Slippage of water past superhydrophobic carbon nanotube forests in microchannels

We present in this letter an experimental characterization of liquid flow slippage over superhydrophobic surfaces made of carbon nanotube forests, incorporated in microchannels. We make use of a micro-PIV (Particule Image Velocimetry) technique to achieve the submicrometric resolution on the flow profile necessary for accurate measurement of the surface hydrodynamic properties. We demonstrate boundary slippage on the Cassie superhydrophobic state, associated with slip lengths of a few microns, while a vanishing slip length is found in the Wenzel state, when the liquid impregnates the surface. Varying the lateral roughness scale L of our carbon nanotube forest-based superhydrophobic surfaces, we demonstrate that the slip length varies linearly with L in line with theoretical predictions for slippage on patterned surfaces.Comment: under revie

Microscopic Derivation of Non-Markovian Thermalization of a Brownian Particle

In this paper, the first microscopic approach to the Brownian motion is developed in the case where the mass density of the suspending bath is of the same order of magnitude as that of the Brownian (B) particle. Starting from an extended Boltzmann equation, which describes correctly the interaction with the fluid, we derive systematicaly via the multiple time-scale analysis a reduced equation controlling the thermalization of the B particle, i.e. the relaxation towards the Maxwell distribution in velocity space. In contradistinction to the Fokker-Planck equation, the derived new evolution equation is non-local both in time and in velocity space, owing to correlated recollision events between the fluid and particle B. In the long-time limit, it describes a non-markovian generalized Ornstein-Uhlenbeck process. However, in spite of this complex dynamical behaviour, the Stokes-Einstein law relating the friction and diffusion coefficients is shown to remain valid. A microscopic expression for the friction coefficient is derived, which acquires the form of the Stokes law in the limit where the mean-free in the gas is small compared to the radius of particle B.Comment: 28 pages, no figure, submitted to Journal of Statistical Physic

Diffusion in pores and its dependence on boundary conditions

We study the influence of the boundary conditions at the solid liquid interface on diffusion in a confined fluid. Using an hydrodynamic approach, we compute numerical estimates for the diffusion of a particle confined between two planes. Partial slip is shown to significantly influence the diffusion coefficient near a wall. Analytical expressions are derived in the low and high confinement limits, and are in good agreement with numerical results. These calculations indicate that diffusion of tagged particles could be used as a sensitive probe of the solid-liquid boundary conditions.Comment: soumis \`a J.Phys. Cond. Matt. special issue on "Diffusion in Liquids, Polymers, Biophysics and Chemical Dynamics

On the fluid-fluid phase separation in charged-stabilized colloidal suspensions

We develop a thermodynamic description of particles held at a fixed surface potential. This system is of particular interest in view of the continuing controversy over the possibility of a fluid-fluid phase separation in aqueous colloidal suspensions with monovalent counterions. The condition of fixed surface potential allows in a natural way to account for the colloidal charge renormalization. In a first approach, we assess the importance of the so called ``volume terms'', and find that in the absence of salt, charge renormalization is sufficient to stabilize suspension against a fluid-fluid phase separation. Presence of salt, on the other hand, is found to lead to an instability. A very strong dependence on the approximations used, however, puts the reality of this phase transition in a serious doubt. To further understand the nature of the instability we next study a Jellium-like approximation, which does not lead to a phase separation and produces a relatively accurate analytical equation of state for a deionized suspensions of highly charged colloidal spheres. A critical analysis of various theories of strongly asymmetric electrolytes is presented to asses their reliability as compared to the Monte Carlo simulations

WhiskyMHD: a new numerical code for general relativistic magnetohydrodynamics

The accurate modelling of astrophysical scenarios involving compact objects and magnetic fields, such as the collapse of rotating magnetized stars to black holes or the phenomenology of gamma-ray bursts, requires the solution of the Einstein equations together with those of general-relativistic magnetohydrodynamics. We present a new numerical code developed to solve the full set of general-relativistic magnetohydrodynamics equations in a dynamical and arbitrary spacetime with high-resolution shock-capturing techniques on domains with adaptive mesh refinements. After a discussion of the equations solved and of the techniques employed, we present a series of testbeds carried out to validate the code and assess its accuracy. Such tests range from the solution of relativistic Riemann problems in flat spacetime, over to the stationary accretion onto a Schwarzschild black hole and up to the evolution of oscillating magnetized stars in equilibrium and constructed as consistent solutions of the coupled Einstein-Maxwell equations.Comment: minor changes to match the published versio

Gravitational waves from inspiralling compact binaries with magnetic dipole moments

We investigate the effects of the magnetic dipole-dipole coupling and the electromagnetic radiation on the frequency evolution of gravitational waves from inspiralling binary neutron stars with magnetic dipole moments. This study is motivated by the discovery of the superstrongly magnetized neutron stars, i.e., magnetar. We derive the contributions of the magnetic fields to the accumulated cycles in gravitational waves as $N_{mag} \sim 6 \times 10^{-3} (H/10^{16}{\rm G})^{2}$, where $H$ denotes the strength of the polar magnetic fields of each neutron star in the binary system. It is found that the effects of the magnetic fields will be negligible for the detection and the parameter estimation of gravitational waves, if the upper limit for magnetic fields of neutron stars are less than $\sim 10^{16}$G, which is the maximum magnetic field observed in the soft gamma repeaters and the anomalous X-ray pulsars up to date. We also discuss the implications of electromagnetic radiation from the inspiralling binary neutron stars for the precursory X-ray emission prior to the gamma ray burst observed by the Ginga satellite.Comment: 15 pages, no figures, accepted for publication in Ap

Signal Transduction Pathways in the Pentameric Ligand-Gated Ion Channels

The mechanisms of allosteric action within pentameric ligand-gated ion channels (pLGICs) remain to be determined. Using crystallography, site-directed mutagenesis, and two-electrode voltage clamp measurements, we identified two functionally relevant sites in the extracellular (EC) domain of the bacterial pLGIC from Gloeobacter violaceus (GLIC). One site is at the C-loop region, where the NQN mutation (D91N, E177Q, and D178N) eliminated inter-subunit salt bridges in the open-channel GLIC structure and thereby shifted the channel activation to a higher agonist concentration. The other site is below the C-loop, where binding of the anesthetic ketamine inhibited GLIC currents in a concentration dependent manner. To understand how a perturbation signal in the EC domain, either resulting from the NQN mutation or ketamine binding, is transduced to the channel gate, we have used the Perturbation-based Markovian Transmission (PMT) model to determine dynamic responses of the GLIC channel and signaling pathways upon initial perturbations in the EC domain of GLIC. Despite the existence of many possible routes for the initial perturbation signal to reach the channel gate, the PMT model in combination with Yen's algorithm revealed that perturbation signals with the highest probability flow travel either via the β1-β2 loop or through pre-TM1. The β1-β2 loop occurs in either intra- or inter-subunit pathways, while pre-TM1 occurs exclusively in inter-subunit pathways. Residues involved in both types of pathways are well supported by previous experimental data on nAChR. The direct coupling between pre-TM1 and TM2 of the adjacent subunit adds new insight into the allosteric signaling mechanism in pLGICs. © 2013 Mowrey et al

DADA: data assimilation for the detection and attribution of weather and climate-related events

A new nudging method for data assimilation, delay‐coordinate nudging, is presented. Delay‐coordinate nudging makes explicit use of present and past observations in the formulation of the forcing driving the model evolution at each time step. Numerical experiments with a low‐order chaotic system show that the new method systematically outperforms standard nudging in different model and observational scenarios, also when using an unoptimized formulation of the delay‐nudging coefficients. A connection between the optimal delay and the dominant Lyapunov exponent of the dynamics is found based on heuristic arguments and is confirmed by the numerical results, providing a guideline for the practical implementation of the algorithm. Delay‐coordinate nudging preserves the easiness of implementation, the intuitive functioning and the reduced computational cost of the standard nudging, making it a potential alternative especially in the field of seasonal‐to‐decadal predictions with large Earth system models that limit the use of more sophisticated data assimilation procedures

Equilibrium Configurations of Strongly Magnetized Neutron Stars with Realistic Equations of State

We investigate equilibrium sequences of magnetized rotating stars with four kinds of realistic equations of state (EOSs) of SLy (Douchin et al.), FPS (Pandharipande et al.), Shen (Shen et al.), and LS (Lattimer & Swesty). Employing the Tomimura-Eriguchi scheme to construct the equilibrium configurations. we study the basic physical properties of the sequences in the framework of Newton gravity. In addition we newly take into account a general relativistic effect to the magnetized rotating configurations. With these computations, we find that the properties of the Newtonian magnetized stars, e.g., structure of magnetic field, highly depends on the EOSs. The toroidal magnetic fields concentrate rather near the surface for Shen and LS EOSs than those for SLy and FPS EOSs. The poloidal fields are also affected by the toroidal configurations. Paying attention to the stiffness of the EOSs, we analyze this tendency in detail. In the general relativistic stars, we find that the difference due to the EOSs becomes small because all the employed EOSs become sufficiently stiff for the large maximum density, typically greater than $10^{15}\rm{g} \rm{cm}^{-3}$. The maximum baryon mass of the magnetized stars with axis ratio $q\sim 0.7$ increases about up to twenty percents for that of spherical stars. We furthermore compute equilibrium sequences at finite temperature, which should serve as an initial condition for the hydrodynamic study of newly-born magnetars. Our results suggest that we may obtain information about the EOSs from the observation of the masses of magnetars.Comment: submitted to MNRA

Cold ideal equation of state for strongly magnetized neutron-star matter: effects on muon production and pion condensationn

Neutron stars with very strong surface magnetic fields have been suggested as the site for the origin of observed soft gamma repeaters (SGRs). In this paper we investigate the influence of such strong magnetic fields on the properties and internal structure of these magnetized neutron stars (magnetars). We study properties of a degenerate equilibrium ideal neutron-proton-electron (npe) gas with and without the effects of the anomalous nucleon magnetic moments in a magnetic field. The presence of a sufficiently strong magnetic field changes the ratio of protons to neutrons as well as the neutron drip density. We also study the appearance of muons as well as pion condensation in strong magnetic fields. We discuss the possibility that boson condensation in the interior of magnetars might be a source of SGRs.Comment: 10 pages included 9 figures, ApJ in pres