34 research outputs found

    A Technology of Multiple Smelting Furnaces per Termite Mound: Iron Production in Chongwe, Lusaka, Zambia

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    With exception of Maluma (1979) and Musambachime (2016, 2017), there have been no archaeometallurgical publications on the technology and culture of iron production in Zambia. This paper presents archaeological and archaeometallurgical evidence of a technology of iron production in Chongwe in terms of spatial organization, the process of metal production (either a three-stage process involving smelting in relatively tall furnaces, refining in miniature (vintengwe) furnaces, and smithing on a hearth or a two-stage process involving smelting and smithing), furnace air supply mechanisms, liquid slag handling techniques, variation in the geochemistry of ore and clay, and the nature of the final smelting products. Archaeological field data collection techniques included ethnoarchaeological interviews, (furnace) excavation, surface collections, and surface walkover surveys, while laboratory analytical techniques included optical microscopy (OM), scanning electron microscopy (SEM), and x-ray fluorescence (XRF). New field evidence indicates that iron production in Chongwe in the previous two centuries was secluded from respective pre-modern settlements for socio-cultural and technical reasons. There are no settlement remains in and around Chongwe smelting sites. Also, most of the archaeological data in Chongwe are supportive of the two-stage process that did not involve iron refining in vintengwe furnaces. There were no iron refining sites in Chongwe. Archaeological evidence also strongly points to the use of natural air supply mechanism for the smelting furnaces because proximal ends of tuyĂšres inter alia were not trumpeted. All smelting sites were systematically located on termite mounds. There were three to four smelting furnaces located on the western side of a termite mound. The presence of tuyĂšre mould slags and thin and elongated slag microstructures strongly indicates that liquid slag was tapped outside the furnace apparently through tuyĂšres and was left to cool quickly. Presence of primary wĂŒstite and iron particles in the slags strongly suggests the production of iron as the final smelting product in Chongwe. The results are compared with the archaeology, chemistry, and mineralogy of iron production from other parts of sub-Saharan Africa, particularly in the Lake Tanganyika-Nyasa Corridor. The presence of three to four smelting furnaces per termite mound makes iron production in Chongwe a unique technology in the Corridor

    Hf–Zr anomalies in clinopyroxene from mantle xenoliths from France and Poland: implications for Lu–Hf dating of spinel peridotite lithospheric mantle

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    Clinopyroxenes in some fresh anhydrous spinel peridotite mantle xenoliths from the northern Massif Central (France) and Lower Silesia (Poland), analysed for a range of incompatible trace elements by laser ablation inductively coupled plasma mass spectrometry, show unusually strong negative anomalies in Hf and Zr relative to adjacent elements Sm and Nd, on primitive mantle-normalised diagrams. Similar Zr–Hf anomalies have only rarely been reported from clinopyroxene in spinel peridotite mantle xenoliths worldwide, and most are not as strong as the examples reported here. Low Hf contents give rise to a wide range of Lu/Hf ratios, which over geological time would result in highly radiogenic ΔHf values, decoupling them from ΔNd ratios. The high 176Lu/177Hf could in theory produce an isochronous relationship with 176Hf/177Hf over time; an errorchron is shown by clinopyroxene from mantle xenoliths from the northern Massif Central. However, in a review of the literature, we show that most mantle spinel peridotites do not show such high Lu/Hf ratios in their constituent clinopyroxenes, because they lack the distinctive Zr–Hf anomaly, and this limits the usefulness of the application of the Lu–Hf system of dating to garnet-free mantle rocks. Nevertheless, some mantle xenoliths from Poland or the Czech Republic may be amenable to Hf-isotope dating in the future

    A new method of discriminating different types of post-Archean ophiolitic basalts and their tectonic significance using Th-Nb and Ce-Dy-Yb systematics

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    AbstractIn this paper, a new discrimination diagram using absolute measures of Th and Nb is applied to post-Archean ophiolites to best discriminate a large number of different ophiolitic basalts. This diagram was obtained using >2000 known ophiolitic basalts and was tested using ∌560 modern rocks from known tectonic settings. Ten different basaltic varieties from worldwide ophiolitic complexes have been examined. They include two basaltic types that have never been considered before, which are: (1) medium-Ti basalts (MTB) generated at nascent forearc settings; (2) a type of mid-ocean ridge basalts showing garnet signature (G-MORB) that characterizes Alpine-type (i.e., non volcanic) rifted margins and ocean-continent transition zones (OCTZ). In the Th-Nb diagram, basalts generated in oceanic subduction-unrelated settings, rifted margins, and OCTZ can be distinguished from subduction-related basalts with a misclassification rate <1%. This diagram highlights the chemical variation of oceanic, rifted margin, and OCTZ basalts from depleted compositions to progressively more enriched compositions reflecting, in turn, the variance of source composition and degree of melting within the MORB-OIB array. It also highlights the chemical contributions of enriched (OIB-type) components to mantle sources. Enrichment of Th relative to Nb is particularly effective for highlighting crustal input via subduction or crustal contamination. Basalts formed at continental margin arcs and island arc with a complex polygenetic crust can be distinguished from those generated in intra-oceanic arcs in supra-subduction zones (SSZ) with a misclassification rate <1%. Within the SSZ group, two sub-settings can be recognized with a misclassification rate <0.5%. They are: (1) SSZ influenced by chemical contribution from subduction-derived components (forearc and intra-arc sub-settings) characterized by island arc tholeiitic (IAT) and boninitic basalts; (2) SSZ with no contribution from subduction-derived components (nascent forearc sub-settings) characterized by MTBs and depleted-MORBs. Two additional discrimination diagrams are proposed: (1) a Dy-Yb diagram is used for discriminating boninite and IAT basalts; (2) a Ce/Yb-Dy/Yb diagram is used for discriminating G-MORBs and normal MORBs. The proposed method may effectively assist in recovering the tectonic affinity of ancient ophiolites, which is fundamental for establishing the geodynamic evolution of ancient oceanic and continental domains, as well as orogenic belts

    The isolated pancreatic islet as a micro-organ and its transplantation to cure diabetes: Celebrating the legacy of Paul Lacy

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    Over the past three decades the pancreatic islet of Langerhans has taken center stage as an endocrine microorgan whose glucoregulatory function is highly explicable on the basis of the increasingly well understood activities of three highly interactive secretory cells. Islet dysfunction underlies both type 1 and type 2 diabetes mellitus (DM); its protection from immune attack and gluco-and lipo-toxicity may prevent the development of DM; and its replacement by non-surgical transplantation may be curative of DM. During a career marked by vision, focus and tenacity, Paul Lacy contributed substantially to the development of each of these concepts. In this review we focus on Lacy's contribution to the development of the concept of the islet as a micro-organ, how this foreshadowed our current detailed understanding of single cell function and cell-cell interactions and how this led to a reduced model of islet function encouraging islet transplantation. Next, we examine how clinical allotransplantation, first undertaken by Lacy, has contributed to a more complex view of the interaction of islet endocrine cells with its circulation and neighboring tissues, both “in situ” and after transplantation. Lastly, we consider recent developments in some alternative approaches to treatment of DM that Lacy could glimpse on the horizon but did not have the chance to participate in
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