28 research outputs found

    Where to park? Architecture and implementation of an empty parking lot, automatic recognition system

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    The traffic congestion present in practically every city has, among its increasing factors, the unavailability of enough parking spaces. A typical driver invests a considerable part of the total trip time looking for a free space where to park his vehicle; in many cases, this leads to delays and the consequent discomfort due to the undesired consequences of the generated tardiness. For this problem it is possible to find partial palliative solutions, minimizing the time spent searching for parking by applying Internet of Things techniques, oriented to smart cities and buildings. This research has been focused on finding an appropriate computer architecture that will allow the implementation of a distributed system, which, thanks to the use of computer vision and machine learning techniques, detects free parking spaces inside a parking lot, and provides real time information to the driver, allowing him to go as directly as possible to a vacant parking space

    Modeling the effect of the electrode potential in SERS by electronic structure calculations.

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    Surface Enhanced Raman Spectroscopy (SERS), due to the ability of greatly intensify the weak Raman signal of molecules adsorbed to metal surfaces, has proven to be a very useful tool to investigate changes in the electronic structure of metal-molecule surface complex. A deep knowledge of the electronic structure of these metal-molecule hybrid systems is key in electrochemistry, catalysis, plasmonics, molecular electronics, and in the development of selective and ultra-sensitive analytical sensors. The origin of this huge enhancement in SERS is due to two contributions: the electromagnetic (EM), related to surface plasmons, and the chemical mechanism, due to resonant charge transfer (CT) process between the adsorbate and the metal (CTSERS). Unfortunately, the SERS implies very complex phenomena where the molecule and the metal nanoparticle are involved. This fact makes challenging to build realistic theoretical models that take into account both the metal and the molecule at quantum level. We propose a methodology, based on DFT and ab initio electronic calculations, to simulate the effect of the electrode potential on the absorption, on the charge transfer states energies, and on the electronic excitations in metal-molecule hybrid systems from a microscopic point of view. This methodology consists on the prediction of Raman intensities from ab initio calculations of the geometries or the energy gradients at the excited states Franck-Condon point, bringing the possibility to predict the intensities in CTSERS as well as in resonance Raman without the need to know the excited state geometries, not always feasible to compute. The microscopic model adopted to mimic the effect of the interphase electric potential consist in a molecule adsorbed to a linear silver cluster [Agn-Adsorbate]q, were n is the number of silver atoms, and the total charge of the system (q) is zero for n=2 and q=±1 for n=1, 3 and 7.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech

    Surface-enhanced photoinduced charge transfer processes in metal-molecule nanoclusters

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    Resumen de conferencia presentada en el congreso ICP2013 en Lovaina (Bélgica) en julio de 2013This work deals with the unexplained efficiency of the electrode potential (EV) in tuning the energy of Charge Transfer (ECT) electronic states of hybrid systems formed by molecules and metal nanostructures. Huge energy gains (G) of up to 5 eV/V observed in electrochemical SERS experiences have been tentatively explained by a local increase of the electric potential at specific adsorption sites.[1] This gain, which is in conflict with the classical picture of the metal-adsorbate CT mechanism (G=1), can be quite relevant since it means that a relatively small change in the applied voltage can produce a large shift in the CT states, and consequently, it can greatly modify the resonant conditions in a SERS experiment. [2] Supported on electronic structure calculations of metal-molecule nanoclusters, we are able to elucidate that this “anomalous” gain is mainly due to two different contributions, firstly, the sensitivity of the CT electronic states of each particular metal-molecule system on the effective charge excess of the metal, and, secondly, to an enhanced electric capacitance of the metallic nanocluster with respect to the macroscopic values. We associate this last contribution with the so-called “edge effect” that causes inhomogeneities in the density charge at local sites of the metallic surface which could correspond to the very popular "hot spots" between the SERS community. [1] L. Cui, D-Y Wu, A. Wang, B. Ren, Z-Q Tian, J. Phys. Chem. C, 2010, 114, 16588-16595. [2] A. Otto, Surface Science, 1984, 138, 319-338Universidad de Málaga. Campus de Excelencia Internacional de Andalucía Tech

    Cobertura y Distribución de las Especies de Mangle en el Humedal Nacional Térraba-Sierpe, Costa Rica

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    El Humedal Nacional Térraba-Sierpe se localiza el sureste de Costa Rica, tiene una extensión aproximada de 14800 ha de mangle y para este trabajo se realizó una clasificación espectral con una imagen satelital Rapid Eye del año 2012 para determinar la distribución de las especies de mangle más abundantes: Rhizophora racemosa, Pelliciera rhizophorae, la asociación entre la especies R. racemosa y P. rhizophorae, y Rhizophora mangle; además de otras especies del humedal presentes como Acrostichum aureum. También, se realizó un análisis de las características geomorfológicas y ecológicas que favorecen a las especies dominantes en el HNTS y cómo los cambios en el uso de la tierra en las zonas adyacentes a esta área silvestre protegida generan alteraciones en este delicado ecosistema de gran importancia internacional

    Medición de la adherencia al lavado de manos, según los cinco momentos de la OMS

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    Contact with objects and people in the hospital environment, promotes the spread of germs that threaten patients, so hand washing prevents infection. Adherence to hand washing in health care officials was measured according to the five moments of hand hygiene WHO. Transversal and quantitative study, which evaluated the adherence to hand washing outpatient and emergency personnel of Assbasalud ESE and impact after training. It was conducted in three phases: pre-training, training and post-training. The final sample was 128 employees in nine Bank suite´s (30%). The adhesion measurement was approved by the Executive Quality Committee Assbasalud ESE. Were taken into account hand hygiene, use of enamels, jewels were evaluated; and relevance of the substances used for aseptic. The overall adherence of handwashing in Phase 1 and 61,8% for the 2nd phase of 78,3% was obtained, with positive results in relation to national and international studies. It is concluded that hand washing, valued at 67,1 % during the thirdth quarter of 2013, is an excellent strategy to strengthen patient safety and prevent hospital infections.El contacto con objetos y personas en el entorno hospitalario, favorece la propagación de gérmenes que amenazan a los pacientes, así que lavarse las manos previene infecciones. Se midió la adherencia al lavado de manos en funcionarios asistenciales según los cinco momentos de la higiene de las manos de la OMS. Estudio transversal y cuantitativo, que evaluó la adherencia al lavado de las manos en personal ambulatorio y de urgencias de Assbasalud ESE y el impacto después de recibir capacitación. Se realizó en tres fases: Precapacitación, capacitación y poscapacitación. Fueron 128 colaboradores en 9 sedes. El Comité de Calidad de la IPS dió el aval. Se tuvieron en cuenta las etapas de la higiene de manos, el uso de esmaltes, joyas y la pertinencia de las sustancias empleadas para la asepsia. La adherencia obtenida al lavado de manos en la 1ª fase fue 61,8% y para la 2ª del 78,3%; resultados positivos con relación a estudios internacionales. Se concluye que el lavado de las manos, valorada en 78,3% durante el cuarto trimestre de 2013, es una excelente estrategia para prevenir infecciones hospitalarias

    Medición de la adherencia al lavado de manos, según los cinco momentos de la OMS

    Get PDF
    Contact with objects and people in the hospital environment, promotes the spread of germs that threaten patients, so hand washing prevents infection. Adherence to hand washing in health care officials was measured according to the five moments of hand hygiene WHO. Transversal and quantitative study, which evaluated the adherence to hand washing outpatient and emergency personnel of Assbasalud ESE and impact after training. It was conducted in three phases: pre-training, training and post-training. The final sample was 128 employees in nine Bank suite´s (30%). The adhesion measurement was approved by the Executive Quality Committee Assbasalud ESE. Were taken into account hand hygiene, use of enamels, jewels were evaluated; and relevance of the substances used for aseptic. The overall adherence of handwashing in Phase 1 and 61,8% for the 2nd phase of 78,3% was obtained, with positive results in relation to national and international studies. It is concluded that hand washing, valued at 67,1 % during the thirdth quarter of 2013, is an excellent strategy to strengthen patient safety and prevent hospital infections.El contacto con objetos y personas en el entorno hospitalario, favorece la propagación de gérmenes que amenazan a los pacientes, así que lavarse las manos previene infecciones. Se midió la adherencia al lavado de manos en funcionarios asistenciales según los cinco momentos de la higiene de las manos de la OMS. Estudio transversal y cuantitativo, que evaluó la adherencia al lavado de las manos en personal ambulatorio y de urgencias de Assbasalud ESE y el impacto después de recibir capacitación. Se realizó en tres fases: Precapacitación, capacitación y poscapacitación. Fueron 128 colaboradores en 9 sedes. El Comité de Calidad de la IPS dió el aval. Se tuvieron en cuenta las etapas de la higiene de manos, el uso de esmaltes, joyas y la pertinencia de las sustancias empleadas para la asepsia. La adherencia obtenida al lavado de manos en la 1ª fase fue 61,8% y para la 2ª del 78,3%; resultados positivos con relación a estudios internacionales. Se concluye que el lavado de las manos, valorada en 78,3% durante el cuarto trimestre de 2013, es una excelente estrategia para prevenir infecciones hospitalarias

    Global urban environmental change drives adaptation in white clover

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    Urbanization transforms environments in ways that alter biological evolution. We examined whether urban environmental change drives parallel evolution by sampling 110,019 white clover plants from 6169 populations in 160 cities globally. Plants were assayed for a Mendelian antiherbivore defense that also affects tolerance to abiotic stressors. Urban-rural gradients were associated with the evolution of clines in defense in 47% of cities throughout the world. Variation in the strength of clines was explained by environmental changes in drought stress and vegetation cover that varied among cities. Sequencing 2074 genomes from 26 cities revealed that the evolution of urban-rural clines was best explained by adaptive evolution, but the degree of parallel adaptation varied among cities. Our results demonstrate that urbanization leads to adaptation at a global scale

    How gender stereotypes affect memory?: Forgetfulness and false memories production in university students

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    Treball Final de Grau en Psicologia. Codi: PS1048. Curs: 2017/2018Introduction : Traditionally, gender stereotypes associated power tasks to male and domestic tasks to females (García - Retamero & López - Zafra , 2006 ; Eagly , 2007 ) . Objective : The aim of this study were to observe if this ideas are still valid in college students and if have influence in their cognitive performance . Methods : UJI students completed a memory task with recognition test and answered three questions about the ability of women and men to develop a professional career . Results : No differences between women and men were observed regarding to explicit questions . To the other hand regarding memory task, both women and men showed more false negative errors for "woman - career" stimuli and more false positive for "men - career" stimuli and less false negative for "woman - career" stimuli and less false positive for "woman - career“ stimuli Conclusions : According to the present study gender stereotype are still existing and have influence to cognitive performance in college students
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