Mesure de la section efficace différentielle de production du boson Z se désintégrant en paires électron-position, dans l'expérience ATLAS

La première mesure du spectre en phi*_eta du boson Z à 7 TeV a été réalisée dans cette thèse. Cette variable permet de sonder la dynamique de production des Z de façon fine. L échantillon complet des données enregistrées par ATLAS en 2011 a été utilisé ce qui correspond à 4.7/fb de luminosité intégrée. Les résultats de cette mesure sont publiés dans la Ref. [18] fondé sur la note interne Ref. [69]. La section efficace différentielle de Z->ee en fonction phi*_eta a été mesurée et comparée aux calculs perturbatifs à ordre fixé, avec/sans resommation pour la région des petits phi*_eta. Le code RESBOS fournit la meilleure description des données, cependant il est incapable de reproduire, à mieux de 4%, la forme détaillée de la section efficace mesurée. La section efficace différentielle a également été comparée aux prédictions de différents générateurs Monte Carlo interfacés avec un algorithme de parton shower. Les meilleures descriptions du spectre en phi*_eta mesuré sont données par les générateurs SHERPA et POWHEG+PYTHIA8. La mesure précise de la section efficace différentielle en phi*_eta fournit des informations précieuses pour l ajustement des codes Monte Carlo. La précision expérimentale typique de cette mesure (~0.5%) est dix fois meilleure que la précision des calculs théoriques et elle est donc aussi précieuse pour contraindre la théorie. La mesure du spectre en ptZ a également été faite pour quantifier l incertitude systématique de cette mesure en utilisant la grande statistique de l échantillon de données. Cela permet de comparer deux mesures qui traitent de l impulsion transverse du boson Z. Dans la plupart du domaine en phi*_eta l incertitude systématique de la mesure de ptZ est deux fois plus grande que celle de la mesure de phi*_eta. Cette comparaison confirme l intérêt de la variable phi*_eta. Les résultats présentés dans cette thèse ont beaucoup d implications pour les études futures. Ajustant les générateurs Monte Carlo en utilisant les résultats de la mesure précise du spectre en phi*_eta minimisera l incertitude sur leurs paramètres. Une mesure de la section efficace doublement différentielle en ptZ et phi*_eta est intéressante pour mieux comprendre la corrélation entre ces deux variables. La mesure précise du spectre en ptZ utilisant la variable phi*_eta peut être appliquée au spectre en ptW et on sait que des mesures plus fines du ptW sont importante pour une détermination précise de la masse du boson W. De plus, une compréhension précise du spectre en ptZ est importante pour comprendre les propriétés cinématiques de la production du boson de Higgs.The first measurement of the phi*_eta spectrum of Z bosons at 7 TeV of pp collisions has been studied in this thesis, which is an alternative way to probe the transverse momentum of Z bosons. The full data sample recorded by the ATLAS detector during 2011 run of the LHC was used, which corresponds with 4.7/fb integrated luminosity. The results of this measurement were reported in Ref. [18] supported by the internal note in Ref. [69]. The differential cross section of Z->ee as a function of phi*_eta has been measured and compared to fixed order perturbative QCD calculations with/without a resummation for the low phi*_eta region. Calculations using RESBOS provide the best descriptions of the data. However, they are unable to reproduce the detailed shape of the measured cross section to better than 4%. The differential cross section was also compared to predictions from different Monte Carlo generators interfaced to a parton shower algorithm. The best descriptions of the measured phi*_eta spectrum are provided by SHERPA and POWHEG+PYTHIA8 Monte Carlo event generators. The precise measurement of the differential cross section as a function of phi*_eta provides valuable information for the tuning of MC generators. The typical experimental precision of this measurement (~0.5%) is ten times better than the typical theoretical precision and therefore is valuable to constrain the theoretical predictions further. The ptZ measurement has been also studied to quantify the systematic uncertainty of this measurement using the high statistic data sample. This allows to compare two measurements which both address the physics issues of the Z transverse momentum. In most of the phi*_eta range, the systematic uncertainty of the ptZ measurement is two times larger than the one of the phi*_eta measurement. This comparison confirms the interest for the phi*_eta variable. The measurements presented in this thesis has many implications for future studies. Tuning MC generators using the result of the precise measurement of the phi*_eta spectrum will minimize the uncertainty on the tuned parameters. A double differential cross section measurement as a function of ptZ and phi*_eta is interesting to understand the correlation between ptZ and phi*_eta variables. The precise measurement of the ptZ spectrum using the new variable phi*_eta can be applied to ptZ. More precise measurement of ptZ are important to obtain precise measurements of the W mass. In addition, a precise understanding of the ptZ spectrum is important to understand kinematic properties of Higgs boson production.SAVOIE-SCD - Bib.électronique (730659901) / SudocGRENOBLE1/INP-Bib.électronique (384210012) / SudocGRENOBLE2/3-Bib.électronique (384219901) / SudocSudocFranceF

Study on anticorrosion properties of epoxy primers on steel.

Epoxy resin DER 671X75 was reinforced by nanoclay cloisite 30B with content of 2% and primer coatings based on epoxy resin DER 671X75 were formed with pigments, fillers. Epoxy coating  films were exposed by electrochemical method in NaCl 3.5 % solution in 28 days and salt spray accelerated tester in 330 hrs. The results show that nanoclay cloisite 30B are improved anticorrosion properties of primer coatings based on epoxy resin DER671X75. Keywords. Epoxy primer coating, nanoclay cloisite 30B, epoxy resin DER 671X75, electrochemical, anticorrosion properties steel

IMPROVEMENT OF CO2 PURIFYING SYSTEM BY PHOTOCATALYST FOR APPLICATION IN MICROALGAE CULTURE TECHNOLOGY

By reactive grinding method Vanadium-doped rutile TiO2 nanoparticle material was obtained with an average particle size of 20‐40nm, the Brunauer–Emmet–Teller (BET) specific surface area about 20 m2g−1 and it absorbed strongly in the UV region and increased at the visible wavelength of 430 – 570 nm. This study focused on the improvement of exhaust gas treatment from coal-fired flue gas of the traditional adsorption-catalysis system (Modular System for Treating Flue Gas - MSTFG) by using the V2O5/TiO2 Rutile as photocatalyst. The results showed that integrating both catalytic systems mentioned above increased the gas treatment efficiency: CO from 77 % to over 98 %, NOx from 50 % to 93 %, SO2 was absent as opposed to the input gas component. Also it showed that V2O5/TiO2 Rutile integrated with MSTFG has got high efficiency of CO treatment, also secured the high obtained CO2 concentration as a valuable carbon source for microagal mass culture as well as saving energy and simplifying devices

Fabrication of transparent flexible electrodes on polyethylene terephthalate substrate with high conductivity, high transmittance, and excellent stability

Transparent flexible electrodes based on silver nanowires (AgNWs) have great potential for practical applications and many studies have been carried out to improve their conductivity, transparency, and surface roughness. In this study, we demonstrate a new approach for the fabrication of high-performance transparent flexible electrodes based on AgNWs and graphene oxide (GO) on polymer substrates using the pressing method. The surface morphology of the pressed AgNW/GO electrode was characterised by atomic force microscopy (AFM) and observed by scanning electron microscope (SEM). The electrode had a low surface roughness with the root mean square (Rq) of 7 nm. The electrode exhibits a low sheet resistance of 22 Ω/sq, a high transmittance of ~88%, resulted in a figures-of-merit (FoM) value of ~12.6. The optical and electrical properties of the electrode are comparable to that of the flexible ITO electrode. In addition, the electrodes also displayed outstanding durability and mechanical stability. This simple and scalable fabrication method is expected to contribute to future studies on flexible transparent conductive electrodes

Crystal structure of two <i>N</i>'-(1-phenyl-benzyl-idene)-2-(thio-phen-3-yl)acetohydrazides.

The synthesis, spectroscopic data, crystal and mol-ecular structures of two N'-(1-phenyl-benzyl-idene)-2-(thio-phen-3-yl)acetohydrazides, namely N'-[1-(4-hy-droxy-phen-yl)benzyl-idene]-2-(thio-phen-3-yl)acetohydrazide, C13H10N2O2S, (3a), and N'-[1-(4-meth-oxy-phen-yl)benzyl-idene]-2-(thio-phen-3-yl)acetohydrazide, C14H14N2O2S, (3b), are described. Both compounds differ in the substituent at the para position of the phenyl ring: -OH for (3a) and -OCH3 for (3b). In (3a), the thio-phene ring is disordered over two orientations with occupancies of 0.762 (3) and 0.238 (3). The configuration about the C=N bond is E. The thio-phene and phenyl rings are inclined by 84.0 (3) and 87.0 (9)° for the major- and minor-occupancy disorder components in (3a), and by 85.89 (12)° in (3b). Although these dihedral angles are similar, the conformation of the linker between the two rings is different [the C-C-C-N torsion angle is -ac for (3a) and -sc for (3b), while the C6-C7-N9-N10 torsion angle is +ap for (3a) and -sp for (3b)]. A common feature in the crystal packing of (3a) and (3b) is the presence of N-H⋯O hydrogen bonds, resulting in the formation of chains of mol-ecules running along the b-axis direction in the case of (3a), or inversion dimers for (3b). The most prominent contributions to the surface contacts are those in which H atoms are involved, as confirmed by an analysis of the Hirshfeld surface

Can a Short Food Supply Chain Create Sustainable Benefits for Small Farmers in Developing Countries? An Exploratory Study of Vietnam

A number of studies have indicated that short food supply chains could create economic, social, and environmental benefits, but most of those chains were implemented in developed countries. This research aims to find out the characteristics of short food supply chains and their benefits to small farmers in Vietnam, which is a developing country, based on the survey results from 338 small farmers in the third quarter of 2020, with the support of Stata 14 software. The results showed that the short food supply chains in the survey sample in Vietnam were characterized by two main actors: small farmers and distributors. Farmers could sell products flexibly at the local market. There was some initial evidence to prove that these chains helped to stabilize the input, output price, and revenue; formulated sustainable income; and increased the satisfaction and confidence of farmers. They eliminated gender discrimination in rural areas and improved livelihood for ethnic minorities. These chains also enhanced the mindset on green, organic, and clean production of farmers, which in turn created environmental benefits. COVID-19 has posed a negative impact on the income of farmers and made them change their production and sales method. Therefore, the research could suggest some policies to sustainably develop the short food supply chains in Vietnam in the future

Synthesis and redetermination of the crystal structure of salicyl-aldehyde <i>N</i>(4)-morpholino-thio-semi-carbazone.

The structure of the title compound (systematic name: N-{[(2-hy-droxy-phen-yl)methyl-idene]amino}-morpholine-4-carbo-thio-amide), C12H15N3O2S, was prev-iously determined (Koo et al., 1977 ▸) using multiple-film equi-inclination Weissenberg data, but has been redetermined with higher precision to explore its conformation and the hydrogen-bonding patterns and supra-molecular inter-actions. The mol-ecular structure shows intra-molecular O-H⋯N and C-H⋯S inter-actions. The configuration of the C=N bond is E. The mol-ecule is slightly twisted about the central N-N bond. The best planes through the phenyl ring and the morpholino ring make an angle of 43.44 (17)°. In the crystal, the mol-ecules are connected into chains by N-H⋯O and C-H⋯O hydrogen bonds, which combine to generate sheets lying parallel to (002). The most prominent contribution to the surface contacts are H⋯H contacts (51.6%), as concluded from a Hirshfeld surface analysis

Safety and efficacy of fluoxetine on functional outcome after acute stroke (AFFINITY): a randomised, double-blind, placebo-controlled trial

Background Trials of fluoxetine for recovery after stroke report conflicting results. The Assessment oF FluoxetINe In sTroke recoverY (AFFINITY) trial aimed to show if daily oral fluoxetine for 6 months after stroke improves functional outcome in an ethnically diverse population. Methods AFFINITY was a randomised, parallel-group, double-blind, placebo-controlled trial done in 43 hospital stroke units in Australia (n=29), New Zealand (four), and Vietnam (ten). Eligible patients were adults (aged ≥18 years) with a clinical diagnosis of acute stroke in the previous 2–15 days, brain imaging consistent with ischaemic or haemorrhagic stroke, and a persisting neurological deficit that produced a modified Rankin Scale (mRS) score of 1 or more. Patients were randomly assigned 1:1 via a web-based system using a minimisation algorithm to once daily, oral fluoxetine 20 mg capsules or matching placebo for 6 months. Patients, carers, investigators, and outcome assessors were masked to the treatment allocation. The primary outcome was functional status, measured by the mRS, at 6 months. The primary analysis was an ordinal logistic regression of the mRS at 6 months, adjusted for minimisation variables. Primary and safety analyses were done according to the patient's treatment allocation. The trial is registered with the Australian New Zealand Clinical Trials Registry, ACTRN12611000774921. Findings Between Jan 11, 2013, and June 30, 2019, 1280 patients were recruited in Australia (n=532), New Zealand (n=42), and Vietnam (n=706), of whom 642 were randomly assigned to fluoxetine and 638 were randomly assigned to placebo. Mean duration of trial treatment was 167 days (SD 48·1). At 6 months, mRS data were available in 624 (97%) patients in the fluoxetine group and 632 (99%) in the placebo group. The distribution of mRS categories was similar in the fluoxetine and placebo groups (adjusted common odds ratio 0·94, 95% CI 0·76–1·15; p=0·53). Compared with patients in the placebo group, patients in the fluoxetine group had more falls (20 [3%] vs seven [1%]; p=0·018), bone fractures (19 [3%] vs six [1%]; p=0·014), and epileptic seizures (ten [2%] vs two [<1%]; p=0·038) at 6 months. Interpretation Oral fluoxetine 20 mg daily for 6 months after acute stroke did not improve functional outcome and increased the risk of falls, bone fractures, and epileptic seizures. These results do not support the use of fluoxetine to improve functional outcome after stroke

Mesure de la section efficace différentielle de production du boson Z se désintégrant en paires électron-positon, dans l'expérience ATLAS

There are several reasons to study the $Z$ and $W$ bosons at LHC. The understanding of weak vector boson production tests the Standard Model predictions and is necessary to maximize the sensitivity to new physics at hadron colliders. Moreover, the $W$ and $Z$ boson productions play an important role in the calibration of the ATLAS (A Toroidal LHC ApparatuS) detector. The focus of my thesis work is on the study of a new variable which addresses the same physics issues as the $Z$ transverse momentum ($p^Z_T$). The relatively large cross section at LHC of the $Z$ production decaying into lepton pairs and its very low background enable a precise measurement of $p^Z_T$ which gives a very sensitive way of studying dynamical effects of the strong interaction, complementary to measurements of the associated production of the bosons with jets. At large $p^Z_T$ (greater than approximately 30 GeV), the radiation of a single parton with large transverse momentum dominates the cross section, and fixed-order perturbative Quantum chromodynamics (pQCD) calculations yield reliable predictions. So this measurement provides an ideal testing of pQCD. At lower $p^Z_T$, pQCD no longer gives accurate results due to the emission of multiple soft gluons. This fact has been solved in two ways: by using resummation to all orders up to next-to-next-to-leading logarithms (NNLL) in $\alpha_s$, or by modeling with parton showers. For such reasons, this measurement is important in tuning Monte Carlo generators. Many studies showed that there is an optimized variable which is less sensitive to the experiment resolution, and probes the same physics as $p^Z_T$. The precise measurement using this optimized variable will allow to test a very small effect like the small-x broadening of the $p^Z_T$ distribution which takes into account the parton fraction dependence in the resummation form factor. My thesis will show the result for the differential cross section of the $Z$ boson as a function of the new variable $\phi^*_\eta$ in comparison with different theoretical predictions and with different Monte Carlo generators. The thesis is organized in 6 chapters. Chapter 1 is devoted to a theoretical review. The predictions from QCD calculations and from different Monte Carlo generators of the $p^Z_T$ spectrum and the $\phi^*_\eta$ spectrum of the $Z$ boson are presented. The general structure of the LHC and the ATLAS detector is introduced in Chapter 2. Their operation parameters at 7 TeV collisions are shown. Chapter 3 introduces the event reconstruction in the ATLAS experiment. A technical study performed by the author is presented here. Chapter 4 is dedicated to the event reconstruction of the $Z$ boson decaying into a pair of electron and positron. The treatments for the different effects such as the multiple interactions in proton-proton collisions, the mis-modeling of the $p^Z_T$ spectrum in data by the Monte Carlo generators are discussed. Most of the work in this chapter concentrates on the QCD background estimation. The differential cross section measurement of the $Z$ boson as a function of $\phi^*_\eta$ is presented in Chapter 6. The result of this measurement is precise at the per mil level. The unfolded $\phi^*_\eta$ spectrum in data is compared with many predictions that will help for the future tuning of Monte Carlo generators. In order to express the complementarity of the $\phi^*_\eta$ measurement with respect to the $p_T^Z$ measurement, the $p_T^Z$ measurement is also done in my thesis and is presented in Chapter 5

Measurement of the differential cross section of the production Z boson decaying into electron-positron pairs in the ATLAS experiment

La première mesure du spectre en phi*_eta du boson Z à 7 TeV a été réalisée dans cette thèse. Cette variable permet de sonder la dynamique de production des Z de façon fine. L’échantillon complet des données enregistrées par ATLAS en 2011 a été utilisé ce qui correspond à 4.7/fb de luminosité intégrée. Les résultats de cette mesure sont publiés dans la Ref. [18] fondé sur la note interne Ref. [69]. La section efficace différentielle de Z->ee en fonction phi*_eta a été mesurée et comparée aux calculs perturbatifs à ordre fixé, avec/sans resommation pour la région des petits phi*_eta. Le code RESBOS fournit la meilleure description des données, cependant il est incapable de reproduire, à mieux de 4%, la forme détaillée de la section efficace mesurée. La section efficace différentielle a également été comparée aux prédictions de différents générateurs Monte Carlo interfacés avec un algorithme de parton shower. Les meilleures descriptions du spectre en phi*_eta mesuré sont données par les générateurs SHERPA et POWHEG+PYTHIA8. La mesure précise de la section efficace différentielle en phi*_eta fournit des informations précieuses pour l’ajustement des codes Monte Carlo. La précision expérimentale typique de cette mesure (~0.5%) est dix fois meilleure que la précision des calculs théoriques et elle est donc aussi précieuse pour contraindre la théorie. La mesure du spectre en ptZ a également été faite pour quantifier l’incertitude systématique de cette mesure en utilisant la grande statistique de l’échantillon de données. Cela permet de comparer deux mesures qui traitent de l’impulsion transverse du boson Z. Dans la plupart du domaine en phi*_eta l’incertitude systématique de la mesure de ptZ est deux fois plus grande que celle de la mesure de phi*_eta. Cette comparaison confirme l’intérêt de la variable phi*_eta. Les résultats présentés dans cette thèse ont beaucoup d’implications pour les études futures. Ajustant les générateurs Monte Carlo en utilisant les résultats de la mesure précise du spectre en phi*_eta minimisera l’incertitude sur leurs paramètres. Une mesure de la section efficace doublement différentielle en ptZ et phi*_eta est intéressante pour mieux comprendre la corrélation entre ces deux variables. La mesure précise du spectre en ptZ utilisant la variable phi*_eta peut être appliquée au spectre en ptW et on sait que des mesures plus fines du ptW sont importante pour une détermination précise de la masse du boson W. De plus, une compréhension précise du spectre en ptZ est importante pour comprendre les propriétés cinématiques de la production du boson de Higgs.The first measurement of the phi*_eta spectrum of Z bosons at 7 TeV of pp collisions has been studied in this thesis, which is an alternative way to probe the transverse momentum of Z bosons. The full data sample recorded by the ATLAS detector during 2011 run of the LHC was used, which corresponds with 4.7/fb integrated luminosity. The results of this measurement were reported in Ref. [18] supported by the internal note in Ref. [69]. The differential cross section of Z->ee as a function of phi*_eta has been measured and compared to fixed order perturbative QCD calculations with/without a resummation for the low phi*_eta region. Calculations using RESBOS provide the best descriptions of the data. However, they are unable to reproduce the detailed shape of the measured cross section to better than 4%. The differential cross section was also compared to predictions from different Monte Carlo generators interfaced to a parton shower algorithm. The best descriptions of the measured phi*_eta spectrum are provided by SHERPA and POWHEG+PYTHIA8 Monte Carlo event generators. The precise measurement of the differential cross section as a function of phi*_eta provides valuable information for the tuning of MC generators. The typical experimental precision of this measurement (~0.5%) is ten times better than the typical theoretical precision and therefore is valuable to constrain the theoretical predictions further. The ptZ measurement has been also studied to quantify the systematic uncertainty of this measurement using the high statistic data sample. This allows to compare two measurements which both address the physics issues of the Z transverse momentum. In most of the phi*_eta range, the systematic uncertainty of the ptZ measurement is two times larger than the one of the phi*_eta measurement. This comparison confirms the interest for the phi*_eta variable. The measurements presented in this thesis has many implications for future studies. Tuning MC generators using the result of the precise measurement of the phi*_eta spectrum will minimize the uncertainty on the tuned parameters. A double differential cross section measurement as a function of ptZ and phi*_eta is interesting to understand the correlation between ptZ and phi*_eta variables. The precise measurement of the ptZ spectrum using the new variable phi*_eta can be applied to ptZ. More precise measurement of ptZ are important to obtain precise measurements of the W mass. In addition, a precise understanding of the ptZ spectrum is important to understand kinematic properties of Higgs boson production