Gravitational Effects on the Morphology and Kinetics of Photodeposition of Polydiacetylene Thin Films From Monomer Solutions

The goal of this proposed work is to study gravitational effects on the photodeposition of polydiacetylene thin films from monomer solutions onto transparent substrates. Polydiacetylenes have been an extensively studied class of organic polymers because they exhibit many unusual and interesting properties, including electrical conductivity and optical nonlinearity. Their long polymeric chains render polydiacetylenes readily conducive to thin film formation, which is necessary for many applications. These applications require thin polydiacetylene films possessing uniform thicknesses, high purity, minimal inhomogeneities and defects (such as scattering centers), etc. Also, understanding and controlling the microstructure and morphology of the films is important for optimizing their electronic and optical properties. The lack of techniques for processing polydiacetylenes into such films has been the primary limitation to their commercial use. We have recently discovered a novel method for the formation of polydiacetylene thin films using photo-deposition from monomer solutions onto transparent substrates with UV light. This technique is very simple to carry out, and can yield films with superior quality to those produced by conventional methods. Furthermore, these films exhibit good third-order properties and are capable of waveguiding. We have been actively studying the chemistry of diacetylene polymerization in solution and the photo-deposition of polydiacetylene thin films from solution. It is well-known that gravitational factors such as buoyancy-driven convection and sedimentation can affect chemical and mass transport processes in solution. One important aspect of polydiacetylene thin film photodeposition in solution, relevant to microgravity science, is that heat generated by absorption of UV radiation induces thermal density gradients that under the influence of gravity, can cause fluid flows (buoyancy-driven convection). Additionally, changes in the chemical composition of the solution during polymerization may cause solutal convection. These fluid flows affect transport of material to and from the film surface and thereby affect the kinetics of the growth process. This manifests itself in the morphology of the resulting films; films grown under the influence of convection tend to have less uniform thicknesses, and can possess greater inhomogeneities and defects. Specifically, polydiacetylene films photodeposited from solution, when viewed under a microscope, exhibit very small particles of solid polymer which get transported by convection from the bulk solution to the surface of the growing film and become embedded. Even when carried out under conditions designed to minimize unstable density gradients (i.e., irradiating the solution from the top), some fluid flow still takes place (particles remain present in the films). It is also possible that defect nucleation may be occurring within the films or on the surface of the substrate; this, too, can be affected by convection (as is the case with crystal growth). Hence films grown in 1-g will, at best, still possess some defects. The objective of this proposal is to investigate, both in 1-g and in low-g, the effects of gravitational factors (primarily convection) on the dynamics of these processes, and on the quality, morphology, and properties of the films obtained

Characterising anomalous transport in accretion disks from X-ray observations

Whilst direct observations of internal transport in accretion disks are not yet possible, measurement of the energy emitted from accreting astrophysical systems can provide useful information on the physical mechanisms at work. Here we examine the unbroken multi-year time variation of the total X-ray flux from three sources: Cygnus X-1 , the microquasar GRS 1915+105 , and for comparison the nonaccreting Crab nebula. To complement previous analyses, we demonstrate that the application of advanced statistical methods to these observational time-series reveals important contrasts in the nature and scaling properties of the transport processes operating within these sources. We find the Crab signal resembles Gaussian noise; the Cygnus X-1 signal is a leptokurtic random walk whose self-similar properties persist on timescales up to three years; and the GRS 1915+105 signal is similar to that from Cygnus X-1, but with self-similarity extending possibly to only a few days. This evidence of self-similarity provides a robust quantitative characterisation of anomalous transport occuring within the systems

The subscale orbital fluid transfer experiment

The Subscale Orbital Fluid Transfer Experiment (SOFTE) is a planned Shuttle Orbiter fluid transfer experiment. CASP (Center for Advanced Space Propulsion) performed certain aspects of the conceptual design of this experiment. The CASP work consisted of the conceptual design of the optical system, the search for alternative experimental fluids, the determination of the flow meter specifications and the examination of materials to use for a bladder that will empty one of the tanks in the experiment

Genotoxic and Anatomical Deteriorations Associated with Potentially Toxic Elements Accumulation in Water Hyacinth Grown in Drainage Water Resources

Potentially toxic elements (PTEs)-induced genotoxicity on aquatic plants is still an open question. Herein, a single clone from a population of water hyacinth covering a large distribution area of Nile River (freshwater) was transplanted in two drainage water resources to explore the hazardous effect of PTEs on molecular, biochemical and anatomical characters of plants compared to those grown in freshwater. Inductivity Coupled Plasma (ICP) analysis indicated that PTEs concentrations in water resources were relatively low in most cases. However, the high tendency of water hyacinth to bio-accumulate and bio-magnify PTEs maximized their concentrations in plant samples (roots in particular). A Random Amplified Polymorphic DNA (RAPD) assay showed the genotoxic effects of PTEs on plants grown in drainage water. PTEs accumulation caused substantial alterations in DNA profiles including the presence or absence of certain bands and even the appearance of new bands. Plants grown in drainage water exhibited several mutations on the electrophoretic profiles and banding pattern of total protein, especially proteins isolated from roots. Several anatomical deteriorations were observed on PTEs-stressed plants including reductions in the thickness of epidermis, cortex and endodermis as well as vascular cylinder diameter. The research findings of this investigation may provide some new insights regarding molecular, biochemical and anatomical responses of water hyacinth grown in drainage water resources.</jats:p

First Measurements of Electron Temperature Fluctuations by Correlation ECE on Tore Supra

Electron temperature fluctuation studies can help to understand the nature of the turbulent transport in to-kamak plasmas. At Tore Supra, a 32-channel heterodyne ECE radiometer has been upgraded with two chan-nels of 100 MHz bandwidth and tunable central frequencies allowing the shift of the plasma sample volume in the radial direction. With the sufficiently large video bandwidth and the long sampling time, it is possible to reduce significantly the thermal noise and to identify "true" high frequency components up to 200 kHz from the cross-correlation between these channels. First results of temperature fluctuation measurements on Tore Supra are reported in this paper.Comment: 12th International Congress on Plasma Physics, 25-29 October 2004, Nice (France

EXPERIMENTAL STUDY OF HYBRID LIQUID DESICCANT BASED VAPOR COMPRESSION COOLING SYSTEM

In the kingdom of Saudi Arabia, a vast amount of energy is used for air-conditioning and this paper describes a new approach to air conditioning. In the proposed hybrid cooling system, liquid desiccant is used to remove the latent load and the conventional vapor-compression system is used to provide sensible cooling only. In this experimental study, calcium chloride solution is used as the desiccant to dehumidify the air. Gauze-type structured packing towers are used for the dehumidification of air and also for regeneration of the weak desiccant. The designed packed bed dehumidifier and the regenerator are combined with a 5-ton capacity vapor compression system along with the heat recovery units. This paper presents results from a detailed experimental investigation of the heat and mass transfer in a structured packing dehumidifier and regenerator under a variety of operating conditions. In the present study, for the sake of comparison between hybrid and conventional cooling systems, the COP for the cooling system is defined as the heat removed from the space to be cooled divided by energy input for the cooling system. Three different modes of regeneration are considered for the hybrid cooling system and the COP values are compared with conventional vapor compression system. Results show that the ratio of the outlet-to-inlet absolute humidity reaches a steady state value of about 0.6 and the temperature of air decreased from 48 to 38o C in the dehumidifier of the hybrid system. Moreover, it is found that hybrid cooling system provides higher COP compared with conventional system

New phiocricetomyine rodents (Hystricognathi) from the Jebel Qatrani Formation, Fayum Depression, Egypt

Background The rich rodent assemblages from the Eocene–Oligocene deposits of the Jebel Qatrani Formation (Fayum Depression, Egypt) have important implications for our understanding of the origin and paleobiogeography of Hystricognathi, a diverse clade that is now represented by the Afro-Asiatic Hystricidae, New World Caviomorpha, and African Phiomorpha. Methods Here we present previously undescribed material of the enigmatic hystricognath clade Phiocricetomyinae, from two stratigraphic levels in the lower sequence of the Jebel Qatrani Formation—a new genus and species (Qatranimys safroutus) from the latest Eocene Locality 41 (~34 Ma, the oldest and most productive quarry in the formation) and additional material of Talahphiomys lavocati from that species’ type locality, early Oligocene Quarry E (~31–33.2 Ma). Results The multiple specimens of Qatranimys safroutus from L-41 document almost the entire lower and upper dentition, as well as mandibular fragments and the first cranial remains known for a derived phiocricetomyine. Specimens from Quarry E allow us to expand comparisons with specimens from Libya (late Eocene of Dur at-Talah and early Oligocene of Zallah Oasis) that have been placed in T. lavocati, and we show that the Dur at-Talah and Zallah specimens do not pertain to this species. These observations leave the Fayum Quarry E as the only locality where T. lavocati occurs

Antenna Characterization for Bluetooth-based Travel Time Data Collection

Several approaches for travel time data collection based on the reading of time-stamped media access control addresses from Bluetooth-enabled devices have been reported in the literature recently. This new approach offers a number of advantages over more conventional methods, including lower costs of hardware and software, the volume of data that can be collected over time, and ease of implementation. A fundamental component that may affect the quantity and the quality of the travel time samples collected with a Bluetooth-based system is the antenna type utilized. Antenna characteristics such as polarization and gain must be matched to specific application environments to optimize the performance of a Bluetooth reader unit. However, experimental data that focuses on antenna characterization as it relates to the use of Bluetooth technology to assess the performance of transportation facilities is lacking. In this study, five different types of antennas were characterized to assess their suitability to support a Bluetooth-based travel time data collection system. The results indicate that vertically polarized antennas with gains between 9dBi and 12dBi are good candidates for travel time data collection. Also, different antenna types are better suited to different uses of the Bluetooth-based system. If the main focus is the collection of travel time data, then an antenna with a lower sampling rate may provide more accurate travel time samples.Keywords: Gain, Antenna, MAC address, Polarization, Travel time, Bluetoot