118 research outputs found
Spin transport in dangling-bond wires on doped H-passivated Si(100)
New advances in single-atom manipulation are leading to the creation of
atomic structures on H passivated Si surfaces with functionalities important
for the development of atomic and molecular based technologies. We perform
total-energy and electron-transport calculations to reveal the properties and
understand the features of atomic wires crafted by H removal from the surface.
The presence of dopants radically change the wire properties. Our calculations
show that dopants have a tendency to approach the dangling-bond wires, and in
these conditions, transport is enhanced and spin selective. These results have
important implications in the development of atomic-scale spintronics showing
that boron, and to a lesser extent phosphorous, convert the wires in
high-quality spin filters.Comment: 11 pages, 4 figure
Thioetherification of Br-Mercaptobiphenyl Molecules on Au(111)
Thioether polymers are fundamental for a variety of applications. Their synthesis is, however, more challenging than that of other metal-catalyzed reactions due to the reported detachment of the S atom during thermal activation. In this study, it has been demonstrated unambiguously that thermal annealing results in the thioetherification of the 4-bromo-4-mercaptobiphenyl molecule (Br-MBP) adsorbed on the surface of Au(111). Through complementary techniques, such as scanning tunneling microscopy, spectroscopy, and first-principle calculations, we have identified four reaction steps, involving sulfhydryl or bromine molecular functional groups and leading to the formation of intermolecular C–S bonds. To form the thioether polymer and to overcome the competitive formation of C–C bonds, two reaction steps, the dehalogenation, and dissociation of the S–Au bond, must occur simultaneously. We detail the electronic properties of the phenyl–sulfur bond and the polymer as a function of the ligand length. This result suggests a wider perspective of this chemical synthesis.L.V. acknowledges the funding of Diputación Foral de Guipuzcoa (Red/Sarea 2021-CIEN-000032-01, Red/Sarea 2022-CIEN-000017-01), the Basque Government (Proyectos de Investigación Básica y/o Aplicada grant number PIBA-2021-0026, and Grupo consolidado IT1453-22. R.R. and N.L. acknowledge financial support from the Spanish State Research Agency Grant PID2021-127917NB-I00 funded by MCIN/AEI/10.13039/501100011033 and by “ERDF A way of making Europe”; from the European Union project ESiM 101046364; and they are grateful for the computer resources at Finisterrae II, and the technical support provided by CESGA
Elastic transport through dangling-bond silicon wires on H passivated Si(100)
We evaluate the electron transmission through a dangling-bond wire on
Si(100)-H (2x1). Finite wires are modelled by decoupling semi-infinite Si
electrodes from the dangling-bond wire with passivating H atoms. The
calculations are performed using density functional theory in a non-periodic
geometry along the conduction direction. We also use Wannier functions to
analyze our results and to build an effective tight-binding Hamiltonian that
gives us enhanced insight in the electron scattering processes. We evaluate the
transmission to the different solutions that are possible for the dangling-bond
wires: Jahn-Teller distorted ones, as well as antiferromagnetic and
ferromagnetic ones. The discretization of the electronic structure of the wires
due to their finite size leads to interesting transmission properties that are
fingerprints of the wire nature
Supramolecular Chemistry Based on 4-Acetylbiphenyl on Au(111)
On a gold surface, supramolecules composed of 4-acetylbiphenyl molecules show
structural directionality, reproducibility and robustness to external
perturbations. We investigate the assembly of those molecules on the Au(111)
surface and analyze how the observed supramolecular structures are the result
of weak long-range dispersive forces stabilizing the 4-acetylbiphenyl molecules
together. Metallic adatoms serve as stabilizing agents. Our analysis suggests
new ways of creating complex molecular nano-objects that can eventually be used
as devices or as seeds for extended hierarchical structures
Real space manifestations of coherent screening in atomic scale Kondo lattices
The interaction among magnetic moments screened by conduction electrons drives quantum phase transitions between magnetically ordered and heavy-fermion ground states. Here, starting from isolated magnetic impurities in the Kondo regime, we investigate the formation of the finite size analogue of a heavy Fermi liquid. We build regularly-spaced chains of Co adatoms on a metallic surface by atomic manipulation. Scanning tunneling spectroscopy is used to obtain maps of the Kondo resonance intensity with sub-atomic resolution. For sufficiently small interatomic separation, the spatial distribution of Kondo screening does not coincide with the position of the adatoms. It also develops enhancements at both edges of the chains. Since we can rule out any other interaction between Kondo impurities, this is explained in terms of the indirect hybridization of the Kondo orbitals mediated by a coherent electron gas, the mechanism that causes the emergence of heavy quasiparticles in the thermodynamic limit.Financial support was provided by the Spanish Plan Nacional de I+ D+ i (grants MAT 2013-46593-C6-3-P, MAT2016-78293-C6-6-R, MAT2015-66888-C3-2-R, and FIS2015-64886-C5-3-P), Charles University (programme PRIMUS/Sci/09) and the European Union through programmes Interreg-POCTEFA (grant TNSI/EFA194/16) and H2020-EINFRA-5-2015 MaX Center of Excellence (grant no. 676598). M. M.-L., M. P., and D. S. acknowledge the use of SAI at Universidad de Zaragoza. R. R. acknowledges The Severo Ochoa Centers of Excellence Program (grant no. SEV-2017-0706) and Generalitat de Catalunya (grant no. 2017SGR1506 and the CERCA Programme)
AFM Imaging of Mercaptobenzoic Acid on Au(110) : Submolecular Contrast with Metal Tips
A self-assembled monolayer of mercaptobenzoic acid (MBA) on Au(110) is investigated with scanning tunneling and atomic force microscopy (STM and AFM) and density functional calculations. High-resolution AFM images obtained with metallic tips show clear contrasts between oxygen atoms and phenyl moieties. The contrast above the oxygen atoms is due to attractive covalent interactions, which is different than previously reported high-resolution images, where Pauli repulsion dominated the image contrast. We show that the bonding of MBA to the substrate occurs mainly through dispersion interactions, whereas the thiol-Au bond contributes only a quarter of the adsorption energy. No indication of Au adatoms mediating the thiol-Au interaction was found in contrast to other thiol-bonded systems. However, MBA lifts the Au(110)-(2 × 1) reconstruction
Magnetic Interplay between π-Electrons of Open-Shell Porphyrins and d-Electrons of Their Central Transition Metal Ions.
Magnetism is typically associated with d- or f-block elements, but can also appear in organic molecules with unpaired π-electrons. This has considerably boosted the interest in such organic materials with large potential for spintronics and quantum applications. While several materials showing either d/f or π-electron magnetism have been synthesized, the combination of both features within the same structure has only scarcely been reported. Open-shell porphyrins (Pors) incorporating d-block transition metal ions represent an ideal platform for the realization of such architectures. Herein, the preparation of a series of open-shell, π-extended Pors that contain magnetically active metal ions (i.e., CuII , CoII , and FeII ) through a combination of in-solution and on-surface synthesis is reported. A detailed study of the magnetic interplay between π- and d-electrons in these metalloPors has been performed by scanning probe methods and density functional theory calculations. For the Cu and FePors, ferromagnetically coupled π-electrons are determined to be delocalized over the Por edges. For the CoPor, the authors find a Kondo resonance resulting from the singly occupied CoII dz 2 orbital to dominate the magnetic fingerprint. The Fe derivative exhibits the highest magnetization of 3.67 μB (S≈2) and an exchange coupling of 16 meV between the π-electrons and the Fe d-states
Electronic decoupling of polyacenes from the underlying metal substrate by sp <sup>3</sup> carbon atoms
We report on the effect of sp3 hybridized carbon atoms in acene derivatives
adsorbed on metal surfaces, namely decoupling the molecules from the supporting
substrates. In particular, we have used a Ag(100) substrate and hydrogenated
heptacene molecules, in which the longest conjugated segment determining its
frontier molecular orbitals amounts to five consecutive rings. The
non-planarity that the sp3 atoms impose on the carbon backbone results in
electronically decoupled molecules, as demonstrated by the presence of charging
resonances in dI/dV tunneling spectra and the associated double tunneling
barriers, or in the Kondo peak that is due to a net spin S=1/2 of the molecule
as its LUMO becomes singly charged. The spatially dependent appearance of the
charging resonances as peaks or dips in the differential conductance spectra is
further understood in terms of the tunneling barrier variation upon molecular
charging, as well as of the different orbitals involved in the tunneling
process
Publisher Correction : Real space manifestations of coherent screening in atomic scale Kondo lattices
Aquesta és una correcció a l'article 10.1038/s41467-019-10103-
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