18 research outputs found
Intriguing Chemistry of Molybdenum Corroles
No full textThe development of new methodologies
for gaining access to low-valent molybdenum complexes led to spectroscopic
identification of mononuclear (oxo)molybdenum(IV) corroles, as well
as the full characterization of a binuclear molybdenum(IV) corrole
that is bridged through axial O atoms by a Mg(THF)<sub>4</sub> moiety
Intriguing Chemistry of Molybdenum Corroles
No full textThe development of new methodologies
for gaining access to low-valent molybdenum complexes led to spectroscopic
identification of mononuclear (oxo)molybdenum(IV) corroles, as well
as the full characterization of a binuclear molybdenum(IV) corrole
that is bridged through axial O atoms by a Mg(THF)<sub>4</sub> moiety
5d Early-Transition-Metal Corroles: a Trioxo-Bridged Binuclear Tungsten(VI) Derivative
No full textThe synthesis and full characterization of the first
tungsten corrole
reveal that it is a binuclear trioxo-bridged complex of tungsten(VI),
a coordination motif without precedence for tungsten chelated by other
ligands
