Total Value of Phosphorus Recovery

Phosphorus (P) is a critical, geographically concentrated, nonrenewable resource necessary to support global food production. In excess (e.g., due to runoff or wastewater discharges), P is also a primary cause of eutrophication. To reconcile the simultaneous shortage and overabundance of P, lost P flows must be recovered and reused, alongside improvements in P-use efficiency. While this motivation is increasingly being recognized, little P recovery is practiced today, as recovered P generally cannot compete with the relatively low cost of mined P. Therefore, P is often captured to prevent its release into the environment without beneficial recovery and reuse. However, additional incentives for P recovery emerge when accounting for the total value of P recovery. This article provides a comprehensive overview of the range of benefits of recovering P from waste streams, i.e., the total value of recovering P. This approach accounts for P products, as well as other assets that are associated with P and can be recovered in parallel, such as energy, nitrogen, metals and minerals, and water. Additionally, P recovery provides valuable services to society and the environment by protecting and improving environmental quality, enhancing efficiency of waste treatment facilities, and improving food security and social equity. The needs to make P recovery a reality are also discussed, including business models, bottlenecks, and policy and education strategies

The silicon trypanosome

African trypanosomes have emerged as promising unicellular model organisms for the next generation of systems biology. They offer unique advantages, due to their relative simplicity, the availability of all standard genomics techniques and a long history of quantitative research. Reproducible cultivation methods exist for morphologically and physiologically distinct life-cycle stages. The genome has been sequenced, and microarrays, RNA-interference and high-accuracy metabolomics are available. Furthermore, the availability of extensive kinetic data on all glycolytic enzymes has led to the early development of a complete, experiment-based dynamic model of an important biochemical pathway. Here we describe the achievements of trypanosome systems biology so far and outline the necessary steps towards the ambitious aim of creating a , a comprehensive, experiment-based, multi-scale mathematical model of trypanosome physiology. We expect that, in the long run, the quantitative modelling enabled by the Silicon Trypanosome will play a key role in selecting the most suitable targets for developing new anti-parasite drugs

Application of an improved global-scale groundwater model for water table estimation across New Zealand

Many studies underline the importance of groundwater assessment at the larger, i.e. global, scale. The groundwater models used for these assessments are dedicated to the global scale and therefore not often applied for studies in smaller areas, e.g. catchments, because of their simplifying assumptions. In New Zealand, advanced numerical groundwater flow models have been applied in several catchments. However, that application is piecemeal: only for a limited amount of aquifers and through a variety of groundwater model suites, formats, and developers. Additionally, there are large areas where groundwater models and data are sparse. Hence, an inter-catchment, inter-regional, or nationwide overview of important groundwater information, such as the water table, does not exist. The investment needed to adequately cover New Zealand with high-resolution groundwater models in a consistent approach would be significant and is therefore not considered possible at this stage. This study proposes a solution that obtains a nationwide overview of groundwater that bridges the gap between the (too-)expensive advanced local models and the (too-)simple global-scale models. We apply an existing, global-scale, groundwater flow model and improve it by feeding in national input data of New Zealand terrain, geology, and recharge, and by slight adjustment of model parametrisation and model testing. The resulting nationwide maps of hydraulic head and water table depths show that the model points out the main alluvial aquifers with fine spatial detail (200 m grid resolution). The national input data and finer spatial detail result in better and more realistic variations of water table depth than the original, global-scale, model outputs. In two regional case studies in New Zealand, the hydraulic head shows excellent correlation with the available groundwater level data. Sensitivity and other analyses of our nationwide water tables show that the model is mostly driven by recharge, model resolution, and elevation (gravity), and impeded by the geology (permeability). The use of this first dedicated New Zealand-wide model can aid in provision of water table estimates in data-sparse regions. The national model can also be used to solve inconsistency of models in areas of trans-boundary aquifers, i.e. aquifers that cover more than one region in New Zealand. Comparison of the models, i.e. the national application (National Water Table model: NWT) with the global model (Equilibrium Water Table model: EWT), shows that most improvement is achieved by feeding in better and higher-resolution input data. The NWT model still has a bias towards shallow water tables (but less than the EWT model because of the finer model resolution), which could only be solved by feeding in a very high resolution terrain model that incorporates drainage features. Although this is a model shortcoming, it can also be viewed as a valuable indicator of the pre-human water table, i.e. before 90 % of wetlands were drained for agriculture since European settlement in New Zealand. Calibration to ground-observed water level improves model results but can of course only work where there are such data available. Future research should therefore focus on both model improvements and more data-driven, improved estimation of hydraulic conductivity, recharge, and the digital elevation model. We further surmise that the findings of this study, i.e. successful application of a global-scale model at smaller scales, will lead to subsequent improvement of the global-scale model equationsThis research has been part of a PhD study of the lead author at the University of Waikato, New Zealand, supervised by Moira Steyn-Ross. It has been performed as part of the Smart Aquifer Characterisation (SAC) Programme, funded by the Ministry of Business, Innovation and Employment, New Zealand. This project has received co-funding from the European Union's Seventh Framework Programme for Research and Technological Development under grant agreement no. 603608, eartH2Observe. We furthermore would like to thank the reviewers for their valuable comments, Waikato Regional Council and Environment Canterbury for their ground-observed data used in the results section, and Jeremy White (GNS Science) for his advice on the sensitivity analysesS

Capturing the Lost Phosphorus

Minable phosphorus (P) reserves are being depleted and will need to be replaced by recovering P that currently is lost from the agricultural system, causing water-quality problems. The largest two flows of lost P are in agricultural runoff and erosion (∼46% of mined P globally) and animal wastes (∼40%). These flows are quite distinct. Runoff has a very high volumetric flow rate, but a low P concentration; animal wastes have low flow rates, but a high P concentration together with a high concentration of organic material. Recovering the lost P in animal wastes is technically and economically more tractable, and it is the focus for this review of promising P-capture technologies. P capture requires that organic P be transformed into inorganic P (phosphate). For high-strength animal wastes, P release can be accomplished in tandem with anaerobic treatment that converts the energy value in the organic matter to CH4, H2, or electricity. Once present as phosphate, the P can be captured in a reusable form by four approaches. Most well developed is precipitation as magnesium or calcium solids. Less developed, but promising are adsorption to iron-based adsorbents, ion exchange to phosphate-selective solids, and uptake by photosynthetic microorganisms or P-selective proteins

Total organic halogen (TOX) species formation at different locations in drinking water distribution systems

Total organic chlorine (TOCl), bromine (TOBr) and iodine (TOI) species and collectively total organic halide (TOX) concentrations were quantified quarterly at 11 US drinking water treatment plants (WTPs) and distribution systems. TOCl was the dominant halogen-specific TOX species in most plants. TOBr concentrations varied with source water bromide (Br−) concentrations at WTPs. TOI was always below the minimum reporting level even though iodine species were present at >1 μg L−1 in some source waters. Ratios of TOCl to TOBr varied seasonally. TOCl increased as intake DOC increased in some plants. Seasonal changes in raw water Br− concentration did not lead to the corresponding variations in TOBr concentrations for most WTPs. For WTPs practicing chloramination, TOCl and TOBr concentrations did not increase significantly from the effluent into their distribution systems. Chlorine contact time for both pre-oxidation and post-chlorination prior to ammonia addition was the most important factor affecting the TOX formation in WTPs. On the other hand in distribution systems with free chlorine residuals, TOCl and TOBr concentrations increased as long as residual chlorine was available. Despite seasonal variations, the ratios of regulated brominated disinfection by-products to TOBr (i.e., Br-DBP/TOBr) were lowest for chloraminated plants treating groundwater and generally higher for WTPs utilizing free chlorine. We observed TOBr levels as high as 116 μg L−1 in one distribution system, while the ratio of regulated brominated DBPs to TOBr was as low as 15% in some systems indicating that the major portion of TOBr in the finished water is unidentified and unmeasured. Given the higher toxicity of brominated DBPs than their chlorinated analogs, it is important to develop treatment and/or operational strategies to reduce the formation of TOBr in distribution systems in order to minimize exposure of the public to such DBPs.This study was funded by Water Research Foundation (#4711). The authors are grateful to the project advisory committee members for providing valuable comments for the entire study. We also would like to thank the participating utilities for their support and the plant staff members who assisted in the collection of samples

Observation of High-Energy Astrophysical Neutrinos in Three Years of IceCube Data

A search for high-energy neutrinos interacting within the IceCube detector between 2010 and 2012 provided the first evidence for a high-energy neutrino flux of extraterrestrial origin. Results from an analysis using the same methods with a third year (2012-2013) of data from the complete IceCube detector are consistent with the previously reported astrophysical flux in the 100 TeV - PeV range at the level of $10^{-8}\, \mathrm{GeV}\, \mathrm{cm}^{-2}\, \mathrm{s}^{-1}\, \mathrm{sr}^{-1}$ per flavor and reject a purely atmospheric explanation for the combined 3-year data at $5.7 \sigma$. The data are consistent with expectations for equal fluxes of all three neutrino flavors and with isotropic arrival directions, suggesting either numerous or spatially extended sources. The three-year dataset, with a livetime of 988 days, contains a total of 37 neutrino candidate events with deposited energies ranging from 30 to 2000 TeV. The 2000 TeV event is the highest-energy neutrino interaction ever observed.Comment: 8 pages, 5 figures. Accepted by PRL. The event catalog, event displays, and other data tables are included after the final page of the article. Changed from the initial submission to reflect referee comments, expanding the section on atmospheric backgrounds, and fixes offsets of up to 0.9 seconds in reported event times. Address correspondence to: J. Feintzeig, C. Kopper, N. Whitehor

Search for Prompt Neutrino Emission from Gamma-Ray Bursts with IceCube

We present constraints derived from a search of four years of IceCube data for a prompt neutrino flux from gamma-ray bursts (GRBs). A single low-significance neutrino, compatible with the atmospheric neutrino background, was found in coincidence with one of the 506 observed bursts. Although GRBs have been proposed as candidate sources for ultra-high energy cosmic rays, our limits on the neutrino flux disfavor much of the parameter space for the latest models. We also find that no more than $\sim1\%$ of the recently observed astrophysical neutrino flux consists of prompt emission from GRBs that are potentially observable by existing satellites.Comment: 15 pages, 3 figure

Improved limits on dark matter annihilation in the Sun with the 79-string IceCube detector and implications for supersymmetry

We present an improved event-level likelihood formalism for including neutrino telescope data in global fits to new physics. We derive limits on spin-dependent dark matter-proton scattering by employing the new formalism in a re-analysis of data from the 79-string IceCube search for dark matter annihilation in the Sun, including explicit energy information for each event. The new analysis excludes a number of models in the weak-scale minimal supersymmetric standard model (MSSM) for the first time. This work is accompanied by the public release of the 79-string IceCube data, as well as an associated computer code for applying the new likelihood to arbitrary dark matter models.Comment: 24 pages, 8 figs, 1 table. Contact authors: Pat Scott & Matthias Danninger. Likelihood tool available at http://nulike.hepforge.org. v2: small updates to address JCAP referee repor

Atmospheric and Astrophysical Neutrinos above 1 TeV Interacting in IceCube

The IceCube Neutrino Observatory was designed primarily to search for high-energy (TeV--PeV) neutrinos produced in distant astrophysical objects. A search for $\gtrsim 100$~TeV neutrinos interacting inside the instrumented volume has recently provided evidence for an isotropic flux of such neutrinos. At lower energies, IceCube collects large numbers of neutrinos from the weak decays of mesons in cosmic-ray air showers. Here we present the results of a search for neutrino interactions inside IceCube's instrumented volume between 1~TeV and 1~PeV in 641 days of data taken from 2010--2012, lowering the energy threshold for neutrinos from the southern sky below 10 TeV for the first time, far below the threshold of the previous high-energy analysis. Astrophysical neutrinos remain the dominant component in the southern sky down to 10 TeV. From these data we derive new constraints on the diffuse astrophysical neutrino spectrum, $\Phi_{\nu} = 2.06^{+0.4}_{-0.3} \times 10^{-18} \left({E_{\nu}}/{10^5 \,\, \rm{GeV}} \right)^{-2.46 \pm 0.12} {\rm {GeV^{-1} \, cm^{-2} \, sr^{-1} \, s^{-1}} }$, as well as the strongest upper limit yet on the flux of neutrinos from charmed-meson decay in the atmosphere, 1.52 times the benchmark theoretical prediction used in previous IceCube results at 90\% confidence.Comment: 18 pages, 12 figure

Highlights from the Pierre Auger Observatory

The Pierre Auger Observatory is the world's largest cosmic ray observatory. Our current exposure reaches nearly 40,000 km$^2$ str and provides us with an unprecedented quality data set. The performance and stability of the detectors and their enhancements are described. Data analyses have led to a number of major breakthroughs. Among these we discuss the energy spectrum and the searches for large-scale anisotropies. We present analyses of our X$_{max}$ data and show how it can be interpreted in terms of mass composition. We also describe some new analyses that extract mass sensitive parameters from the 100% duty cycle SD data. A coherent interpretation of all these recent results opens new directions. The consequences regarding the cosmic ray composition and the properties of UHECR sources are briefly discussed.Comment: 9 pages, 12 figures, talk given at the 33rd International Cosmic Ray Conference, Rio de Janeiro 201