Simulated seasonal impact on middle atmospheric ozone from high-energy electron precipitation related to pulsating aurorae

Recent simulation studies have provided evidence that a pulsating aurora (PsA) associated with high-energy electron precipitation is having a clear local impact on ozone chemistry in the polar middle mesosphere. However, it is not clear if the PsA is frequent enough to cause longer-term effects of measurable magnitude. There is also an open question of the relative contribution of PsA-related energetic electron precipitation (PsA EEP) to the total atmospheric forcing by solar energetic particle precipitation (EPP). Here we investigate the PsA-EEP impact on stratospheric and mesospheric odd hydrogen, odd nitrogen, and ozone concentrations. We make use of the Whole Atmosphere Community Climate Model and recent understanding on PsA frequency, latitudinal and magnetic local time extent, and energy-flux spectra. Analysing an 18-month time period covering all seasons, we particularly look at PsA-EEP impacts at two polar observation stations located at opposite hemispheres: Tromsø in the Northern Hemisphere (NH) and Halley Research Station in the Southern Hemisphere (SH). We find that PsA EEP can have a measurable impact on ozone concentration above 30 km altitude, with ozone depletion by up to 8 % seen in winter periods due to PsA-EEP-driven NOx enhancement. We also find that direct mesospheric NOx production by high-energy electrons (E> 100 keV) accounts for about half of the PsA-EEP-driven upper stratospheric ozone depletion. A larger PsA-EEP impact is seen in the SH where the background dynamical variability is weaker than in the NH. Clearly indicated from our results, consideration of polar vortex dynamics is required to understand PsA-EEP impacts seen at ground observation stations, especially in the NH. We conclude that PsA-EEP has the potential to make an important contribution to the total EPP forcing; thus, it should be considered in atmospheric and climate simulations.publishedVersio

WACCM-D Whole Atmosphere Community Climate Model with D-region ion chemistry

Energetic particle precipitation (EPP) and ion chemistry affect the neutral composition of the polar middle atmosphere. For example, production of odd nitrogen and odd hydrogen during strong events can decrease ozone by tens of percent. However, the standard ion chemistry parameterization used in atmospheric models neglects the effects on some important species, such as nitric acid. We present WACCM-D, a variant of the Whole Atmosphere Community Climate Model, which includes a set of lower ionosphere (D-region) chemistry: 307 reactions of 20 positive ions and 21 negative ions. We consider realistic ionization scenarios and compare the WACCM-D results to those from the Sodankylä Ion and Neutral Chemistry (SIC), a state-of-the-art 1-D model of the D-region chemistry. We show that WACCM-D produces well the main characteristics of the D-region ionosphere, as well as the overall proportion of important ion groups, in agreement with SIC. Comparison of ion concentrations shows that the WACCM-D bias is typically within ±10% or less below 70 km. At 70–90 km, when strong altitude gradients in ionization rates and/or ion concentrations exist, the bias can be larger for some groups but is still within tens of percent. Based on the good agreement overall and the fact that part of the differences are caused by different model setups, WACCM-D provides a state-of-the-art global representation of D-region ion chemistry and is therefore expected to improve EPP modeling considerably. These improvements are demonstrated in a companion paper by Andersson et al

Missing driver in the Sun–Earth connection from energetic electron precipitation impacts mesospheric ozone

Energetic electron precipitation (EEP) from the Earth’s outer radiation belt continuously affects the chemical composition of the polar mesosphere. EEP can contribute to catalytic ozone loss in the mesosphere through ionization and enhanced production of odd hydrogen. However, the long-term mesospheric ozone variability caused by EEP has not been quantified or confirmed to date. Here we show, using observations from three different satellite instruments, that EEP events strongly affect ozone at 60–80 km, leading to extremely large (up to 90%) short-term ozone depletion. This impact is comparable to that of large, but much less frequent, solar proton events. On solar cycle timescales, we find that EEP causes ozone variations of up to 34% at 70–80 km. With such a magnitude, it is reasonable to suspect that EEP could be an important part of solar influence on the atmosphere and climate syste

Retrieval of ozone profiles from GOMOS limb scattered measurements

The GOMOS (Global Ozone Monitoring by Occultation of Stars) instrument on board the Envisat satellite measures the vertical composition of the atmosphere using the stellar occultation technique. While the night-time occultations of GOMOS have been proven to be of good quality, the daytime occultations are more challenging due to weaker signal-to-noise ratio. During daytime GOMOS measures limb scattered solar radiation in addition to stellar radiation. In this paper we introduce a retrieval method that determines ozone profiles between 20–60 km from GOMOS limb scattered solar radiances. GOMOS observations contain a considerable amount of stray light at high altitudes. We introduce a method for removing stray light and demonstrate its feasibility by comparing the corrected radiances against those measured by the OSIRIS (Optical Spectrograph & Infra Red Imaging System) instrument. For the retrieval of ozone profiles, a standard onion peeling method is used. The first comparisons with other data sets suggest that the retrieved ozone profiles in 22–50 km are within 10% compared with the GOMOS night-time occultations and within 15% compared with OSIRIS. GOMOS has measured about 350 000 daytime profiles since 2002. The retrieval method presented here makes this large amount of data available for scientific use

Substorm-induced energetic electron precipitation:impact on atmospheric chemistry

Magnetospheric substorms drive energetic electron precipitation into the Earth's atmosphere. We use the output from a substorm model to describe electron precipitation forcing of the atmosphere during an active substorm period in April–May 2007. We provide the first estimate of substorm impact on the neutral composition of the polar middle atmosphere. Model simulations show that the enhanced ionization from a series of substorms leads to an estimated ozone loss of 5–50% in the mesospheric column depending on season. This is similar in scale to small to medium solar proton events (SPEs). This effect on polar ozone balance is potentially more important on long time scales (months to years) than the impulsive but sporadic (few SPE/year versus three to four substorms/day) effect of SPEs. Our results suggest that substorms should be considered an important source of energetic particle precipitation into the atmosphere and included in high-top chemistry-climate models

Parameterisation of the chemical effects of sprites in the middle atmosphere

Transient luminous events, such as red sprites, occur in the middle atmosphere in the electric field above thunderstorms. We here address the question whether these processes may be a significant source of odd nitrogen and affect ozone or other important trace species. A well-established coupled ion-neutral chemical model has been extended for this purpose and applied together with estimated rates of ionisation, excitation and dissociation based on spectroscopic ratios from ISUAL on FORMOSAT-2. This approach is used to estimate the NO<sub>x</sub> and ozone changes for two type cases. <br><br> The NO<sub>x</sub> enhancements are at most one order of magnitude in the streamers, which means a production of at most 10 mol per event, or (given a global rate of occurrence of three events per minute) some 150–1500 kg per day. The present study therefore indicates that sprites are insignificant as a global source of NO<sub>x</sub>. Local effects on ozone are also negligible, but the local enhancement of NO<sub>x</sub> may be significant, up to 5 times the minimum background at 70 km in extraordinary cases

Heppa III Intercomparison Experiment on Electron Precipitation Impacts: 2. Model‐Measurement Intercomparison of Nitric Oxide (NO) During a Geomagnetic Storm in April 2010

Precipitating auroral and radiation belt electrons are considered to play an important part in the natural forcing of the middle atmosphere with a possible impact on the climate system. Recent studies suggest that this forcing is underestimated in current chemistry-climate models. The HEPPA III intercomparison experiment is a collective effort to address this point. In this study, we apply electron ionization rates from three data-sets in four chemistry-climate models during a geomagnetically active period in April 2010. Results are evaluated by comparison with observations of nitric oxide (NO) in the mesosphere and lower thermosphere. Differences between the ionization rate data-sets have been assessed in a companion study. In the lower thermosphere, NO densities differ by up to one order of magnitude between models using the same ionization rate data-sets due to differences in the treatment of NO formation, model climatology, and model top height. However, a good agreement in the spatial and temporal variability of NO with observations lends confidence that the electron ionization is represented well above 80 km. In the mesosphere, the averages of model results from all chemistry-climate models differ consistently with the differences in the ionization-rate data-sets, but are within the spread of the observations, so no clear assessment on their comparative validity can be provided. However, observed enhanced amounts of NO in the mid-mesosphere below 70 km suggest a relevant contribution of the high-energy tail of the electron distribution to the hemispheric NO budget during and after the geomagnetic storm on April 6

HEPPA III Intercomparison Experiment on Electron Precipitation Impacts: 1. Estimated Ionization Rates During a Geomagnetic Active Period in April 2010

Precipitating auroral and radiation belt electrons are considered an important part of the natural forcing of the climate system. Recent studies suggest that this forcing is underestimated in current chemistry-climate models. The High Energy Particle Precipitation in the Atmosphere III intercomparison experiment is a collective effort to address this point. Here, eight different estimates of medium energy electron (MEE) (urn:x-wiley:21699380:media:jgra56926:jgra56926-math-0001) ionization rates are assessed during a geomagnetic active period in April 2010. The objective is to understand the potential uncertainty related to the MEE energy input. The ionization rates are all based on the Medium Energy Proton and Electron Detector (MEPED) on board the NOAA/POES and EUMETSAT/MetOp spacecraft series. However, different data handling, ionization rate calculations, and background atmospheres result in a wide range of mesospheric electron ionization rates. Although the eight data sets agree well in terms of the temporal variability, they differ by about an order of magnitude in ionization rate strength both during geomagnetic quiet and disturbed periods. The largest spread is found in the aftermath of enhanced geomagnetic activity. Furthermore, governed by different energy limits, the atmospheric penetration depth varies, and some differences related to latitudinal coverage are also evident. The mesospheric NO densities simulated with the Whole Atmospheric Community Climate Model driven by highest and lowest ionization rates differ by more than a factor of eight. In a follow-up study, the atmospheric responses are simulated in four chemistry-climate models (CCM) and compared to satellite observations, considering both the CCM structure and the ionization forcing

HEPPA-II model-measurement intercomparison project : EPP indirect effects during the dynamically perturbed NH winter 2008-2009

We compare simulations from three high-top (with upper lid above 120 km) and five medium-top (with upper lid around 80 km) atmospheric models with observations of odd nitrogen (NOx D NO+NO2), temperature, and carbon monoxide from seven satellite instruments (ACE-FTS on SciSat, GOMOS, MIPAS, and SCIAMACHY on Envisat, MLS on Aura, SABER on TIMED, and SMR on Odin) during the Northern Hemisphere (NH) polar winter 2008/2009. The models included in the comparison are the 3-D chemistry transport model 3dCTM, the ECHAM5/MESSy Atmospheric Chemistry (EMAC) model, FinROSE, the Hamburg Model of the Neutral and Ionized Atmosphere (HAMMO-NIA), the Karlsruhe Simulation Model of the Middle Atmosphere (KASIMA), the modelling tools for SOlar Climate Ozone Links studies (SOCOL and CAO-SOCOL), and the Whole Atmosphere Community Climate Model (WACCM4). The comparison focuses on the energetic particle precipitation (EPP) indirect effect, that is, the polar winter descent of NOx largely produced by EPP in the mesosphere and lower thermosphere. A particular emphasis is given to the impact of the sudden stratospheric warming (SSW) in January 2009 and the subsequent elevated stratopause (ES) event associated with enhanced descent of mesospheric air. The chemistry climate model simulations have been nudged toward reanalysis data in the troposphere and stratosphere while being unconstrained above. An odd nitrogen upper boundary condition obtained from MIPAS observations has further been applied to medium-top models. Most models provide a good representation of the mesospheric tracer descent in general, and the EPP indirect effect in particular, during the unperturbed (pre-SSW) period of the NH winter 2008/2009. The observed NOx descent into the lower mesosphere and stratosphere is generally reproduced within 20 %. Larger discrepancies of a few model simulations could be traced back either to the impact of the models' gravity wave drag scheme on the polar wintertime meridional circulation or to a combination of prescribed NOx mixing ratio at the uppermost model layer and low vertical resolution. In March-April, after the ES event, however, modelled mesospheric and stratospheric NOx distributions deviate significantly from the observations. The too-fast and early downward propagation of the NO x tongue, encountered in most simulations, coincides with a temperature high bias in the lower mesosphere (0.2-0.05 hPa), likely caused by an overestimation of descent velocities. In contrast, upper-mesospheric temperatures (at 0.05-0.001 hPa) are generally underestimated by the high-top models after the onset of the ES event, being indicative for too-slow descent and hence too-low NOx fluxes. As a consequence, the magnitude of the simulated NOx tongue is generally underestimated by these models. Descending NOx amounts simulated with mediumtop models are on average closer to the observations but show a large spread of up to several hundred percent. This is primarily attributed to the different vertical model domains in which the NOx upper boundary condition is applied. In general, the intercomparison demonstrates the ability of state-of- the-art atmospheric models to reproduce the EPP indirect effect in dynamically and geomagnetically quiescent NH winter conditions. The encountered differences between observed and simulated NOx, CO, and temperature distributions during the perturbed phase of the 2009 NH winter, however, emphasize the need for model improvements in the dynamical representation of elevated stratopause events in order to allow for a better description of the EPP indirect effect under these particular conditions.Peer reviewe