Anaerobic membrane reactor: Biomethane from chicken manure and high-quality effluent

Chicken manure was treated in a pilot scale reactor anaerobic membrane bioreactor constituted by a completely mixed reactor combined with an ultrafiltration tube-shaped membrane in a side-stream configuration. The process operated under mesophilic condition and the inhibition of high concentration of ammonia was avoided using an ammonia stripping system. The experimental plan included a preliminary evaluation, where organic loading rates between 1.0 and 7.6 kgVS/m3/day were tested. The organic load higher than 4 kgVS/m3/d caused the accumulation of volatile fatty acids and process instability. Application of the ammonia stripping was also evaluated. The best performances were achieved using a retention time of 21 days, an organic load between 1.4 and 2.0 kgVS/m3/d, and the recirculation of stripped permeate. Reduction of the ammonia permeate content by 90% through stripping and utilization of a mixture of chicken manure/water/permeate in a ratio of 0.22/0.72/0.72 w/w led to a specific biogas production of 0.59 m3biogas/kgVS and methane content of 66–69%. The ammonia thus removed can be recovered by sulphuric acid treatment as ammonium sulphate, which can be used as a fertilizer. The proposed configuration allowed satisfactory biogas production with appropriate methane percentages, recovery of ammonium sulphate, and a high-quality effluent

Characterising plasticised cellulose acetate-based historic artefacts by NMR spectroscopy: a new approach for quantifying the degree of substitution and diethyl phthalate contents

As one of the first semi-synthetic plastics produced industrially, cellulose acetate (CA)-based artefacts represent valued items in museum collections and archives which, however, present stability issues. High temperature and relative humidity conditions have long been known to promote changes in CA properties, for instance, due to the deacetylation of CA polymer chains and the loss of plasticiser from the polymer matrix. However, there is a need for improved methods for the quantification of plasticiser loss and CA deacetylation. In this context, this contribution presents a new approach for enabling the investigation of plasticiser loss and deacetylation degradation processes in historic plasticised CA-based artefacts which is based on high-resolution proton nuclear magnetic resonance spectroscopy (1H NMR). The proposed methods allow for simple and fast quantification of diethyl phthalate contents and average degree of substitution (DS), while requiring no need for extractive separation between the plasticiser and the CA polymer matrix prior to analysis. Both methods are demonstrated by their application towards a series of reference samples, historic artefacts and artificially aged plasticised CA materials. Our analysis indicates that plasticiser content and DS can be accurately quantified by using high-resolution 1H NMR and both methods have been compared to analyses performed using infrared spectroscopy

Perspectives of Long-Haul WDM Transmission Systems Based on Phase-Insensitive Fiber-Optic Parametric Amplifiers

International audienceThe deployment of phase-insensitive fiber-optic parametric amplifiers (PI-FOPAs) as inline amplifiers in long-haul WDM transmission systems is discussed, and it is outlined how to design PI-FOPAs to be a valuable upgrade option for this application

Experimental Demonstration of 6-Mode Division Multiplexed NG-PON2: Cost Effective 40 Gbit/s/Spatial-Mode Access Based on 3D Laser Inscribed Photonic Lanterns

We report the first space-division-multiplexed based symmetric NG-PON2 network by efficiently transmitting 40 Gbit/s/spatial-mode. Error free transmission (BER of 10-9) is obtained for all the downstream and upstream data tributaries over 1-km 6-spatial-mode FMF without using MIMO DSP

Nanocellulose/fullerene hybrid films assembled at the air/water interface as promising functional materials for photo-electrocatalysis

Cellulose nanomaterials have been widely investigated in the last decade, unveiling attractive properties for emerging applications. The ability of sulfated cellulose nanocrystals (CNCs) to guide the supramolecular organization of amphiphilic fullerene derivatives at the air/water interface has been recently highlighted. Here, we further investigated the assembly of Langmuir hybrid films that are based on the electrostatic interaction between cationic fulleropyrrolidines deposited at the air/water interface and anionic CNCs dispersed in the subphase, assessing the influence of additional negatively charged species that are dissolved in the water phase. By means of isotherm acquisition and spectroscopic measurements, we demonstrated that a tetra-sulfonated porphyrin, which was introduced in the subphase as anionic competitor, strongly inhibited the binding of CNCs to the floating fullerene layer. Nevertheless, despite the strong inhibition by anionic molecules, the mutual interaction between fulleropyrrolidines at the interface and the CNCs led to the assembly of robust hybrid films, which could be efficiently transferred onto solid substrates. Interestingly, ITO-electrodes that were modified with five-layer hybrid films exhibited enhanced electrical capacitance and produced anodic photocurrents at 0.4 V vs Ag/AgCl, whose intensity (230 nA/cm2) proved to be four times higher than the one that was observed with the sole fullerene derivative (60 nA/cm2)

Changes in medicine course curricula in Brazil encouraged by the Program for the Promotion of Medical School Curricula (PROMED)

<p>Abstract</p> <p>Background</p> <p>The Program for the Promotion of Changes in Medical School Curricula (PROMED) was developed by the Brazilian Ministries of Health and Education. The objective of this program was to finance the implementation of changes to the curricula of medical schools directed towards the Brazilian national healthcare system (SUS). This paper reports research carried out together with the coordinators responsible for the PROMED of each medical school approved, in which interviews were used to evaluate whether this financial support succeeded in stimulating changes. The aim of this study was to evaluate the impact of this program three years after implementation in the universities that received funding.</p> <p>Methods</p> <p>The 19 course coordinators of the medical schools in which the PROMED project was implemented were interviewed using a questionnaire containing 12 questions for qualitative analysis. This paper focuses partially on the reports of the results of this qualitative analysis. Laurence Bardin's.</p> <p>Results</p> <p>The universities interviewed were found to have some common concerns: the decoupling of basic and professional training difficulties in achieving proximity to the network of services; insufficient funding; and the emphasis of most teachers being on teaching hospitals and specialization. These findings indicate that the direction of curriculum reform (PROMED) is toward providing a targeted training for this system.</p> <p>Conclusion</p> <p>The interviewees were aware that this program would trigger future changes in all aspects of healthcare and represents an ongoing challenge to the academic field. PROMED provided the momentum for change in the nature of medical training in Brazil and was seen as powerful enough to override other processes and as a basis for guidance regarding the methodology, pedagogical approach and scenarios of practical experience.</p

Subspace tracking for independent phase noise source separation in frequency combs

Advanced digital signal processing techniques in combination with ultra-wideband balanced coherent detection have enabled a new generation of ultra-high speed fiber-optic communication systems, by moving most of the processing functionalities into digital domain. In this paper, we demonstrate how digital signal processing techniques, in combination with ultra-wideband balanced coherent detection can enable optical frequency comb noise characterization techniques with novel functionalities. We propose a measurement method based on subspace tracking, in combination with multi-heterodyne coherent detection, for independent phase noise sources identification, separation and measurement. Our proposed measurement technique offers several benefits. First, it enables the separation of the total phase noise associated with a particular comb-line or -lines into multiple independent phase noise terms associated with different noise sources. Second, it facilitates the determination of the scaling of each independent phase noise term with comb-line number. Our measurement technique can be used to: identify the most dominant source of phase noise; gain a better understanding of the physics behind the phase noise accumulation process; and confirm, already existing, and enable better phase noise models. In general, our measurement technique provides new insights into noise behavior of optical frequency combs

Treatment of peripheral arterial disease in diabetes: a consensus of the Italian Societies of Diabetes (SID, AMD), Radiology (SIRM) and Vascular Endovascular Surgery (SICVE).

AbstractDiabetic foot (DF) is a chronic and highly disabling complication of diabetes. The prevalence of peripheral arterial disease (PAD) is high in diabetic patients and, associated or not with peripheral neuropathy (PN), can be found in 50% of cases of DF. It is worth pointing out that the number of major amputations in diabetic patients is still very high. Many PAD diabetic patients are not revascularised due to lack of technical expertise or, even worse, negative beliefs because of poor experience. This despite the progress obtained in the techniques of distal revascularisation that nowadays allow to reopen distal arteries of the leg and foot. Italy has one of the lowest prevalence rates of major amputations in Europe, and has a long tradition in the field of limb salvage by means of an aggressive approach in debridement, antibiotic therapy and distal revascularisation. Therefore, we believe it is appropriate to produce a consensus document concerning the treatment of PAD and limb salvage in diabetic patients, based on the Italian experience in this field, to share with the scientific community

Integrating genomic information and productivity and climate-adaptability traits into a regional white spruce breeding program

Tree improvement programs often focus on improving productivity-related traits; however, under present climate change scenarios, climate change-related (adaptive) traits should also be incorporated into such programs. Therefore, quantifying the genetic variation and correlations among productivity and adaptability traits, and the importance of genotype by environment interactions, including defense compounds involved in biotic and abiotic resistance, is essential for selecting parents for the production of resilient and sustainable forests. Here, we estimated quantitative genetic parameters for 15 growth, wood quality, drought resilience, and monoterpene traits for Picea glauca (Moench) Voss (white spruce). We sampled 1,540 trees from three open-pollinated progeny trials, genotyped with 467,224 SNP markers using genotyping-by-sequencing (GBS). We used the pedigree and SNP information to calculate, respectively, the average numerator and genomic relationship matrices, and univariate and multivariate individual-tree models to obtain estimates of (co)variance components. With few site-specific exceptions, all traits examined were under genetic control. Overall, higher heritability estimates were derived from the genomic- than their counterpart pedigree-based relationship matrix. Selection for height, generally, improved diameter and water use efficiency, but decreased wood density, microfibril angle, and drought resistance. Genome-based correlations between traits reaffirmed the pedigree-based correlations for most trait pairs. High and positive genetic correlations between sites were observed (average 0.68), except for those pairs involving the highest elevation, warmer, and moister site, specifically for growth and microfibril angle. These results illustrate the advantage of using genomic information jointly with productivity and adaptability traits, and defense compounds to enhance tree breeding selection for changing climate.Instituto de Recursos BiológicosFil: Cappa, Eduardo Pablo. Instituto Nacional de Tecnología Agropecuaria (INTA). Instituto de Recursos Biológicos; ArgentinaFil: Cappa, Eduardo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Klutsch, Jenifer G. University of Alberta; Department of Renewable Resources; CanadaFil: Sebastian-Azcona, Jaime. University of Alberta; Department of Renewable Resources; CanadaFil: Ratchiffe, Blaise. University of British Columbia. Faculty of Forestry. Department of Forest and Conservation Sciences; CanadáFil: Xiaojing, Wei. University of Alberta; Department of Renewable Resources; CanadaFil: Da Ros, Letitia. University of British Columbia. Faculty of Forestry. Department of Wood Science; CanadáFil: Yang, Liu. University of British Columbia. Faculty of Forestry. Department of Forest and Conservation Sciences; CanadáFil: Chen, Charles. Oklahoma State University. Department of Biochemistry and Molecular Biology; Estados UnidosFil: Benowicz, Andy. Alberta Agriculture and Forestry. Forest Stewardship and Trade Branch; CanadáFil: Sadoway, Shane. Blue Ridge Lumber Inc.; CanadáFil: Mansfield, Shawn D. University of British Columbia. Faculty of Forestry. Department of Wood Science; CanadáFil: Erbilgin, Nadir. University of Alberta; Department of Renewable Resources; CanadaFil: Thomas, Barb R. University of Alberta; Department of Renewable Resources; CanadaFil: El-Kassaby, Yousry A. University of British Columbia. Faculty of Forestry. Department of Forest and Conservation Sciences; Canad