Nitrogen-Functionalized Graphene Nanoflakes (GNFs:N): Tunable Photoluminescence and Electronic Structures

This study investigates the strong photoluminescence (PL) and X-ray excited optical luminescence observed in nitrogen-functionalized 2D graphene nanoflakes (GNFs:N), which arise from the significantly enhanced density of states in the region of {\pi} states and the gap between {\pi} and {\pi}* states. The increase in the number of the sp2 clusters in the form of pyridine-like N-C, graphite-N-like, and the C=O bonding and the resonant energy transfer from the N and O atoms to the sp2 clusters were found to be responsible for the blue shift and the enhancement of the main PL emission feature. The enhanced PL is strongly related to the induced changes of the electronic structures and bonding properties, which were revealed by the X-ray absorption near-edge structure, X-ray emission spectroscopy, and resonance inelastic X-ray scattering. The study demonstrates that PL emission can be tailored through appropriate tuning of the nitrogen and oxygen contents in GNFs and pave the way for new optoelectronic devices.Comment: 8 pages, 6 figures (including toc figure

Demonstration of a Scalable, Multiplexed Ion Trap for Quantum Information Processing

Author's final manuscript: July 9, 2009A scalable, multiplexed ion trap for quantum information processing is fabricated and tested. The trap design and fabrication process are optimized for scalability to small trap size and large numbers of interconnected traps, and for integration of control electronics and optics. Multiple traps with similar designs are tested with [superscript 111]Cd[superscript +], [superscript 25]Mg[superscript +], and [superscript 88]Sr[superscript +] ions at room temperature and with [superscript 88]Sr[superscript +] at 6 K, with respective ion lifetimes of 90 s, 300 ± 30 s, 56 ± 6 s, and 4.5 ± 1.1 hours. The motional heating rate for [superscript 25]Mg[superscript +] at room temperature and a trap frequency of 1.6 MHz is measured to be 7 ± 3 quanta per millisecond. For [superscript 88]Sr[superscript +] at 6 K and 540 kHz the heating rate is measured to be 220 ± 30 quanta per second.United States. Intelligence Advanced Research Projects ActivityNational Institute of Standards and Technology (U.S.) (Quantum Information Program

Interseismic Deformation and Earthquake Hazard along the Southernmost Longitudinal Valley Fault, Eastern Taiwan

About half of the 8  cm/yr of oblique convergence across the active convergent plate boundaries of Taiwan occurs in eastern Taiwan, across the Longitudinal Valley. Significant shortening and left‐lateral slip occurs across the Longitudinal Valley fault there, both as shallow fault creep and as seismogenic fault slip. The southernmost Longitudinal Valley fault comprises an eastern Peinan strand and a western Luyeh strand. We derive an interseismic block model for these two strands using data from a small‐aperture Global Positioning System (GPS) campaign and leveling. The model provides estimates of fault slip rates and quantifies slip partitioning between the two strands. A 45  mm/yr dip‐slip rate on the northern Peinan strand diminishes southward, whereas the left‐lateral component increases. In contrast, nearly pure dip‐slip motion of about 20  mm/yr on the southern Luyeh strand diminishes northward to about 8  mm/yr and picks up a component of left‐lateral motion of about 15  mm/yr before it dies out altogether at its northern terminus. The Luyeh and the northern Peinan strands record near‐surface creep, but the southern Peinan strand appears locked. The potential earthquake magnitude for the two strands may be as high as M_w 6.5. We anticipate seismic rupture mainly on the locked portion of the Peinan strand

Stochastic Production Of Kink-Antikink Pairs In The Presence Of An Oscillating Background

We numerically investigate the production of kink-antikink pairs in a $(1+1)$ dimensional $\phi^4$ field theory subject to white noise and periodic driving. The twin effects of noise and periodic driving acting in conjunction lead to considerable enhancement in the kink density compared to the thermal equilibrium value, for low dissipation coefficients and for a specific range of frequencies of the oscillating background. The dependence of the kink-density on the temperature of the heat bath, the amplitude of the oscillating background and value of the dissipation coefficient is also investigated. An interesting feature of our result is that kink-antikink production occurs even though the system always remains in the broken symmetry phase.Comment: Revtex, 21 pages including 7 figures; more references adde

Geomorphology of the southernmost Longitudinal Valley fault: Implications for evolution of the active suture of eastern Taiwan

In order to understand fully the deformational patterns of the Longitudinal Valley fault system, a major structure along the eastern suture of Taiwan, we mapped geomorphic features near the southern end of the Longitudinal Valley, where many well‐developed fluvial landforms record deformation along multiple strands of the fault. Our analysis shows that the Longitudinal Valley fault there comprises two major strands. The Luyeh strand, on the west, has predominantly reverse motion. The Peinan strand, on the east, has a significant left‐lateral component. Between the two strands, late Quaternary fluvial sediments and surfaces exhibit progressive deformation. The Luyeh strand dies out to the north, where it steps to the east and joins the Peinan strand to become the main strand of the reverse sinistral Longitudinal Valley fault. To the south, the Luyeh strand becomes an E‐W striking monocline. This suggests that the reverse motion on the Longitudinal Valley system decreases drastically at that point. The Longitudinal Valley fault system is therefore likely to terminate abruptly there and does not seem to connect to any existing structure further to the south. This abrupt structural change suggests that the development of the Longitudinal Valley suture occurs through discrete structural “jumps,” rather than by a continuous northward maturation

Chemical Modification of Graphene Oxide by Nitrogenation: An X-ray Absorption and EmissionSpectroscopy Study

Nitrogen-doped graphene oxides (GO:Nx) were synthesized by a partial reduction of graphene oxide (GO) using urea [CO(NH2)2]. Their electronic/bonding structures were investigated using X-ray absorption near-edge structure (XANES), valence-band photoemission spectroscopy (VB-PES), X-ray emission spectroscopy (XES) and resonant inelastic X-ray scattering (RIXS). During GO:Nx synthesis, different nitrogen-bonding species, such as pyrrolic/graphitic-nitrogen, were formed by replacing of oxygen-containing functional groups. At lower N-content (2.7 at%), pyrrolic-N, owing to surface and subsurface diffusion of C, N and NH is deduced from various X-ray spectroscopies. In contrast, at higher N-content (5.0 at%) graphitic nitrogen was formed in which each N-atom trigonally bonds to three distinct sp2-hybridized carbons with substitution of the N-atoms for C atoms in the graphite layer. Upon nitrogen substitution, the total density of state close to Fermi level is increased to raise the valence-band maximum, as revealed by VB-PES spectra, indicating an electron donation from nitrogen, molecular bonding C/N/O coordination or/and lattice structure reorganization in GO:Nx. The well-ordered chemical environments induced by nitrogen dopant are revealed by XANES and RIXS measurements

Measurement of the Lifetime Difference Between B_s Mass Eigenstates

We present measurements of the lifetimes and polarization amplitudes for B_s --> J/psi phi and B_d --> J/psi K*0 decays. Lifetimes of the heavy (H) and light (L) mass eigenstates in the B_s system are separately measured for the first time by determining the relative contributions of amplitudes with definite CP as a function of the decay time. Using 203 +/- 15 B_s decays, we obtain tau_L = (1.05 +{0.16}/-{0.13} +/- 0.02) ps and tau_H = (2.07 +{0.58}/-{0.46} +/- 0.03) ps. Expressed in terms of the difference DeltaGamma_s and average Gamma_s, of the decay rates of the two eigenstates, the results are DeltaGamma_s/Gamma_s = (65 +{25}/-{33} +/- 1)%, and DeltaGamma_s = (0.47 +{0.19}/-{0.24} +/- 0.01) inverse ps.Comment: 8 pages, 3 figures, 2 tables; as published in Physical Review Letters on 16 March 2005; revisions are for length and typesetting only, no changes in results or conclusion

Measurement of WγW\gamma and ZγZ\gamma Production in ppˉp\bar{p} Collisions at s\sqrt{s} = 1.96 TeV

The Standard Model predictions for $W\gamma$ and $Z\gamma$ production are tested using an integrated luminosity of 200 pb$^{-1}$ of \ppbar collision data collected at the Collider Detector at Fermilab. The cross sections are measured selecting leptonic decays of the $W$ and $Z$ bosons, and photons with transverse energy $E_T>7$ GeV that are well separated from leptons. The production cross sections and kinematic distributions for the $W\gamma$ and $Z\gamma$ are compared to SM predictions.Comment: 7 pages, 4 figures, submitted to PR

Measurement of the ttbar Production Cross Section in ppbar Collisions at sqrt{s}=1.96 TeV using Lepton + Jets Events with Secondary Vertex b-tagging

We present a measurement of the ttbar production cross section using events with one charged lepton and jets from ppbar collisions at a center-of-mass energy of 1.96 TeV. In these events, heavy flavor quarks from top quark decay are identified with a secondary vertex tagging algorithm. From 162 pb-1 of data collected by the Collider Detector at Fermilab, a total of 48 candidate events are selected, where 13.5 +- 1.8 events are expected from background contributions. We measure a ttbar production cross section of 5.6^{+1.2}_{-1.1} (stat.) ^{+0.9}_{0.6} (syst.) pb.Comment: 28 pages, 20 figures. Published in Physical Review

Search for ZZ and ZW Production in ppbar Collisions at sqrt(s) = 1.96 TeV

We present a search for ZZ and ZW vector boson pair production in ppbar collisions at sqrt(s) = 1.96 TeV using the leptonic decay channels ZZ --> ll nu nu, ZZ --> l l l' l' and ZW --> l l l' nu. In a data sample corresponding to an integrated luminosity of 194 pb-1 collected with the Collider Detector at Fermilab, 3 candidate events are found with an expected background of 1.0 +/- 0.2 events. We set a 95% confidence level upper limit of 15.2 pb on the cross section for ZZ plus ZW production, compared to the standard model prediction of 5.0 +/- 0.4 pb.Comment: 7 pages, 2 figures. This version is accepted for publication by Phys. Rev. D Rapid Communication