan Bay Basin, Wales, UK

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    This is the final version. Available on open access from the Geological Society via the DOI in this recordData availability: All data generated during this study are included in the Supplementary information files for this article.The Llanbedr (Mochras Farm) core (Wales, UK) yielded a >1300 m long mudrock sequence that has excellent potential for establishing an integrated stratigraphic scheme for the entire Early Jurassic Epoch. Lithological variations in the core are predominantly driven by hierarchical changes in the carbonate content. These changes also dominate – or may impact upon – many geochemical and physical properties of the core. The bulk carbonate C isotope record displays systematic fluctuations, the largest of which correspond to previously identified phases of environmental perturbation. The magnitudes of negative C isotope excursions in carbonate are inflated compared with equivalents previously described elsewhere as a result of diagenesis and the concomitant loss of primary carbonate. The marine macrofossil record of Mochras reveals biological and isotopic patterns that are generally comparable with other UK basins. Potentially significant differences between the Cleveland and Cardigan Bay basins are observed in the Pliensbachian and Toarcian fossils. This different expression may be related to different habitat structures or palaeoceanographic and water depth differences between these basins. Minima in macrofossil ή18O values generally coincide with peaks in macrofossil wood abundance and sea-level lowstands inferred from sequence stratigraphic interpretation of other UK sections. This relationship suggests a possible relative sea-level control on the observed O isotope records and sediment provenance.Natural Environment Research Council (NERC
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