Functional properties of sodium and calcium caseinate antimicrobial active films containing carvacrol

Active edible films were prepared by adding carvacrol into sodium caseinate (SC) and calcium caseinate (CC) matrices plasticized with two different glycerol concentrations (25 and 35 wt%) prepared by solvent casting. Functional characterisation of these bio-films was carried out by determination of some of their physico-chemical properties, such as colour, transparency, oxygen barrier, wettability, dye permeation properties and antibacterial effectiveness against Gram negative and Gram positive bacteria. All films exhibited good performance in terms of optical properties in the CIELab space showing high transparency. Carvacrol was able to reduce CC oxygen permeability and slightly increased the surface hydrophobicity. Dye diffusion experiments were performed to evaluate permeation properties. The diffusion of dye through films revealed that SC was more permeable than CC. The agar diffusion method was used for the evaluation of the films antimicrobial effectiveness against Escherichia cell and Staphylococcus aureus. Both SC and CC edible films with carvacrol showed inhibitory effects on both bacteria. (C) 2013 Elsevier Ltd. All rights reserved.This research was supported by the Ministry of Science and Innovation of Spain through the projects MAT2011-28468-C02-01, MAT2011-28468-C02-02 and HP2008-0080. M.P. Arrieta thanks Fundacion MAPFRE for "Ignacio Hernando de Larramendi 2009-Medio Ambiente" fellowship (MAPFRE-IHL-01). Authors thank Ferrer Alimentacion S.A., for providing the caseinates powders.Arrieta, MP.; Peltzer, MA.; López Martínez, J.; Garrigós Selva, MDC.; Valente, AJM.; Jimenez Migallon, A. (2014). Functional properties of sodium and calcium caseinate antimicrobial active films containing carvacrol. Journal of Food Engineering. 121:94-101. https://doi.org/10.1016/j.jfoodeng.2013.08.015S9410112

Ternary Mixtures of Sulfolanes and Ionic Liquids for Use in High-Temperature Supercapacitors

ACS AuthorChoice - This is an open access article published under a Creative Commons Attribution (CC-BY) License, which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.Ionic liquids are a natural choice for supercapacitor electrolytes. However, their cost is currently high. In the present work, we report the use of ternary mixtures of sulfolane, 3-methyl sulfolane, and quaternary ammonium salts (quats) as low-cost alternatives. Sulfolane was chosen because it has a high Hildebrand solubility parameter (δ H = 27.2 MPa 1/2 ) and an exceptionally high dipole moment (μ = 4.7 D), which means that it mixes readily with ionic liquids. It also has a high flash point (165 °C), a high boiling point (285 °C), and a wide two-electrode (full-cell) voltage stability window ( > 7 V). The only problem is its high freezing point (27 °C). However, by using a eutectic mixture of sulfolane with 3-methyl sulfolane, we could depress the freezing point to -17 °C. A second goal of the present work was to increase the electrical conductivity of the electrolyte beyond its present-day value of 2.1 mS cm -1 at 25 °C, currently provided by butyltrimethylammonium bis(trifluoromethylsulfonyl)imide (BTM-TFSI). We explored two methods of doing this: (1) mixing the ionic liquid with the sulfolane eutectic and (2) replacing the low-mobility TFSI anion with the high-mobility MTC anion (methanetricarbonitrile). At the optimum composition, the conductivity reached 12.2 mS cm -1 at 25 °C