307 research outputs found
What causes the irregular cycle of the atmospheric tape recorder signal in HCN?
Variations in the mixing ratio of long-lived trace gases entering the stratosphere in the tropics are carried upward with the rising air with the signal being observable throughout the tropical lower stratosphere. This phenomenon, referred to as "atmospheric tape recorder" has previously been observed for water vapor, CO2, and CO which exhibit an annual cycle. Recently, based on Microwave Limb Sounder (MLS) and the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) satellite measurements, the tape recorder signal has been observed for hydrogen cyanide (HCN) but with an approximately two-year period. Here we report on a model simulation of the HCN tape recorder for the time period 2002-2008 using the Chemical Lagrangian Model of the Stratosphere (CLaMS). The model can reproduce the observed pattern of the HCN tape recorder signal if time-resolved emissions from fires in Indonesia are used as lower boundary condition. This finding indicates that inter-annual variations in biomass burning in Indonesia, which are strongly influenced by El Nino events, control the HCN tape recorder signal. A longer time series of tropical HCN data will probably exhibit an irregular cycle rather than a regular biannual cycle. Citation: Pommrich, R., R. Muller, J.-U. Grooss, G. Gunther, P. Konopka, M. Riese, A. Heil, M. Schultz, H.-C. Pumphrey, and K. A. Walker (2010), What causes the irregular cycle of the atmospheric tape recorder signal in HCN?, Geophys. Res. Lett., 37, L16805, doi:10.1029/2010GL044056
A linear CO chemistry parameterization in a chemistry-transport model: evaluation and application to data assimilation
This paper presents an evaluation of a new linear parameterization valid for the troposphere and the stratosphere, based on a first order approximation of the carbon monoxide (CO) continuity equation. This linear scheme (hereinafter noted LINCO) has been implemented in the 3-D Chemical Transport Model (CTM) MOCAGE (MOdèle de Chimie Atmospherique Grande Echelle). First, a one and a half years of LINCO simulation has been compared to output obtained from a detailed chemical scheme output. The mean differences between both schemes are about ±25 ppbv (part per billion by volume) or 15% in the troposphere and ±10 ppbv or 100% in the stratosphere. Second, LINCO has been compared to diverse observations from satellite instruments covering the troposphere (Measurements Of Pollution In The Troposphere: MOPITT) and the stratosphere (Microwave Limb Sounder: MLS) and also from aircraft (Measurements of ozone and water vapour by Airbus in-service aircraft: MOZAIC programme) mostly flying in the upper troposphere and lower stratosphere (UTLS). In the troposphere, the LINCO seasonal variations as well as the vertical and horizontal distributions are quite close to MOPITT CO observations. However, a bias of ~−40 ppbv is observed at 700 Pa between LINCO and MOPITT. In the stratosphere, MLS and LINCO present similar large-scale patterns, except over the poles where the CO concentration is underestimated by the model. In the UTLS, LINCO presents small biases less than 2% compared to independent MOZAIC profiles. Third, we assimilated MOPITT CO using a variational 3D-FGAT (First Guess at Appropriate Time) method in conjunction with MOCAGE for a long run of one and a half years. The data assimilation greatly improves the vertical CO distribution in the troposphere from 700 to 350 hPa compared to independent MOZAIC profiles. At 146 hPa, the assimilated CO distribution is also improved compared to MLS observations by reducing the bias up to a factor of 2 in the tropics. This study confirms that the linear scheme is able to simulate reasonably well the CO distribution in the troposphere and in the lower stratosphere. Therefore, the low computing cost of the linear scheme opens new perspectives to make free runs and CO data assimilation runs at high resolution and over periods of several years
Coincidence isometries of a shifted square lattice
We consider the coincidence problem for the square lattice that is translated
by an arbitrary vector. General results are obtained about the set of
coincidence isometries and the coincidence site lattices of a shifted square
lattice by identifying the square lattice with the ring of Gaussian integers.
To illustrate them, we calculate the set of coincidence isometries, as well as
generating functions for the number of coincidence site lattices and
coincidence isometries, for specific examples.Comment: 10 pages, 1 figure; paper presented at Aperiodic 2009 (Liverpool
Grain boundary energies and cohesive strength as a function of geometry
Cohesive laws are stress-strain curves used in finite element calculations to
describe the debonding of interfaces such as grain boundaries. It would be
convenient to describe grain boundary cohesive laws as a function of the
parameters needed to describe the grain boundary geometry; two parameters in 2D
and 5 parameters in 3D. However, we find that the cohesive law is not a smooth
function of these parameters. In fact, it is discontinuous at geometries for
which the two grains have repeat distances that are rational with respect to
one another. Using atomistic simulations, we extract grain boundary energies
and cohesive laws of grain boundary fracture in 2D with a Lennard-Jones
potential for all possible geometries which can be simulated within periodic
boundary conditions with a maximum box size. We introduce a model where grain
boundaries are represented as high symmetry boundaries decorated by extra
dislocations. Using it, we develop a functional form for the symmetric grain
boundary energies, which have cusps at all high symmetry angles. We also find
the asymptotic form of the fracture toughness near the discontinuities at high
symmetry grain boundaries using our dislocation decoration model.Comment: 12 pages, 19 figures, changed titl
The High Arctic in Extreme Winters: Vortex, Temperature, and MLS and ACE-FTS Trace Gas Evolution
The first three Canadian Arctic Atmospheric Chemistry Experiment (ACE) Validation Campaigns at Eureka (80° N, 86° W) were during two extremes of Arctic winter variability: Stratospheric sudden warmings (SSWs) in 2004 and 2006 were among the strongest, most prolonged on record; 2005 was a record cold winter. New satellite measurements from ACE-Fourier Transform Spectrometer (ACE-FTS), Sounding of the Atmosphere using Broadband Emission Radiometry, and Aura Microwave Limb Sounder (MLS), with meteorological analyses and Eureka lidar and radiosonde temperatures, are used to detail the meteorology in these winters, to demonstrate its influence on transport and chemistry, and to provide a context for interpretation of campaign observations. During the 2004 and 2006 SSWs, the vortex broke down throughout the stratosphere, reformed quickly in the upper stratosphere, and remained weak in the middle and lower stratosphere. The stratopause reformed at very high altitude, above where it could be accurately represented in the meteorological analyses. The 2004 and 2006 Eureka campaigns were during the recovery from the SSWs, with the redeveloping vortex over Eureka. 2005 was the coldest winter on record in the lower stratosphere, but with an early final warming in mid-March. The vortex was over Eureka at the start of the 2005 campaign, but moved away as it broke up. Disparate temperature profile structure and vortex evolution resulted in much lower (higher) temperatures in the upper (lower) stratosphere in 2004 and 2006 than in 2005. Satellite temperatures agree well with Eureka radiosondes, and with lidar data up to 50–60 km. Consistent with a strong, cold upper stratospheric vortex and enhanced radiative cooling after the SSWs, MLS and ACE-FTS trace gas measurements show strongly enhanced descent in the upper stratospheric vortex during the 2004 and 2006 Eureka campaigns compared to that in 2005
The atomic structure of large-angle grain boundaries and in and their transport properties
We present the results of a computer simulation of the atomic structures of
large-angle symmetrical tilt grain boundaries (GBs) (misorientation
angles \q{36.87}{^{\circ}} and \q{53.13}{^{\circ}}),
(misorientation angles \q{22.62}{^{\circ}} and \q{67.38}{^{\circ}}). The
critical strain level criterion (phenomenological criterion)
of Chisholm and Pennycook is applied to the computer simulation data to
estimate the thickness of the nonsuperconducting layer enveloping
the grain boundaries. The is estimated also by a bond-valence-sum
analysis. We propose that the phenomenological criterion is caused by the
change of the bond lengths and valence of atoms in the GB structure on the
atomic level. The macro- and micro- approaches become consistent if the
is greater than in earlier papers. It is predicted that the
symmetrical tilt GB \theta = \q{53.13}{^{\circ}} should demonstrate
a largest critical current across the boundary.Comment: 10 pages, 2 figure
Validation of Aura Microwave Limb Sounder O-3 and CO observations in the upper troposphere and lower stratosphere
International audienceGlobal satellite observations of ozone and carbon monoxide from the Microwave Limb Sounder (MLS) on the EOS Aura spacecraft are discussed with emphasis on those observations in the 215–100 hPa region (the upper troposphere and lower stratosphere). The precision, resolution and accuracy of the data produced by the MLS “version 2.2” processing algorithms are discussed and quantified. O3 accuracy is estimated at ~40 ppbv +5% (~20 ppbv +20% at 215 hPa) while the CO accuracy is estimated at ~30 ppbv +30% for pressures of 147 hPa and less. Comparisons with expectations and other observations show good agreements for the O3 product, generally consistent with the systematic errors quoted above. In the case of CO, a persistent factor of ~2 high bias is seen at 215 hPa. However, the morphology is shown to be realistic, consistent with raw MLS radiance data, and useful for scientific study. The MLS CO data at higher altitudes are shown to be consistent with other observations
Fatal outcome of a hypersensitivity reaction to paclitaxel: a critical review of premedication regimens
Hypersensitivity reactions (HSRs) to paclitaxel are frequently encountered in patients receiving this antitumour drug. Administration of histamine H1- and H2-receptor antagonists and corticosteroids has been shown to reduce significantly the risk of developing an HSR in patients receiving taxanes. In this case report, we describe the fatal outcome of an HSR in a patient receiving paclitaxel despite short-course premedication. The level of evidence supporting the short-course i.v. premedication schedule is challenged, as it is not compatible with the pharmacokinetic properties of dexamethasone
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