Liquid electrolytes for lithium-ion accumulators

Cieľom tejto diplomovej práce bolo meranie elektrickej vodivosti a dynamickej viskozity elektrolytov. Na základe týchto meraní bolo možné overiť Waldenov vzťah medzi meranými veličinami. Boli použité elektrolyty na bázy sulfolanu v kombinácií s propylenkarbonátom a so soľou. Diplomová práca sa tiež zaoberá meraním dielektrických vlastností elektrickou metódou a optickou metódou pomocou refraktometrie. Taktiež boli stanovené body tuhnutia zmesi sulfolanu a propylenkarbonátu pomocou kryoskopie.The aim of this master´s thesis was the measurement of electrical conductivity and dynamic viscosity of the electrolytes. Based on these measurements to verify Walden theorem between measured variables. Electrolytes were used on sulfolane base in combination with propylene carbonate and salt. The thesis also deals with the measuring method of dielectric properties of electrical and optical method with a refractometer. The freezing point of combination of sulfolan and propylene carbonate were determined by cryoscopy.

Observations of Asymmetric Lobe Convection for Weak and Strong Tail Activity

In this study we use high‐quality convection data from the Electron Drift Instrument on board Cluster to investigate how near‐Earth tail activity affects the average convection pattern in the magnetotail lobes when the interplanetary magnetic field has a dominating east‐west (By) component. Two different proxies have been used to represent different levels of reconnection in the near‐Earth tail: The value of the AL index and the substorm phases identified by the Substorm Onsets and Phases from Indices of the Electrojet algorithm. We find that the convection changes from a dominantly YGSM direction, but opposite in the two hemispheres, to a flow oriented more toward the plasma sheet, as the north‐south component of the convection increases when reconnection enhances in the near Earth tail. This result is consistent with recent observations of the convection in the ionosphere, which suggest that the nightside convection pattern becomes more north‐south symmetric when tail reconnection increases. This is also supported by simultaneous auroral observations from the two hemispheres, which shows that conjugate auroral features become more symmetric during substorm expansion phase. The reduced asymmetry implies that the asymmetric pressure balance in the lobes is altered during periods with strong reconnection in the near‐Earth tail

Observations of Asymmetric Lobe Convection for Weak and Strong Tail Reconnection

In this study we use high‐quality convection data from the Electron Drift Instrument on board Cluster to investigate how near‐Earth tail activity affects the average convection pattern in the magnetotail lobes when the interplanetary magnetic field has a dominating east‐west (By) component. Two different proxies have been used to represent different levels of reconnection in the near‐Earth tail: The value of the AL index and the substorm phases identified by the Substorm Onsets and Phases from Indices of the Electrojet algorithm. We find that the convection changes from a dominantly YGSM direction, but opposite in the two hemispheres, to a flow oriented more toward the plasma sheet, as the north‐south component of the convection increases when reconnection enhances in the near Earth tail. This result is consistent with recent observations of the convection in the ionosphere, which suggest that the nightside convection pattern becomes more north‐south symmetric when tail reconnection increases. This is also supported by simultaneous auroral observations from the two hemispheres, which shows that conjugate auroral features become more symmetric during substorm expansion phase. The reduced asymmetry implies that the asymmetric pressure balance in the lobes is altered during periods with strong reconnection in the near‐Earth tail

Dependence of the global dayside reconnection rate on interplanetary magnetic field By and the earth’s dipole tilt

Abstract In the recent years, significant attention has been given to the combined effect of Interplanetary Magnetic Field (IMF) duskward component (By) and dipole tilt on the global magnetosphere-ionosphere system response. Numerous studies have pointed out that when the Earth’s magnetic dipole is tilted away from the Sun (negative dipole tilt during northern winter), and IMF has a positive By component, the effects on ionospheric currents, particle precipitation, ionospheric convection, and average size of the auroral oval, is significantly more enhanced, compared to when IMF By is negative. Furthermore, this IMF By polarity effect reverses when Earth’s dipole is tilted in the opposite direction. The underlying cause has remained unclear. Our analysis shows that substorms tend to be stronger during the same IMF By and dipole tilt polarity combination. Taken together with earlier results showing also more frequent substorms during the same conditions, our observations suggests that when IMF By and dipole tilt have opposite signs, there is a more efficient global dayside reconnection rate. We also show analysis of the occurrence frequency of periods of Steady Magnetospheric Convection, substorm onset latitude, and the isotropic boundary of proton precipitation, that are all consistent with our conclusion that the combination of IMF By and dipole tilt polarity affect the global dayside reconnection rate